Abstract
The models discussed in Chapter A3 are equilibrium models. They assume that the equilibrium position of an adsorption reaction has been reached and that no further reaction occurs. When considering the rate of the reaction, neither of these assumptions is appropriate. At least for short periods of reaction, the approach to equilibrium must be considered; and for long periods some second reaction may follow adsorption. Thus a model for the rate of the reaction may have two rate components — one to describe the rate of the adsorption process and one to describe a possible second reaction.
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References
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© 1987 Martinus Nijhoff Publishers, Dordrecht
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Barrow, N.J. (1987). The rate of reaction with oxides. In: Reactions with Variable-Charge Soils. Developments in Plant and Soil Sciences, vol 31. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3667-6_4
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DOI: https://doi.org/10.1007/978-94-009-3667-6_4
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-8141-2
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