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Thermodynamic Properties

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The Chemistry of the Actinide Elements

Abstract

The necessity of obtaining accurate thermodynamic quantities for the actinide elements and their compounds was recognized at the outset of the Manhattan Project, when a dedicated team of scientists and engineers initiated the program to exploit nuclear energy for military purposes. Since the end of World War II, both fundamental and applied objectives have motivated a great deal of further study of actinide thermodynamics. This chapter brings together many research papers and critical reviews on this subject. It also seeks to assess, to systematize, and to predict important properties of the actinide elements, ions, and compounds, especially for species in which there is significant interest and for which there is experimental basis for the prediction.

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References

  1. Seaborg. G. T, Katz, J. J., Manning. W. M. (eds) (1949) The Transuranium Elements: Research Papers, Natl Nucl. En. Ser., Div. IV, 14B, McGraw-Hill, New York.

    Google Scholar 

  2. Rossini. F. D., Wagman, D. D., Evans, W. H., Levine, S., Jaffe, I. (1952) Selected Values of Chemical Thermodynamic Properties, US Natl Bur. Stand. Circ. 500, US Govt Printing Office, Washington, DC.

    Google Scholar 

  3. Latimer, W. M. (1952) Oxidation Potentials, 2nd edn, Prentice-Hall, New York.

    Google Scholar 

  4. Rand, M. H., Kubaschewski, O. (1963) The Thermochemical Properties of Uranium Compounds, Interscience, New York.

    Google Scholar 

  5. IAEA (1965) Thermodynamic and Transport Properties of Uranium Dioxide and Related Phases, Technical Reports Series no. 39, International Atomic Energy Agency, Vienna.

    Google Scholar 

  6. IAEA (1967) The Plutonium-Oxygen and Uranium-Plutonium-Oxygen Systems: A Thermochemical Assessment, Technical Reports Scries no. 79, International Atomic Energy Agency, Vienna.

    Google Scholar 

  7. Rand, M. H. (1968) Technical Panel on Uranium and Plutonium Carbides, International Atomic Energy Agency, Vienna.

    Google Scholar 

  8. Rand, M. H. (1966) At. Energy Rev., 4, Spec. Issue no. 1, 7–51.

    CAS  Google Scholar 

  9. Oetting, F. L. (1967) Chem. Rev., 67, 261–97.

    CAS  Google Scholar 

  10. Krestov, G. A. (1972) Thermochemistry of Compounds of Rare-Earth and Actinide Elements, Atomizdat, Moscow (English translation: AF.C-tr-7505, National Technical Information Service, Springfield. VA 22151 ).

    Google Scholar 

  11. Rand. M. H. (1975) At. Energy Rev., Spec. Issue no. 5, 7–85.

    Google Scholar 

  12. Wagman, D. D., Evans, W. H., Parker, V. B., Schumm, R. H., Nuttall, R. L. (1981) US. Natl. Bur. Stand. Tech. Note 270-8, US Govt Printing Office. Washington. DC; (1982) J. Phys. Chem. Ref. Data, 11, Suppl. 2.

    Google Scholar 

  13. Glushko, V. P., Medvedev, V. A., Bergman, G. A., Gurvich, L. W., Vorob’ev, A. F., Vasil’ev, V. P., Kolesov, V. P., Yungman, V. S., Reznutskij, L. R., Baibuz, V. F., Gal’chenko, G. L., Yatzimirskij, K. B. (1978) Thermodynamic Constants of Substances, Academy of Science Publishing House, Moscow.

    Google Scholar 

  14. Oetting, F. L., R., M. H., Ackermann, R. J. (1976) The Chemical Thermodynamics of Actinide Elements and Compounds, part 1, The Actinide Elements, STI/PUB/424/1, International Atomic Energy Agency. Vienna.

    Google Scholar 

  15. Fuger, J., Oetting, F. L. (1976) The Chemical Thermodynamics of Actinide Elements and Compounds, part 2, The Actinide Aqueous Ions, STI/PUB/424/2, International Atomic Energy Agency, Vienna.

    Google Scholar 

  16. Cordfunke, E. H. P., O’Hare, P. A. G. (1978) The Chemical Thermodynamics of Actinide Elements and Compounds, part 3, Miscellaneous Actinide Compounds, ST1/PUB/424/3, International Atomic Energy Agency, Vienna.

    Google Scholar 

  17. Gronvold, F., Drowart, J., Westrum, E. F., Jr (1984) The Chemical Thermodynamics of Actinide Elements and Compounds, part 4, The Actinide Chalcogenides (Excluding Oxides), STI/PUB/424/4. International Atomic Energy Agency, Vienna.

    Google Scholar 

  18. Chiotti, P., Akhachinskij, V. V., Ansara, I., Rand, M. H. (1981) The Chemical Thermodynamics of Actinide Elements and Compounds, part 5, The Actinide Binary Alloys, STI/PUB/424/5, International Atomic Energy Agency, Vienna.

    Google Scholar 

  19. Holley, C. E., R., M. H., Storms, E. K. (1984) The Chemical Thermodynamics of Actinide Elements and Compounds, part 6, The Actinide Carbides, STI/PUB/424/6, International Atomic Energy Agency, Vienna.

    Google Scholar 

  20. Fuger. J., Parker, V. B., Hubbard, W. N., Oetting, F. L. (1983) The Chemical Thermodynamics of Actinide Elements and Compounds, part 8, The Actinide Halides, STI/PUB/424/8, International Atomic Energy Agency, Vienna.

    Google Scholar 

  21. Flotow, H. E., Haschke, J. M., Yamauchi, S. (1984) The Chemical Thermodynamics of Actinide Elements and Compounds, part 9, The Actinide Hydrides, STI/PUB/424/9, International Atomic Energy Agency, Vienna.

    Google Scholar 

  22. Kleinschmidt, P. D., Ward, J. W., Haire, R. G. (1983) Proc. II Symp. on High Temperature Materials Chemistry (eds Z. Munir., D. Cubiciotti), Electrochemical Society, Pennington, NJ, pp. 23–31.

    Google Scholar 

  23. Stewart, G. R. (1983) Rev. Sci. Instrum., 54, 1–11.

    CAS  Google Scholar 

  24. Hultgren, R., Desai, P. D., Hawkins, D. T., Gleiscr, M., Kelley, K. K., Wagman, D. D. (1973) Selected Values of the Thermodynamic Properties of the Elements, American Society for Metals, Metals Park, Ohio.

    Google Scholar 

  25. Hultgren, R., Desai, P. D., Hawkins, D. T., Gleiser, M., Kelley, K. K., Wagman, D. D. (1973) Selected Values of the Thermodynamic Properties of the Elements, American Society for Metals, Metals Park, Ohio.

    Google Scholar 

  26. Nugent, L. J. (1975) J. Inorg. Nucl. Chem., 37, 1767–70.

    CAS  Google Scholar 

  27. David, F., Samhoun, K., Guillaumont, R., Edelstein, N. (1978) J. Inorg. Nucl. Chem., 40. 69–74.

    CAS  Google Scholar 

  28. Nugent, L. J., Baybarz, R. D., Burnett, J. L., Ryan, J. L. (1973) J. Phys.Chem., 77, 1528–39.

    CAS  Google Scholar 

  29. Nugent, L. J., Burnett, J. L., Morss, L. R. (1973) J. Chem. Thermodyn., 5. 665–78.

    CAS  Google Scholar 

  30. Fournier, J. M. (1976) J. Phys. Chem. Solids, 37, 235–44.

    CAS  Google Scholar 

  31. Hubener, S., Zvara, I. (1982) Radiochim. Acta, 31, 89–94.

    Google Scholar 

  32. Ward, J. W., Ohse, R. W., Reul, R. (1975) J. Chem. Phys., 62, 2366 –72.

    Google Scholar 

  33. Ward, J. W. and Hill. H. H. (1976) in Heavy Element Properties (eds W. Muller., H. Blank), North-Holland, Amsterdam, pp. 65–79.

    Google Scholar 

  34. Ward, J. W., Kleinschmidt, P. D., Haire, R. G. (1979) J. Physique, 40, Colloq. C4. 233–5.

    Google Scholar 

  35. Ward, J. W., Kleinschmidt. P. D.. and Haire, R. G. (1979) J. Chem. Phys., 71, 3920–5.

    CAS  Google Scholar 

  36. Ward, J. W., Klcinschmidt, P. D., Haire, R. G., and Brown, D. (1980) in Lanthanide and Actinide Chemistry and Spectroscopy (ed. N. Edelstein), American Chemical Society, Washington, DC, pp. 199–220.

    Google Scholar 

  37. Ward, J. W., Kleinschmidt, P. D., Haire, R. G. (1982) J. Chem. Phys., 77, 1464–8.

    CAS  Google Scholar 

  38. Ward, J. W. (1983) J. Less Common Metals, 93, 279–92.

    CAS  Google Scholar 

  39. Morss, L. R., Fuger, J. (1981) J. Inorg. Nucl. Chem., 43, 2059–64.

    CAS  Google Scholar 

  40. Morss, L. R. (1983) J. Less Common Metals, 93, 301–21.

    CAS  Google Scholar 

  41. Morss, L. R. (1983) J. Less Common Metals, 93, 301–21.

    CAS  Google Scholar 

  42. Morss, L. R. (1976) Chem. Rev, 76, 827–41.

    CAS  Google Scholar 

  43. Morss, L. R., McCue, M. C. (1976) J. Chem. Eng. Data. 21, 337–41.

    CAS  Google Scholar 

  44. Shannon. R. D. (1976) Acta Crystallogr. A, 32. 751–67.

    Google Scholar 

  45. Lebedev. I. A. (1981) Radiokhimiya, 23. 12–14.

    CAS  Google Scholar 

  46. Silva, R. J., McDowell, W. J., Keller, O. L., Jr., Tarrant, J. R. (1974) Inorg. Chem, 13, 2233–7.

    CAS  Google Scholar 

  47. Martinot, L. (1978) in Encyclopedia of Electrochemistry of the Elements, vol. VIII (ed. A. J. Bard), Marcel Dekker, New York, pp. 149–206.

    Google Scholar 

  48. Martinot, L., Fuger, J. (1985) in Standard Potentials in Aqueous Solution (eds A. J. Bard, R. Parsons., J. Jordan), Marcel Dekker, New York, chap. 21.

    Google Scholar 

  49. Maly, J. (1967) Inorg. Nucl. Chem. Lett, 3, 373–81.

    CAS  Google Scholar 

  50. Maly, J. Cunningham, B B. (1967) Inorg. Nucl. Chem. Lett, 3. 445–51.

    CAS  Google Scholar 

  51. Maly, J., Sikkeland, T., Silva, R., Ghiorso, A. (1968) Science, 160. 1114–15.

    CAS  Google Scholar 

  52. Mikheev, N. B. (1983) Radiochim. Acta, 32. 69–80.

    CAS  Google Scholar 

  53. Rai, D., Strickert, R. G., Moore, D. A., Ryan, J. L. (1983) Radiochim. Acta, 33, 201–6.

    CAS  Google Scholar 

  54. Dillin. D R.. Milligan, W. O., Williams, R. J. (1973) J. Appl. Crystallogr, 6. 492–4.

    CAS  Google Scholar 

  55. Gmelin Handbuch der Anorganischen Chemie, Verlag Chemie, Weinheim, System- Nummer 39. Scltcncrdclcmente, part C2 (1974).

    Google Scholar 

  56. Aksel’rud, N. V. (1963) Russ. Chem. Rev., 32. 353–66.

    Google Scholar 

  57. Baes, C. F.. Jr., Mesmer. R. E. (1976) The Hydrolysis of Cations, Wiley- Interscience, New York.

    Google Scholar 

  58. Ziv. D. M., Shestakova, I. A. (1965) Radiokhimiya, 7. 175–87.

    CAS  Google Scholar 

  59. Moskvin, A. I. (1971) Radiokhimiya, 13. 293–5.

    CAS  Google Scholar 

  60. In ref. 55, part C3 (1976).

    Google Scholar 

  61. Ahrland, S., Liljenzin, J., Rydberg. J. (1973) in Comprehensive Inorganic Chemistry, vol. V (ed. A. F. Trotman-Dickinson), Pergamon, New York, pp. 465–635.

    Google Scholar 

  62. Allard. B. (1982) in Actinides in Perspective (ed. N. Edelstein), Pergamon, Oxford, pp. 553–80.

    Google Scholar 

  63. Allard. B., Rydberg. J. (1984) in Plutonium Chemistry (eds W. T. Carnall., G. R. Choppin), (Am. Chem. Soc. Symp. Ser. no. 216). American Chemical Society, Washington DC, pp. 275–95.

    Google Scholar 

  64. Allard, B., Olofsson, U., Torstenfelt, B. (1984) Inorg. Chim. Acta, 94, 205–21.

    CAS  Google Scholar 

  65. Silver, G. L. (1981) J. lnorg. Nucl. Chem., 43, 2997–9.

    CAS  Google Scholar 

  66. Hobart, D. E., Samhoun, K., Peterson. J. R. (1982) Radiochim. Acta, 31, 139–45.

    CAS  Google Scholar 

  67. Hobart. D. E.. Varlashkin. P. G., Samhoun, K., Haire, R. G., Peterson, J. R. (1983) Rev. Chim. Miner, 20. 817–27.

    CAS  Google Scholar 

  68. Wester, D. W., Sullivan, J. C. (1980) Inorg. Chem., 19, 2838–40; (1981) J. lnorg. Nucl. Chem., 43, 2919–23; (1983) Radiochim. Radioanal. Lett., 57, 35–42.

    Google Scholar 

  69. Gruen, D. M. (1976) Proc. Int. Symp. on Molten Salts, Washington DC, pp. 204IT.

    Google Scholar 

  70. Gmelin Handbuch der Anorganischen Chemie, Suppl. Ser., Uran, Springer Verlag, Berlin, part Dl (1984), chaps 2 and 4.

    Google Scholar 

  71. Lemire, R. J., Tremaine, P. R. (1980) J. Chem. Eng. Data, 25. 361–70.

    CAS  Google Scholar 

  72. Criss, C. M., Cobble. R. W. (1964) J. Am. Chem. Soc., 86. 5385–90, 5390-93.

    CAS  Google Scholar 

  73. Mayrath, J. E., Wood, R. H. (1982) J. Chem. Thermodyn., 14, 15–26.

    CAS  Google Scholar 

  74. Busey, R. H., Holmes, H. F., Mesmer. R. E. (1984) J. Chem. Thermodyn., 16. 343–72.

    CAS  Google Scholar 

  75. Jekel, E. C., Criss, C. M., Cobble. J. W. (1964) J. Am. Chem. Soc, 86. 5404–7.

    CAS  Google Scholar 

  76. Morss, L. R. (1972) unpublished.

    Google Scholar 

  77. Lemire, R. J. (1984) Atomic Energy of Canada Ltd Report AECL-7817. Whiteshell Nuclear Research Establishment.

    Google Scholar 

  78. Pitzer. K. S. (1977) Acc. Chem. Res., 10, 371–7.

    CAS  Google Scholar 

  79. Helgeson. H. C. (1982) in Chemistry and Geochemistry of Solutions at High Temperatures and Pressures (eds D. Rickard., F. E. Wiekman), Pergamon, Oxford; (1985) Pure Appl. Chem., 57, 31–44.

    Google Scholar 

  80. Phillips, S. L. (1984) Lawrence Berkeley Laboratory Report LBL-17886.

    Google Scholar 

  81. Kosyakov, V. N., Timofeev, G. A., Erin. I. A., Kopytov, V. V., Andreev, V. J. (1977) Radiokhimiya, 19, 82–4.

    CAS  Google Scholar 

  82. Volkov, Yu. F., Visyashcheva, G. I., Tomilin, S. V., Kapshukov, I.I., Rykov, A. G. (1981) Radiokhimiya, 23, 243–7.

    CAS  Google Scholar 

  83. Cleveland. J. M. (1979) in Chemical Modeling in Aqueous Systems (ed. E. A. Jenne), (Am. Chcm. Soc. Symp. Ser. 93). Washington. DC. pp. 321–38.

    Google Scholar 

  84. Cleveland. J. M. (1979) in Chemical Modeling in Aqueous Systems (ed. E. A. Jenne), (Am. Chcm. Soc. Symp. Ser. 93). Washington. DC. pp. 321–38.

    Google Scholar 

  85. Sugar, J. (1973) J. Chem. Phys 59. 788–91; (1974) J. Chem. Phys 60, 4103.

    Google Scholar 

  86. Martin, W. C., Hagan, L., Reader, J., Sugar, J. (1974) J. Phys. Chem. Ref. Data, 3, 771–80.

    CAS  Google Scholar 

  87. Carlson. T. A., Nestor, C. W, Wasserman, N., McDowell. J. D (1970) Oak Ridge National Laboratory Report ORNL-4562.

    Google Scholar 

  88. Johnson. D. A. (1969) J. Chem. Soc. A, 1525–28.

    Google Scholar 

  89. Morss. L. R. (1971) J. Chem. Phys., 75, 392–9.

    CAS  Google Scholar 

  90. Goldman, S., Morss, L. R. (1975) Can. J. Chem., 53, 2695–700.

    CAS  Google Scholar 

  91. Kiselev, Yu. M. (1984) Radiokhimiya, 25, 463–8.

    Google Scholar 

  92. Schoebrechts, J.-P., Fuger, J., Morss, L. R. (1985) Proc. 189th American Chemical Society Meeting, Miami Beach, FL. April. NUCL-23.

    Google Scholar 

  93. Sugar, J. (1983) personal communication.

    Google Scholar 

  94. Moore, C. B. (1970) US. Natl Bur. Stand. Report NSRDS-NBS 34. National Bureau of Standards, Washington, DC.

    Google Scholar 

  95. Worden, E. F. and Conway, J. G. (1980) in Lanthanide and Actinide Chemistry and Spectroscopy (ed. N. Edelstein), (Am. Chem. Soc. Symp. Ser. 131), American Chemical Society, Washington, DC, pp. 381–425.

    Google Scholar 

  96. Rajnak. K., Shore. B. W. (1978) J. Opt. Soc. Am, 68. 360–7.

    CAS  Google Scholar 

  97. Larson, D. T., Haschke, J. M. (1981) Inorg. Chem, 20, 1945–50.

    CAS  Google Scholar 

  98. Flotow, H. E., Tetenbaum, M. (1981) J. Chem. Phys, 74. 5269–77.

    CAS  Google Scholar 

  99. Morss, L. R., Fuger, J., Goffart, J., Haire, R. G. (1983) Inorg. Chem, 22, 1993–6.

    CAS  Google Scholar 

  100. Morss, L. R., Fuger, J., Goffart, J., Haire, R. G. (1983) Inorg. Chem, 22, 1993–6.

    CAS  Google Scholar 

  101. Chereau, P.. Dean.G., DeFranco, M., Gerdanian, P. (1977) J. Chem. Thermodyn, 9. 211–19.

    CAS  Google Scholar 

  102. Besmann, T. M., Lindemer, T. B. (1983) J. Am. Ceram. Soc, 66, 782–5.

    CAS  Google Scholar 

  103. Morss. L. R., Sonnenberger, D. C. (1985) J. Nucl. Mater, 130. 266–72.

    CAS  Google Scholar 

  104. Williams, C. W., Morss, L. R., Choi, I.-K. (1984) in Geochemical Behavior of Disposed Radioactive Waste (eds G. S. Barney, J. D. Navratil., W. W. Schulz), (Am. Chem. Soc. Symp. Ser. 246), American Chemical Society. Washington, DC. pp. 323–34.

    Google Scholar 

  105. Fujino, T., Morss, L. R. (1986) Inorg. Chim. Acta, submitted.

    Google Scholar 

  106. Morss, L. R. (1982) in Actinides in Perspective (ed. N. M. Edelstein), Pergamon. Oxford, pp. 381–407.

    Google Scholar 

  107. Morss, L. R., Fahey, J. A. (1976) Proc. 12th Rare Earth Res. Conf, vol. 1, Denver Research Institute, Denver, CO, pp. 443–50.

    Google Scholar 

  108. Westrum, E. F., Jr, Eyring, L. (1949) in The Transuranium Elements (eds G. T. Seaborg. J. J. Katz., W. M. Manning). Natl Nucl. En. Ser.. Div. IV. 14B. McGraw- Hill. New York, paper 6. 52.

    Google Scholar 

  109. Johnson. G. K., Pennell. R. G., Kim, K.-Y., Hubbard, W. N. (1980) J. Chem. Thermodyn, 12. 125–36.

    CAS  Google Scholar 

  110. Kim, Y.-C, Oishi, J., Kang, S.-H. (1977) J. Chem. Thermodyn., 9, 973–7; idem. (1978) J.Chem. Thermodyn., 10,975–81;Kim, Y.-C., Misumi, M., Yano, H., Oishi, J. (1979) J. Chem. Thermodyn., 11, 657–62.

    Google Scholar 

  111. Gmelin Handbuch der Anorganischen Chemie, Suppl. Ser., Transurane, Verlag Chemie, Weinheim, vol. 4, part C, Compounds (1972).

    Google Scholar 

  112. Parker, V. B., Wagman, D. D., Garvin, D. (1976) US Natl Bur. Stand. Report, NBS1R 75–968.

    Google Scholar 

  113. Brown, D. (1968) Halides of the Lanthanides and Actinides, Wiley-Interscience, London.

    Google Scholar 

  114. Gmelin Handbuch der Anorganischen Chemie, Verlag Chemie, Weinheim, System- Nummer 39, Seltenerdelemente, part C4a/b (1982), part 6 (1978).

    Google Scholar 

  115. Hurtgen, C., Fuger. J., and Brown, D. (1980) J. Chem. Soc., Dalton Trans., 70–5.

    Google Scholar 

  116. Fried, S. (1981) personal communication.

    Google Scholar 

  117. Parker, V. B. (1980) US Natl Bur. Stand. Report, NBSIR 80 - 2029.

    Google Scholar 

  118. Johnson, G. K. (1979) J. Chem. Thermodyn., 11, 483–90.

    CAS  Google Scholar 

  119. Jouniaux, B., Legoux, Y., Merinis, J., Bouissieres, G. (1979) Radiochem. Radioanal. Lett., 39, 2013–40.

    Google Scholar 

  120. ANL (1967) Argonne Nati Lab., Chem. Eng. Div. Report, ANL-7375; Schmets, J. J. (1973) in Gmelin Handbuch der Anorganischen Chemie, Suppl. Ser., Transurane, Verlag Chemie, Wcinhcim, vol. AI, part II, pp. 251–65.

    Google Scholar 

  121. Fuger. J. (1979) J. Physique, 40, Colloq. C4, 207–13.

    Google Scholar 

  122. Feber, R. C., Herrick, C. C. (1965) Ideal Gas Thermodynamic Functions of Lanthanide and Actinide Elements, Los Alamos Scientific Laboratory Report LA- 3184.

    Google Scholar 

  123. Nugent, L. J. (1975) in MTP International Review of Science, Inorganic Chemistry, ser. 2, vol. 7, Butterworths, London, pp. 195–219.

    Google Scholar 

  124. Westrum. E. F., Jr., Gnønvold, F. (1962) Thermodynamics of Nuclear Materials, Proc. Symp. 1962, International Atomic Energy Agency, Vienna, pp. 3–37.

    Google Scholar 

  125. Moskvin. A. I. (1973) Radiokhimiya. 15. 353–62.

    CAS  Google Scholar 

  126. Nakamura. J., Takahashi. Y., Izumi. S., Kanno. M. (1980) J. Nucl. Mater.. 88.64–72.

    CAS  Google Scholar 

  127. Ackermann. R. J., Rauh, E. G. (1972) J. Chem. Thermodyn, 4, 521–32.

    CAS  Google Scholar 

  128. COD ATA (1977) CODATA Recommended Key Values for Thermodynamics, CODATA Bulletin no. 28, CODATA, Paris.

    Google Scholar 

  129. Ackermann. R. J., Rauh. E. G. (1973) High Temp. Sci, 5. 463–73.

    CAS  Google Scholar 

  130. Ackermann, R. J., Rauh, E. G. (1974) J. Chem. Phys, 60. 2266–71.

    CAS  Google Scholar 

  131. Ackermann. R. J., Chandrasekharaiah. M. S. (1975) Thermodynamics of Nuclear Materials. Proc. Symp. 1974, International Atomic Energy Agency, Vienna, pp. 3–26.

    Google Scholar 

  132. Green, D. W. (1980) J. Nucl. Mater., 88. 51-63.

    Google Scholar 

  133. Osborne, D. W., Westrum. E. F., Jr (1953) J. Chem. Phys, 21, 1884–7.

    CAS  Google Scholar 

  134. Ackermann, R. J., Tetenbaum, M. (1980) High Temp. Sci, 13. 91–105.

    CAS  Google Scholar 

  135. Picard, C., Kleppa, O. J. (1980) High Temp. Sci., 12. 89–98.

    CAS  Google Scholar 

  136. Lohr, H. R., Osborne. D. W., Westrum, E. F.. Jr (1964) J. Am. Chem. Soc., 76, 3837–9.

    Google Scholar 

  137. Rajendra Prasad., Nagarajan. K., Singh, Z., Bhupathy, M., Venugopal. V., Sood, D. D. (1980) Thermodynamics of Nuclear Materials. Proc. Symp. 1979, vol. I. International Atomic Energy Agency. Vienna, pp. 45–59.

    Google Scholar 

  138. O’Hare, P. A. G., Ader. M., Hubbard, W. N., Johnson, G. K., Settle, J. L. (1975) Thermodynamics of Nuclear Materials, Proc. Symp. 1974, vol. II, International Atomic Energy Agency, Vienna, pp. 439–53.

    Google Scholar 

  139. Aronson, S. (1967) J. Inorg. Nucl. Chem, 29. 1611–17.

    CAS  Google Scholar 

  140. DeNovion, C.-H., Costa, P. (1972) J. Physique, 33. 257–71.

    CAS  Google Scholar 

  141. Cheda.J. A. R.,Westrum,E.F.,JrandMorss,L. R. (1976) J. Chem. Thermodyn., 8. 25–59.

    CAS  Google Scholar 

  142. Maurice,V..Boutard.J. L., Abbe, D.(1979) J. Physique.40.Colloq.C4,140–1.

    Google Scholar 

  143. Huber, E. J., Jr. Holley, C. E., Jr, and Krikorian, N. H. (1968) J. Chem. Eng. Data, 13. 253–6.

    CAS  Google Scholar 

  144. Danan, J. (1975) J. Nucl. Mater., 57, 280–2.

    CAS  Google Scholar 

  145. Holley, C. E., Jr., Storms, E. K. (1968) Thermodynamics of Nuclear Materials, Proc. Symp. 1967, International Atomic Energy Agency, Vienna, pp. 397–426.

    Google Scholar 

  146. Potter, P. E. (1969) J. Inorg. Nucl. Chem., 31, 1821–9.

    CAS  Google Scholar 

  147. Westrum, E., Jr, Takahashi, Y., Stout, N. D. (1965) J. Phys. Chem., 69. 1520–4.

    CAS  Google Scholar 

  148. Besmann, T. M., Beahm, E. C. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, International Atomic Energy Agency, Vienna.

    Google Scholar 

  149. Subramanian, M. S., Singh, R. N., Sharma, H. D. (1969)J. Inorg. Nucl. Chem., 31, 3789–95.

    CAS  Google Scholar 

  150. Alcock, C. B., Cornish, J. B., Grieveson, P. (1966) Thermodynamics, Proc. Symp. 1965, vol. I, International Atomic Energy Agency, Vienna, pp. 211–30.

    Google Scholar 

  151. Palenzona, A., Cirafici, S. (1975) Thermochim. Acta, 13, 357–60.

    CAS  Google Scholar 

  152. Kubaschcwski, O. (1967) Thermodynamics of Nuclear Materials, Proc. Symp. 1967, International Atomic Energy Agency, Vienna, pp. 685–98.

    Google Scholar 

  153. Skelton, W. H.. Magnani. N. J., Smith, J. F. (1970) Metall Trans, 1, 1833–7.

    CAS  Google Scholar 

  154. Mortimer, M. J. (1979) J. Physique, 40, Colloq. C4, 124–9, and personal communication.

    Google Scholar 

  155. Bradbury, M. H. (1981) J. Less Common Metals, 78, 207–18.

    CAS  Google Scholar 

  156. Fuger, J., Bohet. J., Muller. W.. Whittacker, B., Brown, D. (1978) Inorg. Nucl. Chem. Lett, 14. 11–13.

    CAS  Google Scholar 

  157. Fugcr, J. (1982) in Actinides in Perspective (ed. N. Edelstein), Pergamon, Oxford, pp. 409–31.

    Google Scholar 

  158. Lorenz, R. Scherff, H. L. (1971) Third Int. Protactinium Conf, Schloss Elmau, 1969, Inst. Radiochemie, Tech. Univ. Munich, paper 15.

    Google Scholar 

  159. Rand, M. H. (1979) Thermodynamics of Nuclear Materials. Proc. Symp. 1979, vol. I, International Atomic Energy Agency, Vienna, pp. 197–217.

    Google Scholar 

  160. Steele, B. C. H., Javed, N. A., Alcock, C. B. (1970) J. Nucl. Mater., 35. 1–13.

    CAS  Google Scholar 

  161. Green, D. W., Leibowitz. L. (1981) Argonne National Laboratory Report ANL- CEN-RSD-81-1.

    Google Scholar 

  162. Blackburn, P. E. (1973) J. Nucl. Mater, 46. 244–52.

    CAS  Google Scholar 

  163. Markin.T. L., Wheeler, V. J., Bones. R. J. (1968)J. Inorg. Nucl. Chem., 30,807–17.

    CAS  Google Scholar 

  164. Tetenbaum. M., Hunt. P. D. (1969) J. Chem. Phys, 49, 4739–44.

    Google Scholar 

  165. Huber. E. J., Jr., Holley. C. E., Jr (1969) J. Chem. Thermodyn, 1. 267–72.

    CAS  Google Scholar 

  166. Huntzicker. J. J. and Westrum. E. F., Jr (1971) J. Chem. Thermodyn 3. 61–76.

    CAS  Google Scholar 

  167. Fink, J. K.Chasanov. M. G., Leibowitz, M. G. (1981)J. Nucl. Mater., 102,17–25.

    CAS  Google Scholar 

  168. Long, K. A., Babelot, J. F., Magill, J., Ohse, R. W. (1980) High Temp. High Press, 12, 515–36.

    CAS  Google Scholar 

  169. MacInnes. D. A. (1978) J. Nucl. Mater.. 78, 225–7.

    CAS  Google Scholar 

  170. Ohse. R. W., Babelot, J. F.,Cercignani, C., Kinsman, P. R., Long, K. A., Magill, J., Scott, A. (1979) J. Nucl. Mater.. 80, 232–48.

    CAS  Google Scholar 

  171. Ohse, R. W.. Babelot, J. F., Frezotti. A., Long, K. A., Magill. J. (1980) High Temp. Sci., 13. 35–78.

    CAS  Google Scholar 

  172. Ohse, R. W., Babelot, J. F., Brumme, G. D., and Kinsman. P. R. (1978) Rev. Int. Hautes Temp. Refract, 15, 319–32.

    CAS  Google Scholar 

  173. Thorn, R. J., Winslow, J. S., Ziomek. J. S. (1979)J. Nucl. Mater.. 87,416–18.

    CAS  Google Scholar 

  174. Ackermann, R. H., Rauh, E. G., Rand, M. H. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, International Atomic Energy Agency, Vienna.

    Google Scholar 

  175. Reedy, G. T., Chasanov. M. G. (1972) J. Nucl. Mater, 42, 341–4.

    CAS  Google Scholar 

  176. Tetenbaum, M., Hunt, P. D. (197) J. Nucl. Mater., 34. 86–91.

    Google Scholar 

  177. Affortit, C., Marcon, J. P. (1970) Rev. Hautes Temp. Refract, 7, 236–41.

    CAS  Google Scholar 

  178. Hoch, M. (1972) High Temp. High Press, 4. 493–5.

    CAS  Google Scholar 

  179. Picard. C., Gerdanian, P. (1981) J. Nucl. Mater, 99, 184–9.

    CAS  Google Scholar 

  180. Woodley. R. E., Adamson. M. G. (1979) Thermodynamics of Nuclear Materials. Proc. Symp. 1979, International Atomic Energy Agency, Vienna, pp. 333–55.

    Google Scholar 

  181. Fischer, D. F., Fink, J. K., Leibowitz, M. G. (1981) J. Nucl. Mater., 102, 220–2.

    CAS  Google Scholar 

  182. Fischer, D. F., Fink, J. K., Leibowitz, M. G. (1983)J. Nucl. Mater., 118. 342–8.

    CAS  Google Scholar 

  183. Fuger. J. (1983) in Gmelin Handbuch der Anorganischen Chemie, Suppl. Ser,,Uran. Verlag Chemie, Weinheim, part A6, pp. 165–92.

    Google Scholar 

  184. Westrum, E. F., Jr (1966) Thermodynamics. Proc. Symp. 1965, vol. 2, International Atomic Energy Agency, Vienna, pp. 495–510.

    Google Scholar 

  185. Cordfunke, E. H. P., Aling, P. (1965) Trans. Faraday Soc 61, 50–3.

    CAS  Google Scholar 

  186. Moore, G. E., Kelley. K. K. (1947)J. Am. Chem. Soc., 69,2105–7 (UO3 used in this study was not characterized structurally).

    Google Scholar 

  187. Ackermann, R. J., Chang, A. T. (1973) J. Chem. Thermodyn, 5, 873–90.

    CAS  Google Scholar 

  188. Westrum. E. F.. Jr and Gronvold. F. (1962) J. Phys. Chem. Solids, 23, 39–53.

    CAS  Google Scholar 

  189. Westrum. E. F., Jr., Gronvold. F. (1959) J. Am. Chem. Soc.. 81, 1777–80.

    CAS  Google Scholar 

  190. Aronson. S., Belle, J. (1958) J. Chem. Phys., 29. 151–8.

    CAS  Google Scholar 

  191. Girdhar, H. L., Westrum, E. F., Jr (1968) J Chem. Eng. Data 13, 531–3.

    CAS  Google Scholar 

  192. Roberts, L. F.. J., Walter, A. J. (1961) J. Inorg. Nucl. Chem, 22. 213–29.

    CAS  Google Scholar 

  193. Flotow. H. E., Osborne, D. W., Westrum. E. F.. Jr (1968) J. Chem. Phys, 49. 2438–42.

    CAS  Google Scholar 

  194. Dharwadkar, S. R., Tripathi, S. N., Karkhanavala, M. D., Chandrasekharaiah, M. S. (1975) Thermodynamics of Nuclear Materials. Proc. Symp. 1974, International Atomic Energy Agency, Vienna, pp. 455–65.

    Google Scholar 

  195. Pattoret. A.. Drowart, J., Smoes. S. (1968) Thermodynamics, Proc. Symp. 1967, International Atomic Energy Agency, Vienna, pp 613–36.

    Google Scholar 

  196. Lau. K. H., Hildebrand, D. L. (1982) J. Chem. Phys., 76, 2646–52.

    CAS  Google Scholar 

  197. Ferris, L. M., Mailen, J. C., Smith, F. J. (1971)J. Inorg. Nucl. Chem.. 38. 1325–33.

    Google Scholar 

  198. Burns, J.H,Osborne, D. W., Westrum. E. F.. Jr (1960)J. Chem. Phys.. 33. 387– 94.

    Google Scholar 

  199. Osborne. D. W.. Westrum. E. F., Jr., Lohr. H. R. (1955)J. Am. Chem. Soc., 77, 2737–9.

    CAS  Google Scholar 

  200. Brickwedde, F. G., Hoge. H. J., Scott, R. B. (1948) J. Chem. Phys 16. 429–36.

    CAS  Google Scholar 

  201. Masson. J. P., Desmoulin, J. P.. Charpin, P., Bougon, R. (1976) Inorg. Chem., 15. 2529–31 (corrected).

    Google Scholar 

  202. O’Hare, P. A. G., Malm. J. G. (1982) J Chem. Thermodyn, 14, 331–6.

    Google Scholar 

  203. Lau, K. H., Hildebrand, D. L. (1984) J. Chem. Phys, 80. 1312–17.

    CAS  Google Scholar 

  204. Cordfunke, E. H. P., Ouweltjes, W., Prins, G., van Vlaanderen. P. (1983) J. Chem. Thermodyn., 15, 1103–4.

    CAS  Google Scholar 

  205. Cordfunkc. E. H. P., Kubaschewski. O. (1984) Thermochim. Acta, 74. 235–45.

    CAS  Google Scholar 

  206. Katz, J. J., Rabinowitch, E. (1951) The Chemistry of Uranium, McGraw-Hill. New York.

    Google Scholar 

  207. Greenberg. E., Westrum, E. F., Jr (1956) J. Am. Chem. Soc, 78, 5144–7.

    CAS  Google Scholar 

  208. Greenberg, E. and Westrum, E. F., Jr (1956) J. Am. Chem. Soc., 78, 4526–8.

    CAS  Google Scholar 

  209. Singh. Z., Prasad. R.. Venugopal, V., Roy, K. N., Sood, D. D. (1981)J. Chem. Thermodyn., 13, 485–90.

    CAS  Google Scholar 

  210. Prins. G., Cordfunke. E. H. P., Ouweltjes, W. (1978) J. Chem. Thermodyn, 10. 1003–10.

    CAS  Google Scholar 

  211. Westrum, E. F., Jr., Walters, R. R., Flotow, H. E., Osborne, D. W. (1968) J. Chem. Phys, 48. 155–61.

    CAS  Google Scholar 

  212. Westrum, E. F., Jr., Grønvold. F. (1970) J. Inorg. Nucl. Chem, 32, 2169–77.

    CAS  Google Scholar 

  213. Settle. J. L., O’Hare, P. A. G. (1984) J Chem. Thermodyn, 16, 1175–80.

    CAS  Google Scholar 

  214. Gronvold, F., Westrum. E. F., Jr (1968) J Inorg. Nucl. Chem.. 30. 2127–33.

    Google Scholar 

  215. Takahashi, Y., Westrum. E. F.. Jr (1965) J Phys. Chem., 69, 3618–21.

    CAS  Google Scholar 

  216. Cordfunke, E. H. P., Ouweltjcs, W. (1977) J. Chem. Thermodyn., 9, 1057–62.

    CAS  Google Scholar 

  217. Blaise, A. (1979) J Physique, 40, Colloq. C4, 49–61.

    Google Scholar 

  218. Counsell. F. J., Dell. R. M., Martin, J. F. (1966) Trans. Faraday Soc.. 62. 1736–47.

    CAS  Google Scholar 

  219. Westrum. E. F.. Jr., Barber, C. M. (1966) J Chem. Phys, 45, 635–9.

    CAS  Google Scholar 

  220. Potter, P. E., Mills, K. C., Takahashi. Y. (1986) The Chemical Thermodynamics of Actinide Elements and Compounds, part 7, The Actinide Pnictides, STI/PUB/424/7. International Atomic Energy Agency. Vienna, in preparation.

    Google Scholar 

  221. Potter. P. E., Spear, K. E. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, vol. II. International Atomic Energy Agency, Vienna, pp. 195–227.

    Google Scholar 

  222. Plurien, P, Chatelet, J., Luce. M., Rigny, P. (1973) Proc. 7th Int. Symp. on Fluorine Chemistry, Santa Cruz, CA.

    Google Scholar 

  223. Coulter. L. V.. Pitzer, K. S., Latimer. W. M. (1940) J. Am. Chem. Soc, 62, 2845–51.

    CAS  Google Scholar 

  224. Counsell. F. J.. Dell. R. M., Junkison, A. R., Martin. J. F. (1959) Trans. Faraday Soc, 63. 72–9.

    Google Scholar 

  225. Ono, F., Kanno, M., Mukaibo. T. (1973) J Nucl. Sci. Technol, 10, 764–5.

    CAS  Google Scholar 

  226. Stalinsky, B.. Bieganski. Z., Troc, R. (1966) Phys. Status Solids 17. 837–41.

    Google Scholar 

  227. Counsell, J. F., Martin, J. F., Dell. R. M., Junkison, A. R. (1968) Thermodynamics of Nuclear Materials, Proc. Symp. 1967, International Atomic Energy Agency. Vienna, pp. 385–94.

    Google Scholar 

  228. Alles, A., Falk. B. G., Westrum. E. F., Jr, Gronvold, F., Zaki, M. R. (1977) J. Inorg. Nucl. Chem.. 39. 1993–2000.

    CAS  Google Scholar 

  229. Cordfunke. E. H. P.. Ouweltjes, W., Barten, H. (1982) J Chem. Thermodyn.. 14. 883–6.

    CAS  Google Scholar 

  230. Andon, R. J. L., Counsell, J. F., Martin. J. F., Hedger. H. J. (1964) Trans. Faraday Soc, 60, 1030–7.

    CAS  Google Scholar 

  231. Westrum, E. F., Jr., Suits, E., Lonsdale, H. K. (1965) Advances in Thermophysical Properties at Extreme Temperatures and Pressures, American Society of Mechanical Engineers, New York, pp. 156–61.

    Google Scholar 

  232. Ackermann. R. J.. Oetting, F. L.. Potter. P. F R., and. M. W., and Storms, E. K. (1979) IAEA Technical Panel Series, International Atomic Energy Agency, Vienna.

    Google Scholar 

  233. Oetting, F. L., Navratil, J. D., Storms, E. K. (1972-73)J. Nucl. Mater., 45,271–83.

    Google Scholar 

  234. Gupta, S. K., Gingerich, K. A. (1979) J. Chem. Phys, 71, 3072–80.

    CAS  Google Scholar 

  235. Huber.E. J., Jr, Head, E. L., Holley, C. E.,Jr(1963)J. Phys. Chem., 67,1730–1.

    CAS  Google Scholar 

  236. MacLeod, A. C., Hopkins. S. W. J. (1967) Proc. Br. Ceram. Soc, 8, 15–30.

    Google Scholar 

  237. MacLeod, A. C. (1969) J. Inorg. Nucl. Chem., 31, 715–25.

    CAS  Google Scholar 

  238. Storms, E. K. (1966) Thermodynamics, Proc. Symp. 1965, vol. I, International Atomic Energy Agency. Vienna, pp. 309–43.

    Google Scholar 

  239. Storms, E. K. (1967) The Refractory Carbides, Academic Press, New York, pp. 171–213.

    Google Scholar 

  240. Holley, C. E., Jr (1973) Thermodynamic Properties of Actinide Carbides, Los Alamos Scientific Laboratory Report LA-UR-73-847.

    Google Scholar 

  241. Farr, J. D., Witteman. W. G., Stone, P. L., Westrum, E. F., Jr (1965) Advances in Thermophysical Properties at Extreme Temperatures and Pressures, American Society of Mechanical Engineers. New York. pp. 162–6.

    Google Scholar 

  242. O’Hare. P. A. G. (1977) J. Chem. Thermodyn., 9, 1077–86.

    Google Scholar 

  243. Thakur, L., Prasad, R., Thakur. A. K., Ahmad. M. F. (1979) Indian J. Chem., 18A, 258–9.

    Google Scholar 

  244. Prins, G., Cordfunke. E. H. P., Depaus, R. (1980) J. Nucl. Mater., 89, 221–8.

    CAS  Google Scholar 

  245. Gross, P., Hayman, C., and Clayton, H. (1963) Thermodynamics of Nuclear Materials, Proc. Symp. 1962, International Atomic Energy Agency, Vienna, pp. 653–65.

    Google Scholar 

  246. Alcock, C. B., Grieveson, P. (1961) J. Inst. Metals. 90. 304–10.

    Google Scholar 

  247. Flotow, H. E., Osborne, D. W., O’Hare, P. A. G., Settle. J. L., Mrazek, F. C., Hubbard. W. N. (1969) J. Chem. Phys., 51, 583–92 (C°p and S° refer to UB1.979).

    Google Scholar 

  248. Chiotti. P. and Kateley, J. A. (1969)J. Nucl. Mater., 32, 135–5.

    CAS  Google Scholar 

  249. Johnson, I. and Feder, H. M. (1962) Thermodynamics of Nuclear Materials, Proc. Symp. 1962, International Atomic Energy Agency, Vienna, pp. 319–29.

    Google Scholar 

  250. Johnson, I., Feder, H. M. (1962) Trans. Metall. Soc. AIME 224. 468–73.

    CAS  Google Scholar 

  251. Forsberg, H. C. (1960) Oak Ridge National Laboratory Report ORNL-2885.

    Google Scholar 

  252. Johnson, I. (1964) Proc. Symp. on Compounds of Interest in Nuclear Reactor Technology, AIME, New York; Nucl. Metall, 10. 171.

    Google Scholar 

  253. O’Hare, P. A. G., Malm, J. G. (1984) J. Chem. Thermodyn., 16. 753–9.

    Google Scholar 

  254. Dewally, D., Perrot, P. (1976) Rev. Chim. Minér, 13, 605–13.

    CAS  Google Scholar 

  255. Fujino T.. Tateno. J., Tagawa, H. (1979) J. Solid State Chem., 24, 11–19.

    Google Scholar 

  256. Tateno, J., Fujino. T., Tagawa, H. (1979) J. Solid State Chem, 30, 265–73.

    CAS  Google Scholar 

  257. Westrum, E. F., Jr. Zainel, H. A., and Jakes, D. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, vol. II, International Atomic Energy Agency, Vienna, pp. 143–54.

    Google Scholar 

  258. Gol’tsev, V. P., Tret’yakov, A. A., Kerko. P. F., Barinov, V. I., Malevich. V. M. (1981) Vestsi Akad. Nauk BSSR, Ser. Fiz.-Energ. Navuk., 24–9 (Chem. Abstr., 94, 128546r).

    Google Scholar 

  259. Morss, L. R., Williams. C. W., Choi, l.-K., Gens. R., Fuger. J. (1983) J. Chem. Thermodyn, 15, 1093–102.

    CAS  Google Scholar 

  260. Tagawa, H., Fujino, T. (1978) J. Inorg. Nucl. Chem., 40. 2033–6.

    CAS  Google Scholar 

  261. O’Hare. P. A. G., Flotow, H. E., and Hoekstra. H. R. (1980)J. Chem. Thermodyn., 1003–8.

    Google Scholar 

  262. Morss, L. R., Fuger. J., Jenkina, H. D. B. (1982) J. Chem. Thermodyn., 14, 377–84.

    CAS  Google Scholar 

  263. Gens. R., Fuger. J.. Morss. L. R., Williams. C. W. (1985)J. Chem. Thermodyn., 17. 561–73.

    CAS  Google Scholar 

  264. Cordfunke. E. H. P., Ouweltjes, W. (1981)J. Chem. Thermodyn., 13. 187–92.

    CAS  Google Scholar 

  265. Fuger, J. (1985) J. Nucl. Mater., 130. 253–65.

    CAS  Google Scholar 

  266. Bogacz, A.. Szczepaniak. W.. Bros. J.-P., Fouque, Y., Gaune-Escard. M. (1984) J. Chem. Soc., Faraday Trans, 180. 2935–41.

    Google Scholar 

  267. Lyon. W. G., Osborne. D. W., Flotow, H. E., Hoekstra. H. R. (1977)J. Chem. Thermodyn., 9. 201–10.

    CAS  Google Scholar 

  268. Cordfunke. E. H. P., Muis, R. P.. Ouweltjes, W., Flotow, H. E., and O’Hare, P. A. G. (1982) J. Chem. Thermodyn., 14, 313–22.

    CAS  Google Scholar 

  269. Osborne, D. W., Flotow. H. E. Dallinger. R. P., Hoekstra. H. R. (1974) J. Chem. Thermodyn, 6. 751–6.

    CAS  Google Scholar 

  270. Adamson. M. G., Aitken, E. A., Caputi. R. W., Potter, P. E., Mignanelli. M. A. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, vol. I. International Atomic Energy Agency. Vienna, pp. 503–38.

    Google Scholar 

  271. Suglobova. I. G., Fedorov, V. L., Chirkst, D. E. (1981) Izv. Akad. Nauk SSSR, Neorg. Mater., 17, 712–17 (corrected with accepted binary fluoride ΔH°f, values).

    Google Scholar 

  272. Aurov, N. A., Chirkst. D. E. (1983) Sov. Radiochem 25. 445–9; (1983) Radiokhimiya, 25, 468–73.

    CAS  Google Scholar 

  273. Osborne. D. W., Brletic. P. A., Hoekstra. H. R., Flotow, H. E. (1976)J. Chem. Thermodyn., 8. 361.

    CAS  Google Scholar 

  274. O’Hare. P. A. G., Flotow. H. E., Hoekstra, H. R., (1981)J. Chem. Thermodyn., 13. 1075–80.

    Google Scholar 

  275. Cordfunke, E. H. P., Westrum. E. F.. Jr (1979) Thermodynamics of Nuclear Materials. Proc. Symp. 1979, vol. II, International Atomic Energy Agency. Vienna, pp. 125–41.

    Google Scholar 

  276. Lorenzelli, R., LaDudal, R., Atabeck, R. (1979) Thermodynamics of Nuclear Materials, Proc. Symp. 1979, vol. I, International Atomic Energy Agcncy, Vienna, pp. 539–64.

    Google Scholar 

  277. Morss, L. R., Fuger, J., Goflart, J., Endlestein, N., and ShalimofT, G. M. (1986) J. Less-Common Metals, submitted.

    Google Scholar 

  278. Musikas, C. Couffin, F., and Marteau, M. (1974) J. Chim. Phys, 71. 641–8.

    CAS  Google Scholar 

  279. Zielen. A. J. and Cohen. D. (1970) J. Phys. Chem., 74. 394–405.

    CAS  Google Scholar 

  280. Ackermann. R. J.. Faircloth. R. L.. Rauh. E. G., Thorn, R. J. (1968) J. Inorg. Nucl. Chem.. 28. 111–18.

    Google Scholar 

  281. Ackermann. R. J., Rauh. E. G. (1975) J. Chem. Phys., 62. 108–12.

    CAS  Google Scholar 

  282. Huber, E. J., Jr and Holley, C. E., Jr (1968) J. Chem. Eng. Data, 13. 545–6.

    CAS  Google Scholar 

  283. Osborne, D. W. and Westrum, E. F., Jr (1953) J. Chem. Phys., 21, 1884–7.

    CAS  Google Scholar 

  284. Westrum, E. F., Jr. Hatcher, J. B., Osborne, D. W. (1953) J. Chem. Phys, 21. 419–23.

    CAS  Google Scholar 

  285. Arkhipov, V. A., Gutina. E. A., Dabretsov. V. N., Ustinov, V. A. (1974) Radiokhimiya, 16, 123–5.

    CAS  Google Scholar 

  286. Mulford, R. N. R., Wiewandt, T. A. (1965) J. Phys. Chem., 69, 1641–4.

    CAS  Google Scholar 

  287. Mintz, M. H., Hadari, Z., Bixon, M. (1976)J. Less Common Metals, 48.183–6.

    CAS  Google Scholar 

  288. Osborne. D. W., Weinstock. B., Burns, J. A. (1970) J. Chem. Phys, 52, 1803–10.

    CAS  Google Scholar 

  289. Olson. W. M., Mulford. R. N. R. (1966) J. Phys. Chem.. 70, 2932–4.

    CAS  Google Scholar 

  290. Sandcnaw.T. A.,Gibney, R. B., Holley.C. E., Jr(1973)J. Chem. Thermodyn., 5, 41–7.

    Google Scholar 

  291. Trevorrow, L. E., Gerding, T. J., Steindler. M. J. (1968) Inorg. Chem, 7, 2226–9.

    CAS  Google Scholar 

  292. Gordon. J. E., Hall. R. O. A., Lee. J. A., Mortimer. M. J. (1976) Proc. R. Soc. Lond. A, 351, 179–96.

    CAS  Google Scholar 

  293. Bradbury, M. H., Ohse. R. W. (1979) J. Chem. Phys, 70, 2310–14.

    CAS  Google Scholar 

  294. Musikas, C. (1975) in Gmelin Handbuch der Anorganischen Chemie, Suppl Ser., Transurane, Verlag Chemie, Wcinhcim, vol. 20, pp Dl.

    Google Scholar 

  295. Potter. P E. (1968) Thermodynamics of Nuclear Materials, Proc. Symp. 1967, International Atomic Energy Agency, Vienna, pp. 337–69.

    Google Scholar 

  296. Johnson. G. K. Van Deventer. E. H., Kruger, O. L., Hubbard, W. N. (1969) J. Chem. Thermodyn, 1, 89–98.

    CAS  Google Scholar 

  297. Flotow, H. E., Osborne. D. W., Fried. S. M., Malm. J. G. (1975)J. Chem. Phys., 65. 1124–9.

    Google Scholar 

  298. Kruger. O. L. Savage, H. (1968) J. Chem. Phys, 49. 4540–4.

    CAS  Google Scholar 

  299. Ogard, A. E. (1970) in Plutonium 1970 and Other Actinides. Proc. 4th Int. Conf. on Plutonium and Other Actinides, Santa Fe, NM, vol. I (ed. W. N. Miner), Metallurgical Society, New York. pp. 78–83.

    Google Scholar 

  300. Green. D. W. (1980) Argonne National Laboratory Report ANL-CEN-RSD-80-2.

    Google Scholar 

  301. Chilton, G. R. Edwards, J. (1979) Thermodynamics of Nuclear Materials, Proc Symp. 1979, vol. 1, International Atomic Energy Agency, Vienna, pp. 357–68.

    Google Scholar 

  302. Rand, M H., Roberts. L. E. J. (1966) Thermodynamics. Proc. Symp. 1965, vol. I, International Atomic Energy Agency. Vienna, pp. 3–31.

    Google Scholar 

  303. Woodley. R. E. Adamson, M. G. (1979) J. Nucl. Mater., 82. 65–75.

    CAS  Google Scholar 

  304. Oetting. F. L.. Hodges. A. E.. Haschke. J. M., Flotow, H. E., (1984) J. Chem. Thermodyn, 16, 1089–102.

    CAS  Google Scholar 

  305. Haschke, J. M.. Hodges. A. E.. Smith, C. M., Oetting, F. L. (1980) J. Less Common Metals 73, 41–8.

    CAS  Google Scholar 

  306. Smith, C. M., Hodges, A. E., Haschke, J. M., Oetting, F. L. (1982) J. Chem. Thermodyn, 14, 115–24.

    CAS  Google Scholar 

  307. Haschke. J. M. (1980) US Dcpt of Energy Report RFP-3099.

    Google Scholar 

  308. Kent, R. A . (1968) J. Am. Chem. Soc.. 90, 5657–9.

    CAS  Google Scholar 

  309. Osborne. D. W., Flotow, H. E., Fried, S. M., Malm, J. G. (1974)J. Chem. Phys., 61. 1463–8.

    CAS  Google Scholar 

  310. Osborne. D. W., Flotow, H. E., Fried, S. M., Malm, J. G. (1975)J. Chem. Phys., 63, 4613–17.

    CAS  Google Scholar 

  311. Chudinov, E. G. Choporov, D. Y. (1970) At. Energy (USSR), 28. 151–3.

    CAS  Google Scholar 

  312. Weinstock, B., Weaver. E. E., Malm, J. G. (1959) J. Inorg. Nucl. Chem, 17, 104–14.

    Google Scholar 

  313. Fuger, J. (1983) in Plutonium Chemistry (eds W. T. Carnali., G. R. Choppin), (Am. Chem. Soc. Symp. Ser. 216), American Chemical Society, Washington, DC, ch. 6.

    Google Scholar 

  314. Belyaev, Yu. I., Dobretsov, V. N., Ustinov, V. A. (1979) Sov. Radiochem, 21, 386–7; (1979) Radiokhimiya. 21, 450–1.

    CAS  Google Scholar 

  315. Benz, R. (1961) J. Chem. Phys., 65, 81–4.

    CAS  Google Scholar 

  316. Campbell, G. M., Mullins. L. J., Leary, J. A. (1968) Thermodynamics of Nuclear Materials. Proc. Symp. 1967, International Atomic Energy Agcncy, Vienna, pp. 75–88.

    Google Scholar 

  317. Gruen, D. M. DeKock, C. W. (1967) J. Inorg. Nuci. Chem., 29, 2569–75.

    CAS  Google Scholar 

  318. Phipps. T. E., Sears. G. W., Seifert, R. L., Simpson, O. C. (1950)J. Chem. Phys., 18, 713–23.

    CAS  Google Scholar 

  319. Weigel, F., Wishnevsky, V., Güldner, R. (1982) J. Less Common Metals, 84, 147–55.

    CAS  Google Scholar 

  320. Moser, J. B. and Kruger, O. L. (1968) J. Am. Ceram. Soc, 51, 369–72.

    CAS  Google Scholar 

  321. Hall, R. O. A., Lee, J. A., Martin. D. J., Sutcliffe, P. W. (1978) J. Chem. Thermodyn, 10, 935–40.

    CAS  Google Scholar 

  322. Oetting, F. L. (1978) J. Chem. Thermodyn., 10, 941–8.

    CAS  Google Scholar 

  323. Haines, H. R.. Hall, R. O. A., Lee. J. A., Mortimer, M. J., McElroy, D. (1980) J. Nucl. Mater, 88, 261–4.

    CAS  Google Scholar 

  324. Sandenaw. T. A. Gibney, R. B. (1970) in Plutonium 1970 and Other Actinides, Proc. 4th Int. Cof., on Plutonium and Other Actinides. Santa Fe, NM, vol. 1 (ed. W. N. Miner), Metallurgical Society, New York, pp. 104–12.

    Google Scholar 

  325. Kruger. O. L. Savage, H. (1964) J. Chem. Phys., 40. 3324–8.

    CAS  Google Scholar 

  326. Olson, W. M. Mulford, R. N. R. (1968) Thermodynamics of Nuclear Materials, Proc. Symp. 1967, International Atomic Energy Agency, Vienna, pp. 467–79.

    Google Scholar 

  327. Oetting, F. L. (1980) J. Nucl. Mater, 88, 265–72.

    CAS  Google Scholar 

  328. Benz, R. Leary, J. A. (1961) J. Phys. Chem, 65, 1056–8.

    CAS  Google Scholar 

  329. Hall, R. O. A., Lee, J. A., Mortimer, M. J., McElroy. D. L., Müller, W., Spirlet. J. C. (1980) J. Low Temp. Phys., 41, 397–404.

    CAS  Google Scholar 

  330. Muller. W., Schenkel. R. Schmidt. H E., Spirlet. J. E., McElroy. D. L., Hall. R. O. A., Mortimer, M. J. (1978) J. Low Temp. Phys., 30, 561–78.

    Google Scholar 

  331. Smith. J. L., Stewart. G. R., Huang. C. Y., Haire. R. G. (1979)J. Physique, 40. Colloq. C4, 138–9.

    Google Scholar 

  332. Olson, W. M., Mulford, R. N. R. (1966) J. Phys. Chem., 70, 2934–7.

    CAS  Google Scholar 

  333. Chikalla, T. D., Eyring, L. (1967) J. Inorg. Nucl. Chem., 29, 2281–93.

    CAS  Google Scholar 

  334. Chudinov, E. G. Choporov, D. Ya. (1970) At. Energiya, 28.62–4; (1970) Sov. J. At. Energy, 28, 71.

    Google Scholar 

  335. Raschella. D. L., Fellows. R. L., Peterson. J. R. (1981)J. Chem. Thermodyn.. 13. 303–12.

    CAS  Google Scholar 

  336. Turcotte. R. P., Chikalla. T. D., Eyring, L. (1973) J. Inorg. Nucl. Chem., 35, 809–16.

    CAS  Google Scholar 

  337. Smith. P. K., Peterson. D. E. (1970) J. Chem. Phys, 52, 4963–72.

    CAS  Google Scholar 

  338. Fuger. J., Haire., R. G., Peterson. J. R (1981) J Inorg. Nucl. Chem, 43. 3209–12.

    CAS  Google Scholar 

  339. Fuger. J.. Haire., R. G., Peterson, J. R. (1984)J. Less Common Metals. 98. 315–21.

    CAS  Google Scholar 

  340. Samhoun, K., David, F. (1979) J. Inorg. Nucl. Chem., 41, 357–63.

    CAS  Google Scholar 

  341. Kleinschmidt, P. D., Ward, J. W., Matlack, G. M., Haire, R. G. (1984) J. Chem. Phys, 81. 473–7.

    CAS  Google Scholar 

  342. Mikheev, N. B., Spitsyn, V. I., Kamenskaya. A. N., Rozenkevich, N. A., Rumer. I. A., Auerman, L. N. (1972) Radiokhimiya, 14. 486–7; (1972) Sov. Radiochem., 14, 494–5.

    Google Scholar 

  343. Mikheev, N. B., Spitsyn. V. I., Kamenskaya, A. N., Konovalova, N. A., Rumer, I. A., Auerman, L. N., Podorozhnyi, A. M. (1977) Inorg. Nucl. Chem. Lett, 13, 651–6.

    CAS  Google Scholar 

  344. Hulet, E. K. (1980) in Lanthanide and Actinide Chemistry and Spectroscopy (ed. N. Edelstein), (Am. Chem. Soc. Symp. Ser. 131 ), American Chcmical Society, Washington, DC.

    Google Scholar 

  345. Meyer. R. E., McDowell, W. J., Dinner, P. F., Silva, R. J., Tarrant, J. R. (1976) J. Inorg. Nucl. Chem.. 38. 1171–3.

    CAS  Google Scholar 

  346. Bratsch, S. G. Lagowski, J. J. (1986) J. Phys. Chem., 307–12.

    Google Scholar 

  347. O’Hare. P. A. G. (1985) J. Chem. Thermodyn, 17, 611–22.

    Google Scholar 

  348. Storms. E. K. (1985) J. Nucl. Mater., 132, 231–43.

    CAS  Google Scholar 

  349. Matsui, T. and Naito, K. (1985) J. Nucl. Mater., 132, 212-21.

    Google Scholar 

  350. Uu, K. H., Brittain, R. D.,and Hildenbrand, D. L. (1985)7. Phys. Owm.89,4369- 73.

    Google Scholar 

  351. Fouque, Y., Bros, J. P., Gaunc-Escard. M., Wisniowski. M., Bogacz, A. (1985) Ber. Bunsenyes. Phys. Chem, 89. 777–9.

    CAS  Google Scholar 

  352. Oetting, F. L., Adams. R. O. (1983) J. Chem. Thermodyn, 15. 537–54.

    CAS  Google Scholar 

  353. Brewer. L. (1971) J. Opt. Soc. Am., 61,1101–11, 1106–81; (1984) High-Temp. Sci., 17, 1–30.

    Google Scholar 

  354. Hildenbrand, D. L., Gurvich, L. V., Yungman, V. S. (1985) The Chemical Thermodynamics of Actinide Elements and Compounds, part 13, The Gaseous Actinide Ions, STI/PUB/424/13, International Atomic Energy Agency, Vienna.

    Google Scholar 

  355. Morss, L. R. (1986) to be published.

    Google Scholar 

  356. Lindemer, T. B. Besmann, T. M. (1985) J. Nucl. Mater., 130, 473–88.

    CAS  Google Scholar 

  357. Johnson, G. K. (1985) J. Nucl. Mater., 130, 102–8.

    CAS  Google Scholar 

  358. Westland, A. D. Tarafder, M. T. H. (1983) Can. J. Chem., 61, 1573–7.

    CAS  Google Scholar 

  359. Pyatenko, A. T., Gusarov, A. V., Gorokhov, L. N. (1984) Zh. Fiz. Khim., 58, 1280–1.

    CAS  Google Scholar 

  360. Leitnaker, J. M. (1983) High-Temp. Sci., 16, 239–40.

    CAS  Google Scholar 

  361. Garisto, F. Garisto, N. C. (1985) Nucl. Sci. Eng, 90, 103–10.

    CAS  Google Scholar 

  362. Garisto, F. Garisto, N. C. (1985) Nucl. Sci. Eng., 90, 103–10.

    CAS  Google Scholar 

  363. Lindemer, T. B., Besmann, T. M., Johnson. C. E. (1981) J. Nucl. Mater., 100, 178–226.

    CAS  Google Scholar 

  364. Besmann. T. M. Lindemer, T. B. (1985) J. Nucl. Mater., 130, 489–504.

    CAS  Google Scholar 

  365. Belle, J. Berman, R. M., eds. (1984) Thorium Dioxide: Properties and Nuclear Applications, U.S. Dept. of Energy. Washington. D.C.. DOE/NF.-0060, chapter 5.

    Google Scholar 

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  1. Lester R. Morss
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  1. Chemistry Division, Argonne National Laboratory, USA

    Joseph J. Katz  & Lester R. Morss  & 

  2. Chemistry Division, Lawrence Berkeley Laboratory, USA

    Glenn T. Seaborg

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Morss, L.R. (1986). Thermodynamic Properties. In: Katz, J.J., Seaborg, G.T., Morss, L.R. (eds) The Chemistry of the Actinide Elements. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3155-8_10

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