Abstract
Compounds with alkyiidyne ligands bridging heteronuclear metal-metal bonds provide an opportunity to study the chemistry of μ-CR (R = alkyl or aryl) groups in a variety of different electronic and steric environments. Reactivity patterns are strongly influenced both by the nature of the group R, and by the metal-ligand fragments with which the μ-CR ligands are associated. Discussion will focus on reactions in which the alkylidyne fragment is converted into an alkylidene group. Often the alkyiidyne to alkylidene step is followed by further transformations leading to products of many different structural types.
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Gordon, F., Stone, A. (1989). Carbyne to Carbene Conversion Reactions at Heteronuclear Dimetal Centres. In: Schubert, U. (eds) Advances in Metal Carbene Chemistry. NATO ASI Series, vol 269. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2317-1_2
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DOI: https://doi.org/10.1007/978-94-009-2317-1_2
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