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Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy pp 55–92Cite as

Bicyclo[2.2.1]heptanes

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Abstract

Nomenclature for this system is straightforward, with exo and endo referring to the orientation of substituents on carbons 2, 3, 5, and 6 relative to C-7, and syn and anti used for C-7 substituents. For 7-monosubstituted compounds, the numbering is defined so that the substituent will be syn. Relatively unusual dihedral angles are found about most of the bonds and thus caution should be exercised in applying Δδ effects observed here to other systems.

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Whitesell, J.K., Minton, M.A. (1987). Bicyclo[2.2.1]heptanes. In: Stereochemical Analysis of Alicyclic Compounds by C-13 NMR Spectroscopy. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3161-9_6

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