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Inorganic Reactions of Manganese in Soils

  • Chapter
Manganese in Soils and Plants

Part of the book series: Developments in Plant and Soil Sciences ((DPSS,volume 33))

Abstract

Manganese participates in numerous and diverse reactions in soils, including oxidation and reduction (redox), ion exchange, specific adsorption, and solubility equilibria. The distribution of Mn between solution and solid phases is intimately related to the pH, redox conditions, and the characteristics of ligands and surfaces. Manganese(II) is the predominant form found in solution and in association with exchange sites on soil surfaces, while Mn(III) and Mn(IV) are found predominately in a variety of oxide-rich solid phases. The emphasis of this chapter is on the solution and surface reactions of Mn2+ and the Mn oxides, including reactions associated with fertilizer additions. Chapters 4 and 5 provide greater emphasis on redox processes and cycles in soils, but the effects of redox on mineral solubility relationships and on several surface reactions are covered here.

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References

  1. Adams SN, Honeysett JL and Tiller KG 1969 Factors controlling the increase in cobalt in plants following the addition of a cobalt fertiliser. Aust. J. Soil Res. 7, 29–42

    CAS  Google Scholar 

  2. Alberts JJ, Schindler JE, Nutter DE and Davis E 1976 Elemental, infra-red spectrophotometric and electron spin resonance investigations of non-chemically isolated humic material. Geochim. Cosmochim. Acta 40, 369–372

    CAS  Google Scholar 

  3. Asghar M and Kanehiro Y 1981 The fate of applied iron and manganese in an oxisol and an ultisol from Hawaii. Soil Sci. 131,53–55

    CAS  Google Scholar 

  4. Balistrieri L and Murray JW 1982 The surface chemistry of δMnO2 in major ion seawater. Geochim. Cosmochim. Acta 46,1041–1052

    CAS  Google Scholar 

  5. Bartlett R and James B 1979 Behavior of chromium in soils: III. Oxidation. J. Environ. Qual. 8, 31–35

    CAS  Google Scholar 

  6. Bartlett RJ 1981 Nonmicrobial nitrite-to-nitrate transformation in soils. Soil Sci. Soc. Am. J. 45, 1054–1058

    CAS  Google Scholar 

  7. Bartlett RJ 1986 Soil redox behavior. In Soil Physical Chemistry. Ed. DL Sparks, pp 179–207. CRCPress, BocaRaton, Florida

    Google Scholar 

  8. Bleam WF and McBride MB 1985 Cluster formation versus isolated-site adsorption. A study of Mn(II) and Mg(II) adsorption on boehmite and goethite. J. Colloid Interface Sci. 103,124–132

    CAS  Google Scholar 

  9. Bloom PR 1981 Metal-organic matter interactions in soil. In Chemistry in the Soil Environment. Eds. RH Dowdy, JA Ryan, VV Volk and DE Baker, pp 129–150. American Society of Agronomy, Madison, Wisconsin

    Google Scholar 

  10. Bohn HL 1979 Comparisons of measured and theoretical Mn2+ concentrations in soil suspensions. Soil Sci. Soc. Amer. Proa 34, 195–197

    Google Scholar 

  11. Boxma R and DeGroot AJ 1985 Development and effectiveness of a soluble manganese silicate compound in controlling manganese deficiency in plants. Plant Soil 83,411–417

    CAS  Google Scholar 

  12. Boyle FW Jr and Lindsay WL 1986 Manganese phosphate equilibrium relationships in soils. Soil Sci. Soc. Am. J. 50, 588–593

    Google Scholar 

  13. Burns RG 1976 The uptake of cobalt into ferromanganese nodules, soils, and synthetic manganese (IV) oxides. Geochim. Cosmochim. Acta 40, 95–102

    CAS  Google Scholar 

  14. Camerlynck R and Kiekens L 1982 Speciation of heavy metals in soils based on charge separation. Plant Soil 68, 331–339

    CAS  Google Scholar 

  15. Carpenter R 1983 Quantitative electron spin resonance (ESR) determinations of forms and total amounts of Mn in aqueous environmental samples. Geochim. Cosmochim. Acta 47, 875–885

    CAS  Google Scholar 

  16. Cheng BT and Ouellette GJ 1968 Effect of various anions on manganese toxicity in Solanum tuberosum. Can. J. Soil Sci. 48, 109–115

    CAS  Google Scholar 

  17. Cheng BT and Ouellette G J 1971 Manganese availability in soil. Soils and Fertilizers 34, 589–595

    Google Scholar 

  18. Chukhrov FV, Gorshkov AI, Rudnitskaya ES, Beresovskaya VV and Sivtsov AV 1980 Manganese minerals in clays: A review. Clays Clay Min. 28, 346–354

    CAS  Google Scholar 

  19. Cottenie A and Kiekens L 1972 Exchange of Zn, Mn, Cu and Fe in relation to saturation of the soil complex. In Potassium in Soil. Proceedings of the 9th Colloquium of the International Potash Institute. pp 113–123

    Google Scholar 

  20. Cotton FA and Wilkinson G 1966 Advanced Inorganic Chemistry. Interscience Publishers, New York

    Google Scholar 

  21. Coughlin RW and Matsui I 1976 Catalytic oxidation of aqueous Mn(II). J. Catal. 41,108–123

    Google Scholar 

  22. Cressy PJ, Monk GR, Powell HKJ and Tennent DJ 1983 Fulvic acid studies: evidence for a polycarboxylate co-ordination mode at soil pH. J. Soil Sci. 34, 783–799

    Google Scholar 

  23. Curtin D, Ryan J and Chaudhary RA 1980 Manganese adsorption and desorption in calcareous Lebanese soils. Soil Sci. Soc. Am. J. 44, 947–950

    CAS  Google Scholar 

  24. Curtin D and Smillie GW 1983 Soil solution composition as affected by liming and incubation. Soil Sci. Soc. Am. J. 47, 701–707

    CAS  Google Scholar 

  25. Davies G 1969 Some aspects of the chemistry of manganese(III) in aqueous solution. Coordin. Chem. Rev. 4, 199–224

    CAS  Google Scholar 

  26. Davies SHR 1986 Mn(II) oxidation in the presence of lepidocrocite: The influence of other ions. In Geochemical Processes at Mineral Surfaces. Ed. M J Comstock. pp 487–502. American Chemical Society, Ann Arbor, Michigan

    Google Scholar 

  27. Dayanand D and Sinha MK 1984 Solubility of native forms of iron, manganese, copper and zinc in calcareous soils. Indian Soc. Soil Sci. 32,427–436

    CAS  Google Scholar 

  28. Deczky K and Langford CH 1977 Applications of water nuclear magnetic resonance relaxation times to study of metal complexes of the soluble soil organic fraction fulvic acid. Can. J. Chem. 56, 1947–1951

    Google Scholar 

  29. Diem D and Stumm W 1984 Is dissolved Mn2+ being oxidized by O2 in absence of Mn-bacteria or surface catalysts?. Geochim. Cosmochim. Acta 48, 1571–1573

    CAS  Google Scholar 

  30. Dillard JG and Crowther DL 1982 The oxidation states of cobalt and selected metals in Pacific ferromanganese nodules. Geochim. Cosmochim. Acta 46,755–759

    CAS  Google Scholar 

  31. Dion HG and Mann PJG 1946 Three-valent manganese in in soils. J. Agrie. Sci. 36, 239–245

    CAS  Google Scholar 

  32. Eary LE and Ral D 1987 Kinetics of chromium(III) oxidation to chromium(VI) by reaction with manganese oxide. Environ. Sci. Technol. 21,1187–1193

    Google Scholar 

  33. Farrah S, Slavek J and Pickering WF 1985 Fluoride sorption by soil components: calcium carbonate, humic acid, manganese dioxide and silica. Aust. J. Soil Res. 23,429–439

    CAS  Google Scholar 

  34. Fitts JB, Gammon N Jr and Forbes RB 1967 Relative availability of manganese from several sources. Proc. Soil Crop Soc. Florida 27, 243–251

    CAS  Google Scholar 

  35. Forbes EA, Posner AM and Quirk JP 1976 The specific adsorption of divalent Cd, Co, Cu, Pb, and Zn on goethite. J. Soil Sci. 27, 154–166

    CAS  Google Scholar 

  36. Fujimoto CK and Sherman GD 1948 Behavior of manganese in the soil and the manganese cycle. Soil Sci. 66, 131–145

    CAS  Google Scholar 

  37. Gadde RR and Laitinen HA 1974 Studies of heavey metal adsorption by hydrous iron and manganese oxides. Anal. Chem. 46, 2022–2026.

    CAS  Google Scholar 

  38. Gamble DS, Langford CH and Tong JPK 1976 The structure and equilibria of a manganese(II) complex of fulvic acid studies by ion exchange and nuclear magnetic resonance.Can.J.Chem.54,1239–1245

    CAS  Google Scholar 

  39. Gamble DS, Schnitzer M and Skinner DS 1977 MnII-fulvic acid complexing equilibrium measurements by electron spin resonance spectrometry. Can. J. Soil Sci. 57,47–53

    CAS  Google Scholar 

  40. Geering HR, Hodgson F and Sdano C 1969 Micronutrient cation complexes in soil solution: IV. The chemical state of manganese in soil solution. Soil Sci. Soc. Amer. Proc. 33, 81–85

    CAS  Google Scholar 

  41. Giordano PM and Mortvedt JJ 1969 Phosphorus availability to corn as affected by granulating manganese with ortho- and pyrophosphate fertilizers. Soil Sci. Soc. Amer. Proc. 33,460–463

    CAS  Google Scholar 

  42. Golden DC, Dixon JB and Chen CC 1986 Ion exchange, thermal transformations, and oxidizing properties of birnessite. Clays Clay Min. 34, 511–520

    CAS  Google Scholar 

  43. Gotoh S and Patrick WH Jr 1972 Transformation of manganese in a waterlogged soil as affected by redox potential an pH. Soil Sci. Soc. Amer. Proc. 36, 738–742

    Google Scholar 

  44. Grasmanis VO and Leeper GW 1966 Toxic manganese in near-neutral soils. Plant Soil 25,41–48

    CAS  Google Scholar 

  45. Grimme H 1968 Die adsorption von Mn, Co, Cu und Zn durch goethit aus verdünnten losungen. Z. Pflanzenernaehr. Bodenk. 121,58–65

    CAS  Google Scholar 

  46. Hamilton HA 1966 Effect of nitrogenous and potassic salts with phosphates on the yield and phosphorus, nitrogen, potassium, and manganese contents of oats (Avena sativa L.). Soil Sci. Soc. Amer. Proc. 30, 239–242

    CAS  Google Scholar 

  47. Hamilton HA and Lathwell DJ 1965 Influence of salts in association with monocalcium and diammonium phosphates on the chemical characteristics and movement of soil solution. Can. J. Soil Sci. 45,139–152

    CAS  Google Scholar 

  48. Healy TW, Herring AP and Fuerstenau DW 1966 The effect of crystal structure on the surface properties of a series of manganese dioxides. J. Colloid Interface Sci. 21,435–444

    CAS  Google Scholar 

  49. Hem JD 1978 Redox processes at surfaces of manganese oxide and their effects on aqueous metal ions. Chem. Geol. 21, 199–218

    CAS  Google Scholar 

  50. Hem JD 1981 Rates of manganese oxidation in aqueous systems. Geochim. Cosmochim. Acta 45, 1369–1374

    CAS  Google Scholar 

  51. Hem JD, Roberson CE and Lind CJ 1985 Thermodynamic stability of CoOOH and it coprecipitation with manganese. Geochim. Cosmochim. Acta 49, 801–810

    CAS  Google Scholar 

  52. Hem JD, Roberson CE and Rournier RB 1982 Stability of ßMnOOH and manganese oxide deposition from springwater. Water Resources Res. 18, 563–570

    CAS  Google Scholar 

  53. Hodgson JF 1963 Chemistry of the micronutrient elements in soils. Adv. Agron. 35, 119–159

    Google Scholar 

  54. Hossner LR and Blanchar RW 1970 Manganese reactions and availability as influenced by pH and pyrophosphate content of ammonium phosphate fertilizers. Soil Sci. Soc. Amer. Proc. 34, 509–512

    CAS  Google Scholar 

  55. Hossner LR and Richards GE 1968 The effect of phosphorus source on the movement and uptake of band applied manganese. Soil Sci. Soc. Amer. Proc. 32, 83–85

    CAS  Google Scholar 

  56. Jackson TL, Westermann DT and Moore DP 1966 The effect of chloride and lime on the manganese uptake by bush beans and sweet corn. Soil Sci. Soc. Amer. Proc. 30, 70–73

    CAS  Google Scholar 

  57. James RO and Healy TW 1972 Adsorption of hydrolyzable metal ions at the oxide-water interface. I. Co(II) adsorption on SiO2 and TiO2 as model systems. J. Colloid Interface Sci. 40, 42–52

    CAS  Google Scholar 

  58. Jarvis SC 1984 The association of cobalt with easily reducible manganese in some acidic permanent grassland soils. J. Soil Sci. 35, 431–438

    CAS  Google Scholar 

  59. Jenne EA 1968 Contois on Mn, Fe, Co, Ni, Cu, and Zn concentrations in soils and water: the significant role of hydrous Mn and Fe oxides. In Trace Inorganics in Water, Adv. Chem. Ser. No.73. Ed. RF Gould. pp 337–387. American Chemical Society, Washington, DC

    Google Scholar 

  60. Kerndorff H and Schnitzer M 1980 Sorption of metals on humic acid. Geochim. Cosmochim. Acta 44, 1701–1708

    CAS  Google Scholar 

  61. Khanna PK and Mishra B 1978 Behavior of manganese in some acid soils in western Germany in relation to pH and air-drying. Geoderma 20,289–297

    CAS  Google Scholar 

  62. Kinniburgh DG and Jackson ML 1981 Cation adsorption by hydrous metal oxides and clay. In Adsorption of Inorganics at Solid-Liquid Interfaces. Eds. M A Anderson and A J Rubin, pp 91–160. Ann Arbor Science Publishers, Inc., Ann Arbor,Michigan

    Google Scholar 

  63. Knezek BD and Greinert H 1971 Influence of soil iron and manganese EDTA interactions upon the iron and manganese nutrition of bean plants. Agron. J. 63, 617–619

    CAS  Google Scholar 

  64. Krishnamurti GSR and Huang PM 1987 The catalytic role of birnessite in the transformation of iron. Can. J. Soil Sci. 67, 533–543

    CAS  Google Scholar 

  65. Kubota J and Allaway WH 1972 Geographic distribution of trace element problems. In Micronutrients in Agriculture. Eds. JJ Mortvedt, PM Giordano and WL Lindsay, pp 525–554.Soil Science Society of America, Madison, Wisconsin

    Google Scholar 

  66. Kurdi F and Doner HE 1983 Zinc and copper sorption and interaction in soils. Soil Sci. Soc. Am. J. 47, 873–876

    CAS  Google Scholar 

  67. Lakatos B, Tibai T and Meisel J 1977 EPR spectra of humic acids and their metal complexes. Geoderma 19, 319–338

    CAS  Google Scholar 

  68. Langford CH Gamble DS Underdown AW and Lee S 1983 Interaction of metal ions with a well characterized fulvic acid. In Aquatic and Terrestrial Humic Materials. Eds.RF Christman and ET Gjessing. pp 219–237. Ann Arbor Science Publishers, Ann Arbor, ML

    Google Scholar 

  69. Leeper GW 1947 The forms and reactions of manganese in the soil. Soil Sci. 63,79–94

    CAS  Google Scholar 

  70. Lehr JR 1972 Chemical reactions of micronutrients in fertilizers. In Micronutrients in Agriculture. Eds. JJ Mortvedt, PM Giordano and WL Lindsay, pp 459–503. Soil Science Society of America, Inc., Madison, Wisconsin

    Google Scholar 

  71. Lind CJ 1988 Hausmannite (Mn3O4) conversion to manganite (γ-MnOOH) in dilute oxalate. Environ. Sci. Technol. 22, 62–70

    CAS  Google Scholar 

  72. Lindsay WL 1979 Chemical Equilibria in Soils. John Wiley & Sons, Inc., New York

    Google Scholar 

  73. Lindsay WL and Stephenson HF 1959 Nature of the reactions of monocalcium phosphate monohydrate n soils: I. The solution that reacts with the soil. Soil Sci. Soc. Amer. Proc. 23, 12–18

    CAS  Google Scholar 

  74. Loganathan P and Burau RG 1973 Sorption of heavy metal ions by a hydrous manganese oxide. Geochim. Cosmochim. Acta 37,1277–1293

    CAS  Google Scholar 

  75. Loganathan P, Burau RG and Fuerstenau DW 1977 Influence of pH on the sorption of Co2+, Zn2+ and Ca2+ by a hydrous manganese oxide. Soil Sci. Soc. Amer. J. 41, 57–62

    CAS  Google Scholar 

  76. Manceau A, Llorca S and Calas G 1987 Crystal chemistry of cobalt and nickel in lithiophorite and asbolane from New Caldonia. Geochim. Cosmochim. Acta 51,105–113

    CAS  Google Scholar 

  77. Mantoura RFC, Dickson A and Riley JP 1978 The complexation of metals with humic materials in natural waters. Estuar. Coast. Mar. Sci. 6, 387–408

    CAS  Google Scholar 

  78. Marinsky JA 1987 A two-phase model for the interpretation of proton and metal ion interaction with charged polyelectrolyte gels and their linear analogs. In Aquatic Surface Chemistry: Chemical Processes at the Particle-Water Interface. Ed. W Stumm, pp 49–81. John Wiley & Sons, Inc., New York

    Google Scholar 

  79. Mascagni HJ Jr and Cox FR 1985 Evaluation of inorganic and organic manganese fertilizer sources. Soil Sci. Soc. Amer. Proc. 49,459–461

    Google Scholar 

  80. McBride MB 1979 Chemisorption and precipitaion of Mn2+ at CaCO3 surfaces. Soil Sci. Soc. Am. J. 43, 693–698

    CAS  Google Scholar 

  81. McBride B 1982 Electron spin resonance investigation of Mn2+ complexation in natural and synthetic organics. Soil Sci. Soc. Am. J. 46, 1137–1143

    CAS  Google Scholar 

  82. McBride B 1988 Reactions controlling heavy metal solubility in soils. In Advances in Soil Science. Ed. BA Stewart. Springer-Verlag, New York

    Google Scholar 

  83. McBride MB, Pinnavaia TJ and Mortland M 1975 Electron spin resonance studies of cation orientation in restricted water layer on phyllosilicate (smectite) surfaces. J. Phys. Chem. 79, No. 22,2430–2435

    CAS  Google Scholar 

  84. McKenzie RM 1970 The reaction of cobalt with manganese dioxide minerals. Aust. J. Soil Res. 8, 97–106

    CAS  Google Scholar 

  85. McKenzie RM 1975 The mineralogy and chemistry of soil cobalt. In Trace Elements in Soil-Plant-Animal Systems. Eds. DJD Nicholas and AR Egan. pp 83–93. Academic Press, New York

    Google Scholar 

  86. McKenzie RM 1977 Manganese oxides and hydroxides. In Minerals in Soil Environments. Eds. JB Dixon and SB Weed, pp 181–193. Soil Science Society of America, Madison, Wisconsin

    Google Scholar 

  87. McKenzie RM 1978 The effect of two manganese dioxides on the uptake of lead, cobalt, nickel, copper and zinc by subterranean clover. Aust. J. Soil Res. 16, 209–214

    CAS  Google Scholar 

  88. McKenzie RM 1979 Proton release during adsorption of heavy metal ions by a hydrous manganese dioxide. Geochim. Cosmochim. Acta 43,1855–185

    CAS  Google Scholar 

  89. McKenzie RM 1980 The adsorption of lead and other heavy metals on oxides of manganese and iron. Aust. J. Soil Res. 18, 61–73

    CAS  Google Scholar 

  90. McKenzie RM 1981 The surface charge on manganese dioxides. Aust. J. Soil Res. 19,41–50

    CAS  Google Scholar 

  91. McKenzie RM 1983 The adsorption of molybdenum on oxide surfaces. Aust. J. Soil Res. 21(4), 505–51

    CAS  Google Scholar 

  92. McLaren RG, Lawson DM and Swift RS 1986 Sorption and desorption of cobalt by soils and soil components. J. Soil Sci. 37, 413–426

    CAS  Google Scholar 

  93. Miner GS, Traore S and Tucker MR 1986 Corn response to starter fertilizer acidity and manganese materials varying in water solubility. Agron. J. 78, 291–295

    CAS  Google Scholar 

  94. Morgan JJ 1967 Chemical equilibria and kinetic properties of manganese in natural waters. In Principles and Applications of Water Chemistry. Eds.SD Faust and JV Hunter, pp 561–624. John Wiley & Sons, Inc., New York

    Google Scholar 

  95. Mortvedt JJ and Giordano PM 1970 Manganese movement from fertilizer granules in various soils. Soil Sci. Soc. Amer. Proc. 34, 330–334

    CAS  Google Scholar 

  96. Mortvedt JJ and Giordano PM 1975 Crop response to manganese sources applied with ortho- and polyphosphate fertilizers. Soil Sci. Soc. Amer. Proc. 39, 782–787

    CAS  Google Scholar 

  97. Mulder EG and Gerretsen FC 1952 Soil manganese in relation to plant growth. Adv. Agron. 4,221–279

    CAS  Google Scholar 

  98. Murphy LS and Walsh LM 1972 Correction of micronutrient deficiencies with fertilizers. In Micronutrients in Agriculture. Eds. JJ Mortvedt, PM Giordano and WL Lindsay, pp 347–387. Soil Science Society of America, Inc., Madison, Wisconsin

    Google Scholar 

  99. Murray JW 1975 The interaction of metal ions at the manganese dioxide-solution interface. Geochim. Cosmochim. Acta 39, 505–519

    CAS  Google Scholar 

  100. Murray JW and Dillard JG 1979 The oxidation of cobalt(II) adsorbed on manganese dioxide. Geochim. Cosmochim. Acta 43,781–787

    CAS  Google Scholar 

  101. Murray JW, Dillard JG, Giovanoli R, Moers H and Stumm W 1985 Oxidation of Mn(II): Initial mineralogy, oxidation state and ageing. Geochim. Cosmochim. Acta 49,463–470

    CAS  Google Scholar 

  102. Nordstrom DK, Plummer LN, Wigley TML, Wolery TJ, Ball JW, Hoffman M, Holdren GR Jr, Lafrom GM, Mattigod SV, McDuff RE, Morel F, Reddy MM, Sposito G and Thrailkill J 1979 A comparison of computerized chemical models for equilibrium calculations in aqueous systems. In Chemical Modeling in Aqueous Systems. Ed. EA Jenne. pp 857–892. American Chemical Society, Washington, DC

    Google Scholar 

  103. Norvell WA 1972 Equilibria of metal chelates in soil solution. In Micronutrients in Agriculture. Eds. JJ Mortvedt, PM Giordano and WL Lindsay, pp 115–138. Soil Science Society of America, Inc., Madison, Wisconsin

    Google Scholar 

  104. Norvell WA 1980 Surface reactions of heavy metals with clays, oxides and humic substances. In Agrochemicals in Soils. Eds. A Banin and U Kafkafi. pp 315–336. International Irrigation Information Center, Bet Dagan, Israel

    Google Scholar 

  105. Olomu MO, Racz G J and Cho CM 1973 Effect of flooding on the Eh, pH, and concentrations of Fe and Mn in several Manitoba soils. Soil Sci. Soc. Amer. J. 37, 220–224

    CAS  Google Scholar 

  106. Oscarson DW, Huang PM, Liaw WK and Hammer UT 1983 Kinetics fo oxidation of arsenite by various manganese dioxides. Soil Sci. Soc. Am. J. 47, 644–648

    CAS  Google Scholar 

  107. Page ER 1962 Studies in soil and plant manganese. II. The relationship of soil pH to Manganese availability. Plant Soil 26, 247–257

    Google Scholar 

  108. Parks GA 1965 The isoelectric points of solid oxides, solid hydroxides, and aqueous hydroxo complex systems. Chem. Rev. 65, 177–198

    CAS  Google Scholar 

  109. Pasricha NS and Ponnamperuma FN 1976 Influence of salt and alkali on ionic equilibria in submerged soils. Soil Sci. Soc. Am. J. 40, 374–376

    CAS  Google Scholar 

  110. Passioura JB and Leeper GW 1963 Available manganese and the X hypothesis. Agrochimica 8,81–90

    CAS  Google Scholar 

  111. Pétrie SE and Jackson TL 1984 Effects of fertilization on soil solution pH and manganese concentration. Soil Sci. Soc. Am. J. 48(2), 315–318

    Google Scholar 

  112. Ponnamperuma FN 1972 The chemistry of submerged soils. Adv. Agron. 24, 29–96

    CAS  Google Scholar 

  113. Ponnamperuma FN, Loy TA and Tianco EM 1969 Redox equilibria in flooded soils: II. The manganese oxide systems. Soil Sci. 108, 48–57

    CAS  Google Scholar 

  114. Posselt HS, Anderson FJ and Weber WJ 1968 Cation sorption on colloidal hydrous manganese dioxide. Environ. Sci. Technol. 2, 1087–1093

    CAS  Google Scholar 

  115. Postma D 1985 Concentration of Mn and separation from Fe in sediments-I. Kinetics and stoichiometry of the reaction between birnessite and dissolved Fe(II) at 10°C. Geochim. Cosmochim. Acta 49,1023–1033

    CAS  Google Scholar 

  116. Ross DS and Bartlett RJ 1981 Evidence for nonmicrobial oxidation of manganese in soil. Soil Sci. 132, 153–159

    CAS  Google Scholar 

  117. Sanders JR 1983 The effect of pH on the total and free ionic concentrations of manganese, zinc and cobalt in soil solutions. J. Soil Sci. 34, 315–323

    CAS  Google Scholar 

  118. Schnitzer M and Khan SU 1972 Humic Substances in the Environment. Marcel Dekkerjnc, New York

    Google Scholar 

  119. Schnitzer R and Hansen EH 1970 Organo-metaliic interactions in soils: 8. An evaluation of methods for the determination of stability constants of metal-fulvic acid complexes. Soil Sci. 109, 333–340

    CAS  Google Scholar 

  120. Schwab AP and Lindsay WL 1983 The effect of redox on the solubility and availability of manganese in a calcareous soil. Soil Sci. Soc. Am. J. 47, 217–220

    CAS  Google Scholar 

  121. Sherman GD and Harmer PH 1943 The manganous-manganic equilibrium of soils. Soil Sci. Soc. Amer. Proa 7, 398–405

    CAS  Google Scholar 

  122. Sherman GD, McHargue JS and Hageman RH 1943 The influence of halides on the oxidation of manganese in soil. Soil Sci. 56, 127–134

    CAS  Google Scholar 

  123. Shuman LM, Boswell FC, Ohki K, Parker MB and Wilson DO 1979 Soybean yield, leaf manganese, and soil manganese as affected by sources and rates of manganese and soil pH. Agron. J. 71,989–991

    CAS  Google Scholar 

  124. Singh AK and Subramanian V 1984 Hydrous Fe and Mn oxides-scavengers of heavy metals in the aquatic environment. Crit Rev. Environ. Contr. 14, 33–90

    Google Scholar 

  125. Sposito G and Mattigod SV 1979 Geochem: A Computer Program for the Calculation of Chemical Equilibria in Soil Solutions and other Natural Water Systems. Kearney Foundation of Soil Science, Riverside, California

    Google Scholar 

  126. Stevenson FJ 1982 Humus Chemistry. Genesis, Composition, Reactions. John Wiley & sons, Inc., New York

    Google Scholar 

  127. Stumm W, Huang CP and Jenkins SR 1970 Specific chemical interaction affecting the stability of dispersed systems. Croat. Chem. Acta 42,223–245

    CAS  Google Scholar 

  128. Stumm W and Morgan JJ 1981 Aquatic Chemistry. An Introduction Emphasizing Chemical Equilibria in Natural Waters. John Wiley & Sons, New York, New York

    Google Scholar 

  129. Taylor RM and McKenzie RM 1966 The assoication of trace elements with manganese minerals in Australian soils. Aust. J. Soil Res. 4, 29–39

    CAS  Google Scholar 

  130. Traina SJ and Doner HE 1985 Co, Cu, Ni, and Ca sorption by a mixed suspension of smectite and hydrous manganese dioxide. Clays Clay Min. 33,118–122

    CAS  Google Scholar 

  131. Traina SJ and Doner HE 1988 Heavy metal induced releases of manganese (II) from a hydrous manganese dioxide. Soil Sci. Soc. Am. J. 49, 317–321

    Google Scholar 

  132. Van der Weijden CH and Kruissink EC 1977 Some geochemical controls on lead and barium concentrations in ferromanganese deposits. Mar. Chem. 5,93–112

    Google Scholar 

  133. Van Dijk H 1971 Cation binding of humic acids. Geoderma 5, 53–67

    Google Scholar 

  134. Voth RD and Christenson DR 1980 Effect of fertilizer reaction and placement on availability of manganese. Agron. J. 72,769–773

    CAS  Google Scholar 

  135. Wada H, Seirayosakol A, Kimura M and Takai Y 1978 The process of manganese deposition in paddy soils. I. A hypothesis and its verification. Soil Sci. Plant Nutr. 24, 55–62

    CAS  Google Scholar 

  136. Wagman DD, Evans WH, Parker VB, Halow I, Bailey SM and Schumm RH 1968 Selected values of chemical thermodynamic properties. NBS Technical Note 270–3. Superintendent of Documents, U.S. Government Printing Office, Washington, DC

    Google Scholar 

  137. Westall JC 1986 Reactions at the oxide-solution interface: Chemical and electrostatic models. In Geochemical Processes at Mineral Surfaces. Ed. MJ Comstock. pp 54–78. American Chemical Society, Washington,DC

    Google Scholar 

  138. Westermann DT, Jackson TL and Moore DP 1971 Effect of potassium salts on extractable soil manganese Soil Sci. Soc. Amer. Proa 35,43–46

    CAS  Google Scholar 

  139. White GN and Zelazny LW 1986 Charge properties of soil colloids. In Soil Physical Chemistry. Ed. DL Sparks, pp 39–81. CRC Press, Inc., Boca Raton, Florida

    Google Scholar 

  140. Wilson D 1980 Surface and complexation effects on the rate of Mn(II) oxidation in natural waters. Geochim. Cosmochim. Acta 44,1311–1317

    CAS  Google Scholar 

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  1. W. A. Norvell
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Editor information

Editors and Affiliations

  1. Department of Agronomy, Waite Agricultural Research Institute, University of Adelaide, Glen Osmond, Australia

    Robin D. Graham

  2. Northfield Laboratories, South Australian Department of Agriculture, Adelaide, Australia

    Robert J. Hannam

  3. School of Agriculture, La Trobe University, Bundoora, Australia

    Nicholas C. Uren

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© 1988 Kluwer Academic Publishers

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Norvell, W.A. (1988). Inorganic Reactions of Manganese in Soils. In: Graham, R.D., Hannam, R.J., Uren, N.C. (eds) Manganese in Soils and Plants. Developments in Plant and Soil Sciences, vol 33. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2817-6_4

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  • DOI: https://doi.org/10.1007/978-94-009-2817-6_4

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7768-2

  • Online ISBN: 978-94-009-2817-6

  • eBook Packages: Springer Book Archive

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