Skip to main content
SpringerLink
Log in

NMR of Adsorbed Species and Surfaces

  • Chapter
Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications

Part of the book series: NATO ASI Series ((ASIC,volume 322))

Abstract

Conventional high resolution NMR yields useful information on the state of sufficiently mobile adsorbed molecules, their mobility, kinetic transformations.MAS, CP, SEDOR, multiple quantum coherenc are successfully applied to characterize both the adsorbate and the adsorbent in mutual interaction. The acidity of the surfaces is determined by both MAS 1H NMR of the acidic sites and 13C and 15N NMR of adsorbed bases. The mutual effects of adsorbent-adsorbate interactions are evidenced by 29Si, 192Pt and 13C NMR. The confinement effects are shown by 13C NMR of adsorbed tetramethylammonium ions and by 129Xe NMR of adsorbed xenon. The surface defect groups are identified by 1H, 29Si and 17O NMR. The mobility of the adsorbed molecules is illustrated by 13C and 2H NMR of adsorbed xylenes. Finally it is shown that the catalytic transformations can easily be followed directly in the adsorbed state.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. G. Engelhardt,and D. Michel, ‘High-Resolution Solid-State NMR of Silicates and Zeolites’, Wiley, Chichester, 1987, 368.

    Google Scholar 

  2. H. Pfeifer in ‘NMR Basic Principles and Progress’, P. Diehl et al., eds., 7, Springer, Berlin, 1972, 53.

    Google Scholar 

  3. H. Pfeifer, Phys. Rep., Sect. C, 26, 293 (1976).

    Article  Google Scholar 

  4. J. B. Nagy, G. Engelhardt,and D. Michel, Adv. Colloid Interface Sci., 23, 67 (1985).

    Article  CAS  Google Scholar 

  5. E.G. Derouane,and J. B. Nagy,Catalytic Materials: ‘Relationship between Structure and Reactivity’, T.E. Whyte Jr. et al., eds, ACS Symposium Series 248, Washington D.C., 1984, 101.

    Google Scholar 

  6. T.M. Duncan, and C. Dybowski, Surf. Sci. Reports, 1, 157 (1981).

    Article  CAS  Google Scholar 

  7. J. Conard, J. Chim. Phys., 84, 1249 (1987).

    CAS  Google Scholar 

  8. P.K. Wang, J.-P. Ansermet, S.L. Rudaz, Z. Wang, S. Shore, C.P. Slichter, and J. H. Sinfelt, Science, 234, 35 (1986).

    Article  CAS  Google Scholar 

  9. R. Ryo, S.-B. Liu, L.C. de Menorval, K. Takegoshi, B. Chmelka, M. Trecoske,and A. Pines, J. Phys. Chem., 91, 6575 (1987).

    Article  Google Scholar 

  10. H.A. Resing, Adv. Mol. Rel. Proc., 1, 109 (1968).

    Article  CAS  Google Scholar 

  11. T.H. Walter, G.L. Turner, and E. Oldfield, J. Magn. Reson., 76, 106 (1988).

    CAS  Google Scholar 

  12. P. Bodart, J. B. Nagy, G. Debras, Z. Gabelica, and P.A. Jacobs, J. Phys. Chem., 90, 5183 (1986).

    Article  CAS  Google Scholar 

  13. L.B. Welsh,and S.L. Lambert, in ‘Perspectives in Molecular Sieve Science’, ACS Symposium Series 368, ACS, Washington D.C., 1988, 33.

    Book  Google Scholar 

  14. T. Ito, and J. Fraissard, J. Chem. Soc., Faraday Trans.1, 83, 451 (1987).

    Article  CAS  Google Scholar 

  15. J. Fraissard, and T. Ito, Zeolites, 8, 350 (1988).

    Article  CAS  Google Scholar 

  16. E.G. Derouane, A.A. Lucas,and J.M. André, J. Catal., 137, 58 (1988).

    Article  Google Scholar 

  17. E.G. Derouane,and J. B. Nagy, Chem. Phys. Letters, 137, 341 (1987).

    Article  CAS  Google Scholar 

  18. M. Boudart, L.-C. de Menorval, J. Fraissard, and G.P. Valenga, J. Phys. Chem., 92, 4033 (1988).

    Article  CAS  Google Scholar 

  19. C.A. Fyfe, G.J. Kennedy, C.T. Schutter, and G.T. Kokotailo, J. Chem. Soc., Chem. Commun., 541, (1984).

    Google Scholar 

  20. G.W. West, Aust. J. Chem., 37, 455 (1984).

    Article  CAS  Google Scholar 

  21. B. Boddenberg, in Lectures on Surface Science, G.R. Castro, M. Cardona, eds., Springer, Berlin, 1987, 226.

    Google Scholar 

  22. I. Kustanovich, D. Fraenkel, Z. Luz, S. Vega, and H. Zimmermann, J. Phys. Chem., 92, 4134 (1988).

    Article  CAS  Google Scholar 

  23. J. B. Nagy,and E.G. Derouane, in ‘Perspectives in Molecular Sieve Science’, W.H. Flank, T.E. White, Jr., eds., ACS Symposium Series 368, Washington, D.C., 1988, 2.

    Google Scholar 

  24. N. Dewaele, Z. Gabelica, P. Bodart, J. B. Nagy, G. Giordano, and E.G. Derouane, Stud. Surf. Sci. Catal., 37, 65(1987).

    Article  Google Scholar 

  25. E.G. Derouane, J. Fraissard, J.J. Fripiat,and W.E.E. Stone, Catal. Rev., 7, 121 (1972).

    Article  CAS  Google Scholar 

  26. A. Michael, W. Meiler, D. Michel, H. Pfeifer, D. Hoppach, and J. Delman, J. Chem. Soc., Faraday Trans 1,82, 3053 (1986).

    Article  CAS  Google Scholar 

  27. G. Engelhardt, H.-G. Jerschkewitz, U. Lohse, P. Saw, A. Samoson, and E. Lippmaa, Zeolites, 7, 291 (1987).

    Article  Google Scholar 

  28. D. Michel, A. Germanus, and H. Pfeifer, J. Chem. Soc., Faraday Trans 1, 78, 237 (1982).

    Article  CAS  Google Scholar 

  29. P. Bodart, J. B. Nagy, G. Debras, Z. Gabelica, and P.A. Jacobs, J. Phys. Chem., 90, 5183 (1986).

    Article  CAS  Google Scholar 

  30. G. Debras, A. Gourgue, J. B. Nagy, and G. De Clippeleir, Zeolites, 6, 161 (1986).

    Article  CAS  Google Scholar 

  31. A. Tuel, H. Hommel, A.-P. Legrand, Y. Chevalier, and J.-C. Morawski, J.Non-Cryst.Solids,in press

    Google Scholar 

  32. E. Lippmaa, M. Magi, A. Samoson, M. Tarmak, and G. Engelhardt, J. Am. Chem. Soc., 103, 4992 (1981).

    Article  CAS  Google Scholar 

  33. J. B. Nagy, P. Bodart, H. Collette, J. El Hage-Al Asswad, Z. Gabelica, R. Aiello, A. Nastro, and C. Pellegrino, Zeolites, 8, 209 (1988).

    Article  CAS  Google Scholar 

  34. R.A. van Santen, J. Keijsper, G. Ooms, and A.G.T.G. Kortbeek, Stud. Surf. Sci. Catal., 28, 169 (1986).

    Article  Google Scholar 

  35. G. Giordano, J. B. Nagy, E.G. Derouane, N. Dewaele and Z. Gabelica, in Proc. Symposium on Advances in Zeolite Synthesis, Los Angeles, 1988, ACS Symposium Series, in press.

    Google Scholar 

  36. H.K. Beyer, I.M. Belenykaja, I.W. Mishin, and Y. Boberly,Stud. Surf. Sci. Catal., 18, 133 (1984).

    Article  CAS  Google Scholar 

  37. P. Fejes, I. Hannes, I. Kirichi, H. Pfeifer, D. Freude, and W. Oehme, Zeolites, 5, 45 (1985)

    Article  CAS  Google Scholar 

  38. A. Tuel, Ph.D. Thesis, Universite Paris 6, 1987.

    Google Scholar 

  39. K.F.M.G.J. Scholle, Ph.D. Thesis, Nijmegen, The Netherlands, 1985.

    Google Scholar 

  40. W.D. Basler, Colloids and Surfaces, 12, 59 (1984).

    Article  CAS  Google Scholar 

  41. J.A. Ripmeester, J. Magn. Reson.,56, 247 (1987).

    Google Scholar 

  42. D.W. Johnson, and L. Griffiths, Zeolites, 7, 484 (1987).

    Article  CAS  Google Scholar 

  43. R. Brinkmann, C.A. Paulick, M. Elwenspoek, M. von Hartrott, M. Kiehl, P. Maxim, and D. Quitmann, Phys. Letters, 111A, 435 (1985).

    CAS  Google Scholar 

  44. F.H.A. Rummens, Van der Waals forces in NMR. Intermolecular shielding effects, ‘NMR Basic Principles and Progress’, 10, Springer, Berlin, 1975.

    Google Scholar 

  45. T. Ito, J. Fraissard, J. B. Nagy, N. Dewaele, Z. Gabelica, A. Nastro, and E.G. Derouane, in Proc. 8th Intern. Zeolite Conf., Amsterdam, The Netherlands, July 10–14, 1989, in press.

    Google Scholar 

  46. T. Ito, J.L. Bonardet, J. Fraissard, J. B. Nagy, C. Andre, Z. Gabelica, and E.G. Derouane, Appl. Catal., 43, L5 (1988).

    Article  CAS  Google Scholar 

  47. J. Demarquay, and J. Fraissard, Chem. Phys. Lett., 136, 314 (1987).

    Article  CAS  Google Scholar 

  48. E.G. Derouane, J. B. Nagy, B. De Roover, and C. Fernandez in Proc. 8th Intern. Zeolite Conf., Amsterdam, The Netherlands, July 10–14, 1989, in press.

    Google Scholar 

  49. W.T. Raynes, A.D. Buckingham, and H.J. Bernstein, J. Chem. Phys., 72, 2111 (1968).

    Article  Google Scholar 

  50. J. B. Nagy, E.G. Derouane, H.A. Resing, and G.R. Miller, J. Phys. Chem., 87, 833 (1983).

    Article  CAS  Google Scholar 

  51. P.T. Reischman, K.D. Schmitt, and D.H. Olson, J. Phys. Chem., 92, 5165 (1988).

    Article  CAS  Google Scholar 

  52. E.L. Wu, S.L. Lawton, D.H. Olson, A.C. Rohrman, and G.T. Kokotailo, J. Phys. Chem., 83, 2777 (1979).

    Article  CAS  Google Scholar 

  53. C.D. Makowka, C.P. Slichter, and J.H. Sinfelt, Phys. Rev. Lett., 49, 379 (1982).

    Article  CAS  Google Scholar 

  54. P.K. Wang, C.P. Slichter, and J.H. Sinfelt, J. Phys. Chem., 89, 3606 (1985).

    Article  CAS  Google Scholar 

  55. E.G. Derouane, C. Lefebvre, and J. B. Nagy, J. Molec. Catal., 38, 387 (1986).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire de Catalyse, ISIS, Facultés Universitaires Notre-Dame de la Paix, 61, rue de Bruxelles, B-5000, Namur, Belgium

    Janos B. Nagy

Authors
  1. Janos B. Nagy
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Institut de Chimie, Université Louis Pasteur, Strasbourg, France

    Pierre Granger

  2. Department of Chemistry, Science Laboratories, University of Durham, Durham, UK

    Robin K. Harris

Rights and permissions

Reprints and permissions

Copyright information

© 1990 Kluwer Academic Publishers

About this chapter

Cite this chapter

Nagy, J.B. (1990). NMR of Adsorbed Species and Surfaces. In: Granger, P., Harris, R.K. (eds) Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications. NATO ASI Series, vol 322. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2149-8_20

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-2149-8_20

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7467-4

  • Online ISBN: 978-94-009-2149-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation