Abstract
Chemical analyses were performed on 387 sequential precipitation samples, both rain and snow, collected at Brookhaven National Laboratory, Long Island, New York, on 96 different days during the period from October 1983 to June 1985. The collection time for each individual sample was typically 30 min. The chemical species determined and the volume-weighted average and maximum concentrations (in parentheses) in units of μM were: H202:7(120), H2CO:6(60), H+:5l(500), NO3-: 30(350), S04 2-:25(270), NH4 +: 18(250), Ca2+:3(48), Na+:32(400), and C1-:37(380). A strong seasonal dependence was observed for H202 concentration, the maximum concentration in summer (120 μM) being 6 times greater than in winter. In addition, H202 concentration also exhibited a strong diurnal variation, with a maximum peaking in the afternoon and a minimum after midnight. These observations suggest that the production of H202 may be governed by photochemical activity. Nitrate concentration also displayed a strong diurnal variation, having a maximum around noon, but did not show a seasonal dependence. Relationships between various species and their possible sources are briefly discussed.
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References
Bufalini, J.J., Lancaster, H.T., Namie, G.R., and Gay, B.W., Jr., J. Environ. Sci. Health, A14, 135. Calvert, J.G., ed., 1984, SO 2 and NO 2 oxidation mechanisms: Atmospheric considerations, Butterworth, Boston.
Gaffney, J.S. and Senum, G.I., 1984, Peroxides, peracids, aldehydes and PANs and their links to natural and anthropogenic organic sources, in Proceedings of the Conference on Gas-Liquid Chemistry of Natural Waters, Brookhaven National Laboratory, Upton, New York, April, Paper No. 5.
Guilbault, G.G., Brignac, P., and Juneau, M., 1968, Anal. Chem., 40, 1256.
Hanst, P.L. and Gay, B. Jr., 1983, Atmos. Environ., 17, 2259.
Hoffmann, M.R. and Edwards, J.O., 1975, J. Phys. Chem., 79, 2096.
Heikes, B.G., Lazrus, A.L., and Kok, G.L., 1985, Measurements of H2O2 in the lower troposphere, presented at the 17th International Symposium on Free Radicals, Granby, Colorado, August 18–23, 1985.
Kelly, T.J., Daum, P.H., and Schwartz, S.E., 1985, J. Geophys. Res. 90, 7861.
Kleinman, L.I., 1984, Atmospheric formation of gas phase H2O2 and other oxidants in the eastern U.S., Report BNL–33367, Brookhaven National Laboratory, Upton, NY.
Kuntz, R. Lonneman, W., Namie, G., and Hull, L.A., 1980, Anal. Letts. 13, 1409.
Martin, L.R. and Damschen, D.E., 1981,, 15, 1615.
National Research Council, 1983, Acid deposition: Atmospheric processes in Eastern Northern America, Environmental Studies Board, National Academy Press, Washington, DC.
National Academy of Sciences, 1976, Vapor-Phase Organic Pollutants, Committee on Medical and Biological Effects of Environmental Pollutants, Washington, DC.
Raynor, G.S. and Hayes, J.V., 1983, Differential rain and snow scavenging efficiency implied by ionic concentration differences in winter precipitation. In Precipitation, Scavenging, Dry Deposition, and Resuspension, Pruppacher, H.R., Semonin, R.G., and Slinn, W.G.N., eds. Elsevier, New York, 1983.
Raynor, G.S. and Hayes, J.V., 1984, The sequential precipitation chemistry sampling program at Brookhaven National Laboratory with an analytical summary of 1976–1982 data. Brookhaven National Laboratory report, No. 51819.
Richards, L.W., 1983, Atmos. Environ.,17, 397.
Tanner, R.I., and Meng, Z., 1984, Environ. Sci. Technol.,18, 723.
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© 1986 Springer Science+Business Media Dordrecht
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Lee, YN., Shen, J., Klotz, P.J. (1986). Chemical Composition of Precipitation at Long Island, NY. In: Martin, H.C. (eds) Acidic Precipitation. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3385-9_13
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DOI: https://doi.org/10.1007/978-94-009-3385-9_13
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