Synopsis
Na-Ca and Na-Mg binary exchange isotherms at 25°C have been determined in samples of zeolite A and X gels as a function of crystallization time which varied from 0 to 14 hours for zeolite A and 0–24 hours for zeolite X. Increasing crystallinity in the zeolite A samples has been shown to decrease the selectivity for the divalent ion. In the case of the zeolite X samples, the selectivity for the divalent ion first decreases with increasing crystallization time but a reversal in this selectivity occurs with crystalline zeolite X.
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References
Savitsky, A.C. Soap Cosmet. Chem. Spec., No. 3, vol. 53, 29, 1977.
Kühl, G.H. and Sherry, H.S. “Proc. Fifth Int. Conf. Zeolites” (Ed. L.V.C. Rees) Heyden, London, p. 813, 1980.
Barri, S.A.I, and Rees, L.V.C. J. Chromatog., vol. 201, 21, 1980.
Rees, L.V.C. “Proc. Sixth Int. Conf. Zeolites” (Ed. D. Olson and A. Bisio) Butterworths Scientific, Guildford, p. 626, 1984.
Drummond, D., DeJonge, A. and Rees, L.V.C. J. Phys. Chem., vol. 87, 1967, 1983.
Meise, F. and Schwochow, F.E. Molecular Sieves, A.C.S. Adv. in Chem., Ser. 121, 209, 1973.
Breck, D.W. “Zeolite Molecular Sieves”, John Wiley, p. 274, 1973.
Jansen, J.C., Van der Gaag, F.J. and Van Bekkum, H., Zeolites, vol. 4, 369, 1984.
Coudurier, G., Naccache, C. and Vedrine, J.C., J. Chem. Soc. Chem. Commun. 1413, 1982.
Tsurata, Y., Satoh, T., Yoshida, T., “Proc. Seventh Int. Conf. Zeolites” (Ed. Y. Murakami, A. Iijima and J.W. Ward) Kodansha, Elsevier, Tokyo, p. 1001, 1986.
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© 1987 Elsevier Applied Science Publishers Ltd
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Mole, V.C., Rees, L.V.C. (1987). Ion Exchange in Zeolites A and X Precursor Gels as a Function of Crystallization Time. In: Williams, P.A., Hudson, M.J. (eds) Recent Developments in Ion Exchange. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3449-8_26
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DOI: https://doi.org/10.1007/978-94-009-3449-8_26
Publisher Name: Springer, Dordrecht
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