Abstract
The Flowing Afterglow Technique (Ferguson et al., 1969) provided the first chemically versatile method for measuring ion-molecule reactions at room temperature, later extended from 80K to 900K (Lindinger et al., 1974). Positive and negative ions of great variety can be studied, including metal ions, heavily solvated ions, doubly charged positive ions, electronically excited ions and now vibrationally excited ions. A variety of neutrals including H, O, N atoms, OH radicals O3, H2O2, HNO3, H2SO4 and N2O5 have been reacted with ions in the Flowing Afterglow. Reactions of ions with vibrationally excited N2 (Schmeltekopf et al., 1968) and H2 (Jones et al., 1986) have been carried out. The chemical versatility is unmatched by any other technique.
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Ferguson, E.E. (1987). Production, Quenching and Reaction of Vibrationally Excited Ions in Collisions with Neutrals in Drift Tubes. In: Ausloos, P., Lias, S.G. (eds) Structure/Reactivity and Thermochemistry of Ions. NATO ASI Series, vol 193. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3787-1_5
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DOI: https://doi.org/10.1007/978-94-009-3787-1_5
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