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Fluid Phase Separations in Polymerizing Systems at Elevated Pressures

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Book cover High Pressure Chemistry and Biochemistry

Part of the book series: NATO ASI Series ((ASIC,volume 197))

Abstract

Phase separations that tend to accompany polymerization reactions are reviewed from a classic thermodynamic standpoint. Both lower and upper critical miscibility may occur and are details of the same phenomenon, partial miscibility in its dependence on pressure and temperature. Since pressure plays a marked role, we discuss fluid phase equilibria in terms of a mean-field lattice gas equation of state capable of adequate descriptions of observed phenomena and of predictions of the influence of pressure, molar mass and polymer chain structure characteristics such as chain branching.

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Author information

Authors and Affiliations

  1. DSM Research & Patents, PO Box 18, 6160 MD, Geleen, Netherlands

    L. A. Kleintjens

  2. Chemistry Department, University of Antwerp, B-2610, Wilrijk, Belgium

    R. Van der Haegen & R. Koningsveld

Authors
  1. L. A. Kleintjens
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  2. R. Van der Haegen
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  3. R. Koningsveld
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Editor information

Editors and Affiliations

  1. Institute for Physical and Theoretical Chemistry, Johann Wolfgang Goethe University, Frankfurt am Main, Germany

    R. van Eldik

  2. Department of Chemistry, University of Illinois, Urbana, Illinois, USA

    J. Jonas

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© 1987 D. Reidel Publishing Company

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Kleintjens, L.A., Van der Haegen, R., Koningsveld, R. (1987). Fluid Phase Separations in Polymerizing Systems at Elevated Pressures. In: van Eldik, R., Jonas, J. (eds) High Pressure Chemistry and Biochemistry. NATO ASI Series, vol 197. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3827-4_7

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  • DOI: https://doi.org/10.1007/978-94-009-3827-4_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-8203-7

  • Online ISBN: 978-94-009-3827-4

  • eBook Packages: Springer Book Archive

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