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The Reactions of Mo(NtBu)(=CHtBu)(CH2But)2 With Alcohols: Competition Between Molybdenum to Carbon Single and Double Bond Reactivities

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Advances in Metal Carbene Chemistry

Part of the book series: NATO ASI Series ((ASIC,volume 269))

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Abstract

The reactions of Mo(NtBu)(=CHtBu)(CH2But)2 with a series of alcohols are investigated. Depending on the nature of the alcohol ROH, three organometallic products are observed a) Mo(NtBu)(=CHtBu) (OR)(CH2 tBu), b)Mo(NtBu)(OR)(CH2 tBu)3 and c) Mo(NtBu)(OR)(OR’)(CH2 tBu)2. The mechanism of formation of these products is discussed.

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References

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Author information

Authors and Affiliations

  1. Institut Le Bel, Université Louis Pasteur, 67000, Strasbourg, France

    J. Kress, J. A. Osborn & G. Schoettel

Authors
  1. J. Kress
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  2. J. A. Osborn
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  3. G. Schoettel
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Editor information

Editors and Affiliations

  1. Institute for Inorganic Chemistry, University of Würzburg, Würzburg, Germany

    U. Schubert

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© 1989 Kluwer Academic Publishers

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Kress, J., Osborn, J.A., Schoettel, G. (1989). The Reactions of Mo(NtBu)(=CHtBu)(CH2But)2 With Alcohols: Competition Between Molybdenum to Carbon Single and Double Bond Reactivities. In: Schubert, U. (eds) Advances in Metal Carbene Chemistry. NATO ASI Series, vol 269. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2317-1_34

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  • DOI: https://doi.org/10.1007/978-94-009-2317-1_34

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7541-1

  • Online ISBN: 978-94-009-2317-1

  • eBook Packages: Springer Book Archive

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