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Proton Transfer Reactions of Anions

  • Charles H. DePuy
  • Veronica M. Bierbaum
Part of the NATO ASI Series book series (ASIC, volume 193)

Abstract

Proton transfer reactions are, obviously, among the most important in all of chemistry, and they play a key role in the chemistry of gas phase anions. Their primary importance is in their use in the formation of anions when a strong base, e.g. HO, reacts with an acid. Endothermic proton transfers are also extremely important in gas phase anion chemistry, especially that of carbanions, for these can lead to hydrogen-deuterium exchange reactions and these reactions can, in turn, give vital information about ion structure and reaction mechanism. Simple and complex H/D exchange is discussed in terms of mechanism and energetics, and examples are given of its use in deducing ion structure.

Keywords

Proton Transfer Reaction Hydrogen Exchange Proton Abstraction Hide Exchange Flowing Afterglow 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Copyright information

© D. Reidel Publishing Company, Dordrecht, Holland 1987

Authors and Affiliations

  • Charles H. DePuy
    • 1
  • Veronica M. Bierbaum
    • 1
  1. 1.Department of Chemistry and BiochemistryUniversity of ColoradoBoulderUSA

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