Abstract
The occurrence of geometric isomers of type 1 where X and Y may be C, N or O is well documented. [1–8] Recent work in our laboratory has focussed on the occurrence of E and Z isomers of 1 and their role in the stereochemistry of anionic polymerization of vinyl monomers CH2CHC(Y)X where X = 0 or N and Y = 0, N or C.
This is a preview of subscription content, log in via an institution.
Buying options
Tax calculation will be finalised at checkout
Purchases are for personal use only
Learn about institutional subscriptionsPreview
Unable to display preview. Download preview PDF.
References
H. O. House, Modern Synthetic Reactions, Benjamin, New York, 1965
R. E. Ireland, R. H. Mueller, A. K. Willard, J. Am. Chem. Soc. 98, 2868 (1976).
A.I. Meyers, E.S. Snyders, J.J.H. Ackerman, J. Am. Chem.Soc. 100, 8189 (1978).
M.A Hooler, D.E. Bergbreiter, M.Newcomb, J. Am. Chem.Soc. 100, 8182 (1978).
A.I. Meyers, D.R. Williams and M.Druelinger, J. Am. Chem. Soc. 98, 3032 (1976).
T. E Hogen-Esch and W. L. Jenkins, J. Am. Chem. Soc. 103, 3666 (1981)
L. Vancea and S. Bywater, Macromolecules 14, 1321 (1981).
I. M. Khan and T. E. Hogen-Esch, Makromol. Chem., Rapid Commun. 4, 569 (1983)
I. M. Khan, Ph.D. Thesis, University of Florida, 1984.
W. R. Hertler, Private Communication.
F. A. Bovey and L. W. Jelinski, “Chain Structure and Conformation of Macro- molecules”, Academic Press, 1982, Chapter 3.
B. D. Coleman and T. G. Fox, J. Am. Chem. Soc. 85, 1241 (1963).
A. Soum and T. E. Hogen-Esch, Macromolecules 18(4), 690 (1985).
I. M. Khan and T. E. Hogen-Esch, Polymer Preprints, 26(2), 273 (1985).
B. D. Coleman and T. G. Fox, J. Chem. Phys. 38, 1065(1963).
H. L. Frisch, F. A. Bovey and C. L. Heatly, Macromolecules 1 533 (1968).
F. A. Bovey and G. U. D. Tiers, J. Polym. Sci. 44, 173 (1960).
L. F. Johnson, F. Heatley and F. A. Bovey, Macromolcules 3, 175 (1970).
T. Suzuki, O. Yamada, Y. Watanabe and Y. Takigame, Polym. J. 14, 343 (1982).
Y. Inoue, A. Nishioka and R. Chujo, Polym. J. 4, 535 (1971).
T. Suzuki and H. F. Harwood, Polymer Preprints 16, 638 (1975).
L. Vancea and S. Bywater, Macromolecules 14, 1776 (1982).
S. S. Huang, A. H. Soum and T. E. Hogen-Esch, J. Polym. Sci. (Polym. Letters), 21, 559 (1983).
A. Soum and T. E. Hogen-Esch, Macromolecules 18(4), 690 (1985).
I. M. Khan and T. E. Hogen-Esch, Macromolecules, Submitted.
B. C. Bell, Ph.D. Thesis, University of Florida, 1986.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1987 Elsevier Science Publishing Co., Inc.
About this paper
Cite this paper
Khan, I.M., Hogen-Esch, T.E. (1987). Role of E-and Z-Carbanions in the Stereochemistry of Anionic Vinyl Polymerization. In: Hogen-Esch, T.E., Smid, J. (eds) Recent Advances in Anionic Polymerization. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3175-6_18
Download citation
DOI: https://doi.org/10.1007/978-94-009-3175-6_18
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7924-2
Online ISBN: 978-94-009-3175-6
eBook Packages: Springer Book Archive