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High-Resolution Solid-State NMR Investigations of the Lattice Structures of Zeolite Catalysts and Sorbents

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Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications

Part of the book series: NATO ASI Series ((ASIC,volume 322))

Abstract

In this chapter the information which can be obtained regarding the lattice structures of zeolite catalysts and sorbents from high-resolution solid-state NMR investigations will be considered. In general, as with many other solid-state systems the results are complementary to those from X-ray diffraction measurements. Particular emphasis will be placed on the integration of data from these two sources for a better and more complete description of the structures.

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References

  1. W.M. Meier, in Molecular Sieves, Soc. Chem. Ind. London, (1968).

    Google Scholar 

  2. D.W. Breck, Zeolite Molecular Sieves, Wiley Interscience, (1974).

    Google Scholar 

  3. J.V. Smith, Zeolite Chemistry and Catalysis, Ed.J.A., Rabo, ACS Monograph. 171, (1976).

    Google Scholar 

  4. R.M. Barrer, Zeolites and Clay Minerals as Sorbents and Molecular Sieves, Acad. Press, London, (1978).

    Google Scholar 

  5. W.M. Meier, and D.H. Olson, Atlas of Zeolite Structure Types, Structure Commission of the International Zeolite Association, (1978).

    Google Scholar 

  6. It has recently been demonstrated that the use of synchrotron X-ray sources permits single crystal studies to be carried out on much smaller samples. P. Eisenberger, J.B. Newsam, M.E. Leonowicz, D.E.W. Vaughan, Nature, 45, 309 (1984).

    Google Scholar 

  7. The use of Rietveld refinement techniques allows better structural information to be obtained from powder diffraction data. W.I.F. David, W.T.A. Harrison, M.W. Johnson. High Resolution Powder Diffraction, Materials Science Forum, vol. 9, Ed. Catlow, C.R.A.; 89–101, Trans. Tech. Publication Andermannsdorf, Switzerland.

    Google Scholar 

  8. C.A. Fyfe, G.C. Gobbi, J.S. Hartman, R.E. Lenkinski, J.H. O’Brien, E.R. Beange, and M.A.R. Smith, J. Mag. Res., 47, 168 (1982).

    CAS  Google Scholar 

  9. E. Lippmaa, M. Magi, A. Samoson, A.R. Grimmer, and G. Engelhardt, J. Am. Chem. Soc., 102, 4889 (1980).

    Article  CAS  Google Scholar 

  10. E. Lippmaa, M. Magi, A. Samoson, M. Tarmak, and G. Engelhardt, J. Am. Chem. Soc. 103, 4992 (1981).

    Article  CAS  Google Scholar 

  11. C.A. Fyfe, J.M. Thomas, J. Klinowski, and C.G. Gobbi, Angew, Chem. 95, 257 (1983), and Angew Chem. Int. Ed. 22, 259 (1983).

    Article  CAS  Google Scholar 

  12. A recent and very complete compilation of the results of NMR studies of zeolites is given in: G. Engelhardt, D. Michel, High Resolution Solid State NMR of Zeolites and Related Systems, John Wiley & Sons, (1987).

    Google Scholar 

  13. J. Klinowski, S. Ramdas, J.M. Thomas, C.A. Fyfe, and J.S. Hartmann, J. Chem. Soc., Farad Trans. 2, 78, 1025 (1983).

    Article  Google Scholar 

  14. C.A. Fyfe, G.C. Gobbi, G.J. Kennedy, J.D. Graham, R.Z. Ozubko, W.J. Murphy, A. Bothner-By, J. Dadok, and A.S. Chesnik, Zeolites, 5, 179 (1985).

    Article  CAS  Google Scholar 

  15. J. Klinowski, J.M. Thomas, C.A. Fyfe, G.C. Gobbi, and J.S. Hartman, Inorg. Chem. 22, 63 (1983).

    Article  CAS  Google Scholar 

  16. G. Engelhardt, in reference (6b) p. 349 (1987).

    Google Scholar 

  17. G. Boxhoorn, R.A. van Santen, W.A. van Erp, G.R. Huis, and D. Clague, J. Chem. Soc., Chem. Commun. 264 (1982).

    Google Scholar 

  18. K.F.M.G.J. Scholle, Ph. D. Thesis, Nijmegen (1985).

    Google Scholar 

  19. K.F.M.G.J. Scholle, W.S. Veeman, Zeolite,, 5, 118 (1985)..

    Article  CAS  Google Scholar 

  20. H.K.C. Timken, G.L. Turner, J.P. Gilson, L.B. Welsh, and E. Oldfield, J. Am. Chem. Soc., 108, 7231 (1986).

    Article  CAS  Google Scholar 

  21. D. Freude, M. Hunger, and H. Pfeifer, Chem. Phys. Lett. 91, 307 (1982).

    Article  CAS  Google Scholar 

  22. D. Freude, Adv. Colloid Interace Sci., 23, 21 (1985).

    Article  CAS  Google Scholar 

  23. H. Pfeifer, D. Freude, and M. Hunger, Zeolites, 5, 273 (1985).

    Article  Google Scholar 

  24. G. Engelhardt, U. Lohse, A. Samoson, M. Magi, M. Tarmak, and E. Lippmaa, Zeolites, 2, 59 (1985).

    Article  Google Scholar 

  25. C.A. Fyfe, G.C. Gobbi, A. Putnis, J.M. Thomas, and J. Klinowski, J. Chem. Soc. Chem. Comm. 556 (1983).

    Google Scholar 

  26. A. Putnis, E. Salje, S.A.T. Redfern, C.A. Fyfe, and H. Strobl, Phys. Chem. Minerals 14, 446 (1987).

    Article  CAS  Google Scholar 

  27. C.A. Fyfe, G.C. Gobbi, and A. Putnis, J. Amer. Chem. Soc. 108, 3218 (1986).

    Article  CAS  Google Scholar 

  28. W. Loewenstein, Amer. Mineralog. 39, 92 (1954).

    CAS  Google Scholar 

  29. C.A. Fyfe, G.T. Kokotailo, G.J. Kennedy, G.C. Gobbi, C.T. DeSchutter, R.S. Ozubko and W.J. Murphy, Proc. Int. Symp. Zeolite 85, Elsevier Ed. B.Draj., D. Hocevar and S. Pjenovich, 219 (1985).

    Google Scholar 

  30. G.T. Kokotailo, C.A. Fyfe, G.J. Kennedy, G.C. Gobbi, H.J. Strobl, C.T. Pasztor, G.E. Barlow, S. Bradley, W.J. Murphy, and R.S. Ozubko, Pure and Applied Chemistry,, 58, 1367 (1986).

    Article  CAS  Google Scholar 

  31. C.A. Fyfe, G.J. Kennedy, G.T. Kokotailo, and C.T. DeSchutter, J. Chem. Soc. Chem. Comm., 1093 (1984).

    Google Scholar 

  32. C.A. Fyfe, G.C. Gobbi, W.J. Murphy, R.S. Ozubko and D.A. Slack, Chem. Lett., 1547 (1983).

    Google Scholar 

  33. C.A. Fyfe, G.C. Gobbi, W.J. Murphy, R.S. Ozubko and D.A. Slack, J. Am. Chem. Soc.,, 106, 4435 (1984).

    Article  CAS  Google Scholar 

  34. J. Klinowski, M.W. Anderson, and J.M. Thomas, J. Chem. Soc., Chem. Comm., 525 (1983)...

    Google Scholar 

  35. U.S. Patent 3, 702, 886.

    Google Scholar 

  36. G.T. Kokotailo, S.L. Lawton, D.H. Olson, and W. Meier, Nature,, 272, 437 (1978).

    Article  CAS  Google Scholar 

  37. G.T. Kokotailo, and W.M. Meier, Spec. Publ. Chem. Soc., 33, 133 (1980).

    CAS  Google Scholar 

  38. C.A. Fyfe, G.T. Kokotailo, G.J. Kennedy, and C.T. DeSchutter, J. Chem. Soc., Chem. Comm., 306 (1985).

    Google Scholar 

  39. C.A. Fyfe, G.C. Gobbi, J. Klinowski, J.M. Thomas, and S. Ramdas, Nature, 296, 530 (1982).

    Article  CAS  Google Scholar 

  40. C.A. Fyfe, G.C. Gobbi, and G.J. Kennedy, Chem. Lett., 1551 (1984).

    Google Scholar 

  41. J.M. Thomas, J. Klinowski, and M.W. Anderson, Chem. Lett., 1555 (1983).

    Google Scholar 

  42. C.A. Fyfe, G.C. Gobbi, and G.J. Kennedy, J. Phys. Chem., 88, 3248 (1984).

    Article  CAS  Google Scholar 

  43. C.A. Fyfe, G.J. Kennedy, C.T. DeSchutter, and G.T. Kokotailo, J. Chem. Soc., Chem. Comm., 541 (1984).

    Google Scholar 

  44. G.W. West, Aust. J. Chem., 37, 455 (1984).

    Article  CAS  Google Scholar 

  45. C.A. Fyfe, G.J. Kennedy, G.T. Kokotailo, J.R. Lyerla, and W.W. Fleming. J. Chem. Soc., Chem. Comm., 740 (1985).

    Google Scholar 

  46. D.G. Hay, H. Jaeger, and G.W. West, J. Phys. Chem., 89, 1070 (1985).

    Article  CAS  Google Scholar 

  47. C.A. Fyfe, J.H. O’Brien and H. Strobl, Nature, 363, 6110 (1987).

    Google Scholar 

  48. C.A. Fyfe, H. Strobl, G.T. Kokotailo, C.T. Pasztor, G.E. Barlow, and S. Bradley, Zeolites, 8, 132 (1988).

    Article  CAS  Google Scholar 

  49. H. Strobl, C.A. Fyfe, G.E. Barlow, and G.T. Kokotailo, to be published.

    Google Scholar 

  50. C.A. Fyfe, H. Strobl; G.T. Kokotailo, G.J. Kennedy, and G.E. Barlow, J. Am. Chem. Soc., 110, 3373 (1988).

    Article  CAS  Google Scholar 

  51. H. Gies, C.A. Fyfe, H. Strobl, G.T. Kokotailo, Yi Feng, and D.E. Cox, Unpublished results.

    Google Scholar 

  52. C.A. Fyfe, H. Gies, G.T. Kokotailo, C.T. Pasztor, H. Strobl, and D.E. Cox, Can. J. Chem., 66, 1942 (1988).

    Article  CAS  Google Scholar 

  53. U.S. Patent 3, 709, 979.

    Google Scholar 

  54. G.T. Kokotailo, P. Chu, S.L. Lawton, and W.M. Meier, Nature,, 275, 119 (1978).

    Article  CAS  Google Scholar 

  55. C.A. Fyfe, G.T. Kokotailo, G.J. Kennedy, and C.T. DeSchutter, J. Chem. Soc. Chem. Comm., 306 (1985).

    Google Scholar 

  56. C.A. Fyfe, H. Gies, G.T. Kokotailo, C. Pasztor, H. Strobl, and D.E. Cox, J. Am. Chem. Soc. (In press).

    Google Scholar 

  57. U.S. PAtent 4, 287, 166.

    Google Scholar 

  58. J.L. Schlenker, F.G. Dwyer, E.E. Jenkins, W.J. Rohrbaugh, G.T. Kokotailo, and W.M. Meier, Nature, 294, 340 (1981).

    Article  CAS  Google Scholar 

  59. H. Gies, F. Liebau, and H. Gerke, Angew. Chem., 94, 214 (1982), and Angew. Chem. Inter. Ed., 21, 206 (1982).

    Article  CAS  Google Scholar 

  60. H. Gies, Z. Kristallogr., 167, 73 (1984).

    Article  CAS  Google Scholar 

  61. H. Strobl, C.A. Fyfe, G.T. Kokotailo, and C.T. Pasztor, J. Am. Chem. Soc., 109, 7433 (1987).

    Article  Google Scholar 

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Author information

Authors and Affiliations

  1. Department of Chemistry, University of British Columbia, Vancouver, British Columbia, V6T 1Y6, Canada

    C. A. Fyfe, G. T. Kokotailo, H. Gies & H. Strobl

Authors
  1. C. A. Fyfe
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  2. G. T. Kokotailo
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  3. H. Gies
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  4. H. Strobl
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Editors and Affiliations

  1. Institut de Chimie, Université Louis Pasteur, Strasbourg, France

    Pierre Granger

  2. Department of Chemistry, Science Laboratories, University of Durham, Durham, UK

    Robin K. Harris

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© 1990 Kluwer Academic Publishers

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Fyfe, C.A., Kokotailo, G.T., Gies, H., Strobl, H. (1990). High-Resolution Solid-State NMR Investigations of the Lattice Structures of Zeolite Catalysts and Sorbents. In: Granger, P., Harris, R.K. (eds) Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications. NATO ASI Series, vol 322. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2149-8_23

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  • DOI: https://doi.org/10.1007/978-94-009-2149-8_23

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7467-4

  • Online ISBN: 978-94-009-2149-8

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