Abstract
Proton transfer reactions are, obviously, among the most important in all of chemistry, and they play a key role in the chemistry of gas phase anions. Their primary importance is in their use in the formation of anions when a strong base, e.g. HO−, reacts with an acid. Endothermic proton transfers are also extremely important in gas phase anion chemistry, especially that of carbanions, for these can lead to hydrogen-deuterium exchange reactions and these reactions can, in turn, give vital information about ion structure and reaction mechanism. Simple and complex H/D exchange is discussed in terms of mechanism and energetics, and examples are given of its use in deducing ion structure.
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© 1987 D. Reidel Publishing Company, Dordrecht, Holland
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DePuy, C.H., Bierbaum, V.M. (1987). Proton Transfer Reactions of Anions. In: Ausloos, P., Lias, S.G. (eds) Structure/Reactivity and Thermochemistry of Ions. NATO ASI Series, vol 193. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3787-1_15
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DOI: https://doi.org/10.1007/978-94-009-3787-1_15
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