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Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications pp 187–199Cite as

The Relation between Chemical Shift and Structure

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Part of the book series: NATO ASI Series ((ASIC,volume 322))

Abstract

Chemical shifts for a variety of nuclei are discussed with emphasis on the energies of the molecular orbitals in relation to σp, the screening constant. For 59Co, 103Rh, 195Pt, 119Sn, 31P and 15N it is suggested that relatively large changes in δ can be related to the (Eunocc-Eoccup)−1 term in σp consequendy to molecular structure.

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Author information

Authors and Affiliations

  1. Laboratorium für Anorganische Chemie, ETH-Z, Universitätstrasse 6, CH-8092, Zürich, Switzerland

    P. S. Pregosin

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  1. P. S. Pregosin
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Editors and Affiliations

  1. Institut de Chimie, Université Louis Pasteur, Strasbourg, France

    Pierre Granger

  2. Department of Chemistry, Science Laboratories, University of Durham, Durham, UK

    Robin K. Harris

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© 1990 Kluwer Academic Publishers

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Pregosin, P.S. (1990). The Relation between Chemical Shift and Structure. In: Granger, P., Harris, R.K. (eds) Multinuclear Magnetic Resonance in Liquids and Solids — Chemical Applications. NATO ASI Series, vol 322. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-2149-8_12

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  • DOI: https://doi.org/10.1007/978-94-009-2149-8_12

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7467-4

  • Online ISBN: 978-94-009-2149-8

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