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Rotation Selective Intramolecular Vibrational Relaxation in the S1-State of Benzene

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Book cover Stochasticity and Intramolecular Redistribution of Energy

Part of the book series: NATO ASI Series ((ASIC,volume 200))

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Abstract

An oscillator carrying (light) rovibronic state is coupled to symmetry like (dark) states via anharmonic interactions and to (dark) states with different symmetry via combined anharmonic and Coriolis interactions. For the model of equally spaced but randomly distributed dark states analytic expressions for the width of the light state are derived. As an example the linewidth of the 14112-state of benzene is discussed as function of the rotational quantum numbers J and K.

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References

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Author information

Authors and Affiliations

  1. Technische Universität München, Institut für theoretische Physik T38, D-8046, Garching, Fed. Rep. Germany

    S. F. Fischer & W. Dietz

Authors
  1. S. F. Fischer
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  2. W. Dietz
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Editor information

Editors and Affiliations

  1. Laboratoire de Photophysique Moléculaire du CNRS, Orsay, France

    R. Lefebvre

  2. Department of Chemistry, University of Rochester, New York, USA

    S. Mukamel

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© 1987 D. Reidel Publishing Company

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Fischer, S.F., Dietz, W. (1987). Rotation Selective Intramolecular Vibrational Relaxation in the S1-State of Benzene. In: Lefebvre, R., Mukamel, S. (eds) Stochasticity and Intramolecular Redistribution of Energy. NATO ASI Series, vol 200. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3837-3_15

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  • DOI: https://doi.org/10.1007/978-94-009-3837-3_15

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8208-2

  • Online ISBN: 978-94-009-3837-3

  • eBook Packages: Springer Book Archive

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