Abstract
We report here the observation of excited states In van der Waals complexes whose dissociation lead to electronic relaxation (Hg N2) or to chemical reaction (Hg H2). The spectroscopic observation of those complexes gives some new information on the intermediate states responsible for relaxation or chemical reaction. This kind of exeriment is a selective way of observing the collision complex in relaxation and reactive processes.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
D.H. Levy, Photoselective Chemistry Advances in Chemical physics XLVII 1981, page 323.
a) C. Jouvet, B. Soep, J. Chem. Phys. 75 166 (1981)
C. Jouvet, B. Soep, J. Chem. Phys. 80 2229 (1984)
A. Gato, M. Eujii, N. Mikami, M. Ito J. Phys. Chem. 90 2370 (1986).
a) C. Jouvet, B. Soep, Chem, Phys. Lett. 96 426 (1983)
W.H. Breckenridge, C. Jouvet, B. Soep J. Chem. Phys. 84 1443 (1986).
J. A. Kolts and D. W. Setser, page 202, Reactive intermediates in gas phase. Ed. D. W. Setser - Academic press 1979.
J. Pitre, K. Hammond, L. Krause Can. J. Phys. 6 2101 (1972).
E. Samson, Phys. Rev. 40 940 (1932).
H. Horiguchi, S. Tsuchiya Bull. Chem. Soc. Japan 44 1213 (1971).
A. B. Callear, P.M. Wood Trans. Faraday Soc. 67 272 et 598 (1971).
H. Horigushi, S. Tsuchiya Bull. Chem. Soc. Japan 50 1657 et 1661 (1977).
a) E. E. Nikitin, Theorie of elementary atom and moleculars process in gases. Clarendon press. Oxford 1974.
H. Horiguchi and S. Tsuchiya Jour, of Chem. Soc. Faraday Trans. l, 71 1164 (1975).
a) K. Fuke, T. Saito, K. Kaya J. Chem. Phys. 81 2591 (1984).
M.C. Duval, C. Jouvet et B. Soep Chem. Phys. Lett. 119 317 (1985).
S. Holmgrem, M. Waldman, W. Klemperer J. Chem. Phys. 67 4414 (1977) and ret. therein.
a) R. E. Smalley, P. A. Auerback, P.S.H. Fitch, O.H. Levy and L. Wharton J. Chem. Phys. 66 3778 (1977).
G. Henderson, G. Ewing, Ar-Og J. Chem. Phys. 59 2280 (1973).
G. Henderson, G. Ewing, Ar-Ng Mot. Phys. 27 903 (1973).
G. Henderson, G. Ewing, Ar-Ng Mot. Phys. 27 903 (1973).
C. Jouvet, A. Beswick To be published.
A. C. Vikis, D.J. Le Roy Can. J. Phys. 51 1207 (1973) and Ref. therein.
W. H. Breckenridge, M.C. Duval, C. Jouvet, B. Soep Journal de Chimie Physique. In press.
A. B. Callear, J.C. Mc Gurk J. of Chem. Society Faraday Trans II, 62 289 (1972).
A. Bernier, P. Millie To be published.
W. H. Breckenridge, In reaction In small transient species Ed. by A. Fontigne, M. A. H. Glyne (Academic London 1983) and ref. therein.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 D. Reidel Publishing Company
About this chapter
Cite this chapter
Breckenridge, W.H., Benoist d’Azy, O., Duval, M.C., Jouvet, C., Soep, B. (1987). Excited Van Der Waals Complexes as a Probe for Intermediate States in Collisions. In: Lefebvre, R., Mukamel, S. (eds) Stochasticity and Intramolecular Redistribution of Energy. NATO ASI Series, vol 200. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3837-3_11
Download citation
DOI: https://doi.org/10.1007/978-94-009-3837-3_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8208-2
Online ISBN: 978-94-009-3837-3
eBook Packages: Springer Book Archive