Abstract
Interactions of organometallic compounds with metal surfaces can be used to produce metal films and coatings as well as to modify the properties of metal catalysts for hydrocarbon conversion. The literature is reviewed, and results are evaluated characterizing the interaction of metal carbonyl clusters with surfaces of supported metals under mild conditions. The reactions lead to the preparation of highly dispersed bimetallic particles, which have homogeneous compositions and nonadditive properties in CO hydrogenation and hydrocarbon conversion.
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Ryndin, Y.A., Yermakov, Y.I. (1988). Reactions of Organometallic Compounds with Surfaces of Supported and Unsupported Metals. In: Basset, JM., et al. Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis. NATO ASI Series, vol 231. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2971-5_6
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DOI: https://doi.org/10.1007/978-94-009-2971-5_6
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