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The Effect of Electronic Excitation in the Reactions of Oxygen Atoms with Simple Hydride Molecules

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Selectivity in Chemical Reactions

Part of the book series: NATO ASI Series ((ASIC,volume 245))

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Abstract

On excitation of the lowest electronic state of the oxygen atom, the rates of its reactions with hydride molecules typically increase by about six orders of magnitude and the dynamics of the reactions change from simple hydrogen atom abstractions to more complex processes in which the oxygen inserts into the molecular bond under attack. This results in the transient formation of a strongly-bound singlet intermediate, which may undergo very complex dynamical behaviour before dissociating-to products. This behaviour is illustrated by detailed discussions of the oxygen atom reactions with H2 and the hydrogen halides.

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Authors and Affiliations

  1. Department of Chemistry, University of Waterloo, Waterloo, Canada, N2L3G1

    J. J. Sloan, E. J. Kruus & B. I. Niefer

  2. Department of Chemistry, Carleton University, Ottawa, Canada, K1S5B6

    J. J. Sloan, E. J. Kruus & B. I. Niefer

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  1. J. J. Sloan
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  2. E. J. Kruus
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  3. B. I. Niefer
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  1. Department of Chemistry, University of Manchester, Manchester, UK

    J. C. Whitehead

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© 1988 Kluwer Academic Publishers

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Sloan, J.J., Kruus, E.J., Niefer, B.I. (1988). The Effect of Electronic Excitation in the Reactions of Oxygen Atoms with Simple Hydride Molecules. In: Whitehead, J.C. (eds) Selectivity in Chemical Reactions. NATO ASI Series, vol 245. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-3047-6_7

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  • DOI: https://doi.org/10.1007/978-94-009-3047-6_7

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