Abstract
The magic-angle spinning experiment is described and its use with cross-polarization to obtain high-resolution spectra of dilute spins is discussed, with examples. Spectral editing by dipolar dephasing is presented. The occurrence of spinning sidebands and their analysis are reviewed. Several experiments using two-dimensional methods with magic-angle spinning are described, particularly for the study of chemical exchange and/or spin diffusion.
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References
A general, applications-oriented, account of these studies is given in C.A. Fyfe, Solid State NMR for Chemists, CFC Press. 1984.
T.M. Duncan and C.R. Dybowski, Surface Science Reports, 1. 157 (1981).
E.R. Andrew, A. Bradbury and R.G. Eades, Nature, 182, 1659 (1958).
E.R. Andrew, A. Bradbury and R.G. Eades, Nature, 183, 1802 (1959).
I.J. Lowe, Phys. Rev. Lett., 2, 285 (1959).
E.R. Andrew, Internat. Rev. Phys. Chem., 1, 195 (1981).
F.D. Doty, P.D. Ellis, Rev. Sci. Instrum., 52, 1868 (1981).
J. Schaefer, E.O. Stejskal, J. Amer. Chem. Soc., 98, 1031 (1976).
C.A. Fyfe, G.C. Gobbi, J.S. Hartman, R.E. Lenkinski, J.H. O’Brien, E.R. Beange, M.A.R. Smith, J. Magn. Reson., 47, 168 (1982).
C.A. Fyfe, J.R. Lyerla, C.S. Yannoni, Acc. Chem. Res., 15, 208 (1982).
E. Kundla, A. Samoson, E. Lippmaa, Chem. Phys. Lett., 83, 229 (1981).
A. Samoson, E. Kundla, E. Lippmaa, J. Magn. Reson., 49, 350 (1983).
E. Oldfield, R.A. Kinsey, B. Montey, T. Ray, K.A. Smith, J. C. S. Chem. Commun., 254 (1982).
M.D. Meadows, K.A. Smith, R.A. Kinsey, T.M. Rothgeb, R.P. Skarjunl, E. Oldfield, Proc. Natl. Acad. Sci. USA, 79, 1351 (1982).
C.A. Fyfe, H. Mossbruger, C.S. Yannoni, J. Magn. Reson., 36, 61 (1979).
P. Myhre, C.S. Yannoni, J. Amer. Chem. Soc., 103, 230 (1981).
R.L. Dudley, C.A. Fyfe, Fuel, 61, 651 (1982).
S.J. Opella, M.H. Frey, J. Amer. Chem. Soc., 101, 5854 (1979).
R.F. Childs, B.D. Dickie, R. Faggiani, C.A. Fyfe, C.J.L. Lock, R.E. Wasylishen to be published.
J. Schaefer, E.O. Stejskal, R.A. McKay, J. Magn. Reson., 25, 269 (1977).
E. Lippmaa, M. Alla, T. Tuherm, XIX Congress Ampere, Heidelberg. (1976).
J. Herzfeld, A.E. Berger, J. Chem. Phys., 73, 6021 (1980).
W.T. Dixon, J. Magn. Reson., 44, 220 (1981).
W.T. Dixon, J. Chem. Phys., 77, 1800 (1982).
W.T. Dixon, J. Schaefer, M.D. Sefcik, E.O. Stejskal, R.A. McKay, J. Magn. Reson., 49, 341 (1982).
M.M. Maricq, J.S. Waugh, J. Chem. Phys., 70, 3300 (1979).
N.J. Clayden, C.M. Dobson, L. Lian, D.J. Smith, J. Magn. Reson.. 69, 476 (1986).
R.K. Harris, L.H. Merwin, G. Hägele, J.C.S. Faraday 1, 85, 1409 (1989).
Bai Haiping, R.K. Harris and A. Sebald, unpublished work.
I.J. Cox, Ph.D. Thesis, University of East Anglia (1984).
P. Jackson, Ph.D. Thesis, University of Durham (1987).
J. Schraml, J.M. Bellama, Two-dimensional NMR spectroscopy, Wiley-Interscience (1988).
N.M. Szeverenyi, M.J. Sullivan, G.E. Maciel, J. Magn. Reson., 47, 462 (1982).
J. Jeener, B.H. Meier, P. Bachmann, R.R. Ernst, J. Chem. Phys.. 71, 4546 (1979).
P. Caravatti, J.A. Deli, G. Bodenhausen, R.R. Ernst, J. Amer. Chem. Soc., 104, 5506 (1982).
S.J. Opella, M.H. Frey, J. Amer. Chem. Soc., 106, 4942 (1984).
D.L. VanderHart, J. Magn. Reson., 72, 13 (1987).
V. Bark, J. Schaefer, J. Magn. Reson., 78, 348 (1988).
R. Benn, H. Grondey, C. Brevard, A. Pagelot, J. C. S. Chem. Commun., 102 (1988).
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© 1990 Kluwer Academic Publishers
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Fyfe, C.A. (1990). Magic-Angle Spinning. In: Granger, P., Harris, R.K. (eds) Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications. NATO ASI Series, vol 322. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2149-8_17
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DOI: https://doi.org/10.1007/978-94-009-2149-8_17
Publisher Name: Springer, Dordrecht
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