Abstract
Chemical evolution of molecular clouds seems to be governed by both chemistry and dynamics. We briefly describe the basics of the coupled chemical-dynamical evolution. Current problems involving the simplest species, such as C, CO, O2 , H2O, in quiescent clouds are then discussed. We emphasize the simplest molecules, because their chemistry is much less uncertain than the chemistry of the larger, more complex molecules. This allows the role of dynamics to be elucidated with a little bit more confidence. A particularly interesting issue in this area is the possibility that a molecule or a suite of molecules may serve as signpost of quiescent dynamical evolution. It is recognized that complex molecules may be more useful for this purpose, once their chemistry is at least fairly understood. Energetic dynamical phenomenon, such as shocks, produce dramatic chemical signatures, such as the dramatically enhanced CH+ abundance, due to the opening of otherwise forbidden chemical reaction paths. As a corollary, chemistry may have the potential to improve our understanding of the impulsive dynamical processes in a significant manner. Equally impressive are the footprints of star formation on the chemical evolution of the parent dense cloud. This has been discussed with respect to the star forming region in the Orion. It seems possible that chemistry might act as a tracer of embedded protostellar or stellar objects which manage to elude direct observations.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Adams, N. G., Smith, D., and Millar, T. J. 1984, Mon. Not. R. Astr. Soc., 211, 857.
Allen, M., and Robinson, G. W. 1975, Ap. J., 195, 91.
Allen, M., and Robinson, G. W. 1977, Ap. J., 212, 396.
Allamandola, L. J., Tielens, A. G. G. M., and Barker, J. R. 1985, Ap. J. (Letters), 290, L25.
Barlow, S. E., Dunn, G. H., and Schauer, M. 1984, Phys. Rev. Lett., 52, 902.
Barsuhn, J., and Walmsley, C. M. 1977, Astr. Ap., 54, 345.
Bastien, P., Bieging, J., Henkel, C., Martin, R. N., Pauls, T., Wamsley, C. M., and Ziurys, L. M. 1981, Astr. Ap. 98, L94.
Bates, D. R. 1979, J. Phys. B, 12, 4135.
Bates, D. R. 1983a, Ap. J. (Letters), 267, L121.
Bates, D. R. 1983b. Ap. J., 270, 564.
Black, J. H., and Dalgarno, A. 1977, Ap. J. Suppl., 34, 405.
Black, D. C., and Scott, E. H., 1982, Ap . J., 263, 697.
Blake, G. A. 1986, Ph. D. Thesis. California Institute of Technology.
Blitz, L. 1984 (April), Scientific American, page 88.
Bohme, D. K. 1986, Nature,319, 473.
Boland, W., and de Jong, T. 1982, Ap. J., 261, 110.
Boland, W., and de Jong, T. 1984, Astr. Ap., 134, 87.
Burke, J. R., and Hollenbach, D. J. 1983, Ap. J., 265, 223.
Clary, D. C. 1985, Mol. Phys.,54, 605.
Dalgarno, A. 1982, Phil. Trans. R. Soc. Lond., A303, 513.
de Jong, T., Dalgarno, A., and Boland W. 1980, Astr. Ap., 91, 68.
DeMore, W. B. et al., NASA Panel for Data Evaluation 1985, JPL Publication 85–37, Jet Propulsion Laboratory, California Institute for Technology, Pasadena, California, USA.
Dickman, R. L., Somerville, W. B., Whittet, D. C. B., McNally, D., and Blades, J. C. 1983, Ap. J. Suppl., 53, 55.
Disney, M. J., McNally, D., and Wright, A. E. 1969, Mon. Not. R. Astr. Soc.,146, 123.
Draine, B. T. 1978, Ap. J. Suppl., 36, 595.
Draine, B. T. 1986, Submitted to Ap, J.
Draine, B. T. and Anderson, N. 1985, Ap. J., 292, 491.
Draine, B. T., and Katz, N. 1986, Ap. J., 306, 655.
Duley, W. W., Millar, J. J., and Williams, D. A. 1980, Mon. Not. R. Astr. Soc., 192, 945.
Elitzur, M., and Watson, W. D. 1980, Ap. J., 236, 172.
Federman, S. R., and Glassgold, A. E. 1980, Astr. Ap., 89, 113.
Federman, S. R., and Glassgold, A. E., Jenkins, E. B., and Shaya, E. J. 1980, Ap. J., 242, 545.
Frerking, M. A., Langer, W. D., and Wilson, R. W. 1982, Ap. J., 262, 590.
Friberg, P. 1984, Astr. Ap.,132, 265.
Genzel, R., Downes, D., Ho, P. T. P., Bieging, J. 1982, Ap. J. (Letters), 259, L103.
Gerola, H., and Glassgold, A. E. 1978, Ap, J. Suppl.,37, 1.
Glassgold, A. E. 1985, in Protostars and Planets. II., Ed. D. C. Black and M. Matthews, (Tucson: University of Arizona Press)
Glassgold, A. E., and Langer, W. D. 1974, Ap. J., 193, 73.
Glassgold, A. E. 1976, Ap. J., 206, 85.
Goldsmith, P. F., and Langer, W. D. 1978, Ap. J., 222, 881.
Graff, M., and Dalgarno, A. 1986, submitted to Ap. J.
Graedel, T. E., Langer, W. D., and Frerking, M. A. 1982, Ap. J. Suppl., 48, 321.
Goldsmith, P. F., Krotkov, R., Snell, R. L., Brown, R. D., and Godfrey, P. 1983, Ap. J.,274, 184.
Hartquist, T. W., Oppenheimer, M., and Dalgarno, A. 1980, Ap. J., 236, 180.
d’Hendecourt, L. B., Allamandola, L. J., Bass, F., and Greenberg, J. M. 982, Astr. Ap., 109, L12.
d’Hendecourt, L. B., Allamandola, L. J., and Greenberg, J. M. 1985, Astr. Ap.,152, 130.
Henning, K. 1981, Astr. Ap. Suppl., 44, 405.
Herbst, E. 1982, Ap. J., 252, 810.
Herbst, E. 1983a, Ap. J., 270, 564.
Herbst, E. 1983b, Ap. J. (Letters), 267, L121.
Herbst, E. 1985, Ap. J., 291, 226.
Herbst, E. 1987. This volume.
Herbst, E., and Klemperer, W. 1973, Ap. J., 185, 505.
Hollenbach, D. J., and Salpeter, E. E. 1970, J. Chem. Phys., 82, 3152.
Hollenbach, D. J., and Salpeter, E. E. 1971, Ap. J., 163, 155.
Hollenbach, D. J., and Salpeter, E. E., Werner, M. W., and Salpeter, E. E. 1971, Ap. J., 163, 165.
Hunter, J. H. 1969, Mon. Not. R. Astr. Soc., 142, 473.
Huntress, W. T., Jr. 1977, Ap. J. Suppl., 33, 495.
Iglesias, E. R. 1977, Ap. J., 218, 697.
Iglesias, E. R., and Silk, J. 1978, Ap. J., 226, 851.
Irvine, W. M., Good, J. C., and Schloerb, F. P. 1983, Astr. Ap., 127, L10.
Irvine, W. M., Schloerb, F. P., Hajlmarson, A., and Herbst, E. 1985, in Protostars and Planets. II., Ed. D. C. Black and M. Matthews (Tucson: University of Arizona Press)
Irvine, W. M., Goldsmith, P. F., and Hjalmarson, A. 1987. This volume. Jenkins, E. B. 1987. This volume.
Jenkins, E. B., Savage, B. D., and Spitzer, L. 1986, Ap. J., 301, 355.
Johansson, L. E. B., Andersson, C., Ellder, J., Friberg, P., Hjalmarson, A., Hoglund, B., Irvine, W. M., Olofsson, H., and Rydbeck, G. 1984, Astr. Ap., 130, 227.
Keenan, F. P., Dufton, P. L., Hilbert, A., and Murray, M. J. 1986. Mon. Not. R. Astr. Soc.. , 222, 143.
Keene, J., Blake, G. A., Phillips, T. G., Huggins, P. J., and Beichman, C. A. 1985, Ap. J., 299, 967.
Kessler, M. F., and Phillips, J. P. 1984, Galactic and Extra Galactic Infrared Spectroscopy. Ed. M. F. Kessler and J. P. Phillips (Reidel: Dordrecht)
Kiguchi, M., Suzuki, H., Sata, K., Miki, S., Tominatsu, A., and Nakagawa, Y. 1974, Pub. Astr. Soc. Japan. 26, 499
Knapp G., and Jura, M. 1976, Ap. J., 209, 782.
Lacy, J. H., Bass, F., Allamandola, L. J., Persson, A. C., McGregor, P. J., Landsdale, C. J., Gaballe, T. R., and van de Bult, C. E. P. M. 1984, Astr. Ap., 276, 533.
Langer, W. D., Graedel, T. E., Frerking, M. A., and Armentrout, P. B. 1985, Ap. J., 277, 581.
Leger, A., and Puget, J. L. 1984, Astr. Ap., 137, L5.
Leger, A., Jura, M., and Omont, A. 1985, Astr. Ap., 144, 147.
Leung, C. M., Herbst, E., and Huebner, W. F. 1984, Ap. J. Suppl., 56, 231.
Leung, C. M., and Herbst, E., 1986. In press with Mon. Not. R. Astr. Soc.
Lizst, H. S. 1979, Ap. J. (Letters), 233, L147.
Liszt, H. S. 1985, Ap. J, 298, 281.
Liszt, H. S., and Vanden Bout, P. A. 1985, Ap. J., 291, 178.
Mann, A. P. C., and Williams, D. A. 1984, Mon. Not. R. Astr. Soc., 209, 33.
Mann, A. P. C., and Williams, D. A. 1985, Mon. Not. R. Astr. Soc., 214, 279.
Mathis, J. A., Merzer, P. C., and Panagia, N. 1983, Astr. Ap., 128, 212.
Matthews, H. E., Friberg, P., and Irvine, W. M. 1985, Ap. J., 290, 609.
McEwan, M. J., Anicich, V. G., Huntress, W. T., Jr., Kemper, P. R., and Bowers, M. T. 1980, Chem. Phys Letters., 75, 278.
Millar, T. J., and Freeman, A. 1984a, Mon. Not. R. Astr. Soc., 207, 405.
Millar, T. J., and Freeman, A. 1984b, Mon. Not. R. Astr. Soc., 204, 425.
Millar, T. J., Adams, N. G., Smith, D., and Clary, D. C. 1985, Mon. Not. R. Astr. Soc., 216, 1025
Millar, T. J., and Nejad, L. A. M. 1985, Mon. Not. R. Astr. Soc., 217, 507.
Mitchell, G. M. 1984, Ap. J. Suppl. 54, 81.
Mitchell, G. M., and Deveau, T. J. 1983, Ap. J., 266, 646.
Mitchell, G. M., and Watts, G. D. 1985, Astr. Ap., 151, 121.
Mitchell, G. M., Ginzberg, J. L., and Kunz, P. J. 1978, Ap. J. Suppl., 38, 39.
Moore, E. L., Langer, W. D., and Huguenin, G. R. 1986, Ap. J., 306, 682.
Morton, D. C. 1975, Ap. J., 197, 85.
Olofsson, H. 1984, Astr. Ap., 134, 36.
Olofsson, H., Ellder, J. Hjalmarson, A., and Rydbeck, G. 1982, Astr. Ap., 113, L18.
Omont, A. 1986, Astr. Ap., 164, 159.
Oppenheimer, M., and Dalgarno, A. 1975, Ap. J., 200, 419.
Paleogolou, E. V., and Mouschovias, T. Ch. 1983, Ap. J., 275, 838.
Penston, M. V. 1969, Mon. Not. R. Astr. Soc., 145, 457.
Phillips, T. G., and Huggins, 1981, Ap. J., 251, 533.
Pickles, J. B., and Williams, D. A. 1977a, Astr. Space. Sci., 52, 443.
Pickles, J. B., and Williams, D. A. 1977b, Astr. Space Sci., 52, 453.
Pickles, J. B., and Williams, D. A., 1981, Mon. Not. R. Astr. Soc., 197, 429.
Pineau des Fortes, G., Flower, D. R., Hartquist, T. W., and Dalgarno, A., 1984, Mon. Not. R. Astr. Soc., 220, 801.
Plambeck, R. L., Wright, M. C. H., Welch, W. J., Bieging, J. H., Baud, B., Ho, P. T. H., and Vogel, S. N. 1982, Ap. J., 259, 617.
Platt, J. R. 1956, Ap. J., 123, 486.
Prasad, S. S. 1987, to appear in IAU Symposium 120, Asrochemistrv. eds. M. S. Vardya and S. P. Tarafdar (Dordrecht:Reidel)
Prasad, S. S., and Huntress, W. T., Jr. 1982, Ap. J., 260, 590.
Prasad, S. S., and Huntress, W. T. 1980a, Ap. J. Suppl., 43, 1.
Prasad, S. S., and Huntress, W. T. 1980b, Ap. J., 239, 151.
Prasad, S. S., and Tarafdar, S. P. 1983, Ap. J., 267, 603.
Schloerb, F. P., Loren, R. B. 1982, in Symposium on the Orion Nebula to Honor Henry Draper. eds A. E. Glassgold, P. J. Huggins, and E. L. Shuckling (Ann N. Y. Acad. Sci., New York)
Sellgren, K. 1984, Ap. J., 277, 623.
Shu, F. 1983, Ap. J., 273, 202.
Spitzer, L. 1978, Physical Processes in the Interstellar Medium (Interscience:New York)
Smith, D., and Adams, N. G. 1984, Ap. J. (Letters), 284, L13.
Suzuki, H., Miki, S., Sata, K., Kiguchi, M., and Nakagawa, Y. 1976, Progr. Theoret. Phys. (Japan). 56, 1111.
Sweitzer, J. S. 1978, Ap. J., 225, 116.
Takahasi, T., Hollenbach, D. J., and Silk, J. 1983, Ap. J., 275, 145.
Tarafdar, S. P., and Krishnaswamy, K. S. 1982, Mon. Not. R. Astr. Soc., 200, 431.
Tarafdar, S. P., Prasad, S. S., and Huntress, W. T., Jr. 1983, Ap. J., 267, 156.
Tarafdar, S. P., Prasad, S. S., Huntress, W. T. Jr., Villere, K. R., and Black, D. C. 1985, Ap. J., 289, 220 (TPHVB).
Tielens, A. G. G. M., and Hollenbach, D. J. 1985a, Ap. J., 291, 722.
Tielens, A. G. G. M., and Hollenbach, D. J. 1985b, Ap. J., 291, 747.
Thaddeus, P., Guelin, M., and Linke, R. A. 1981, Ap. J. (Letters), 246, L41.
van de Hulst, H. C. 1949, Rech. Astr. Obs. Utrecht. 11, part 2.
van Dishoeck, E. F., and Black, J. H. 1986, Ap. J. Suppl. in press.
Vardya, M. S., and Tarafdar, S. P. 1987, eds. Astrochemistry. IAU Symposium 120 (Reidel:Dordrecht).
Vrtileck, J. M., Thaddeus, P., and Gottlieb, C. A. 1985, Bull. Am. Astr. Soc., 17, 568.
Wannier, P. G., Penzias, A. S., and Jenkins, E. B. 1982, Ap. J., 254, 100.
Watson, W. D., and Salpeter, E. E. 1972, Ap. J., 174, 321.
Williams, D. A., and Hartquist, T. W. 1984, Mon. Not. R. Soc., 210, 41.
Whittet, D. C. B., Bode, M. F., Longmore, A. J., Baines, D. W. T., and Evans, A. 1983, Nature. 303, 218.
Wootten, A., Evans, N. J., Snell, R., and Vanden Bout, P. 1978, Ap. J., (Letters). 225, L143.
Wynn-Williams, C. G., Genzel, R., Becklin, E. E., and Downes, D. 1984, Ap. J., 281, 172.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 D. Reidel Publishing Company
About this paper
Cite this paper
Prasad, S.S., Tarafdar, S.P., Villere, K.R., Huntress, W.T. (1987). Chemical Evolution of Molecular Clouds. In: Hollenbach, D.J., Thronson, H.A. (eds) Interstellar Processes. Astrophysics and Space Science Library, vol 134. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3861-8_23
Download citation
DOI: https://doi.org/10.1007/978-94-009-3861-8_23
Publisher Name: Springer, Dordrecht
Print ISBN: 978-90-277-2485-4
Online ISBN: 978-94-009-3861-8
eBook Packages: Springer Book Archive