Abstract
This paper reviews and compares various optical diagnostic techniques for low pressure plasmas used in etching and deposition processes for microelectronics devices. Optical emission induced by electron-molecule collisions is reviewed. Both space and time-resolved measurements, combined with high-resolution lineshape measurements and rare-gas actinometry have yielded information on radical and ion formation processes, ion motion, etc. Absorption techniques are also covered, including UV, visible and IR absorption, using both lamps and tunable lasers to determine absolute number densities of stable molecules and radicals. Laser-spectroscopic techniques covered include laser-induced fluorescence, laser raman scattering, optogalvanic effects, and tunable IR laser absorption.
Surface diagnostic optical techniques are also described briefly, including laser interferometry, ellipsometry, multipass IR absorption, glancing angle reflection absorption, raman scattering, and second harmonic generation. Some of these methods have not yet been employed in plasma environments, but have the potential to yield valuable information.
Much of this material is contained in chapter 1 of a book entitled “Plasma Diagnostics”, ed. D. L. Flamm and O. Auciello, (Academic Press, 1989).
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References
D. L. Flamm, V. Donnelly, and D. E. Ibbotson, in VLSI Electronics Microstructure Science, Vol. 8, Plasma Processing for VLSI, edited by N. G. Einspruch and D. M. Brown (Academics, Orlando FL, 1984), Chap. 8.
V. M. Donnelly, D. E. Ibbotson, and D. L. Flamm, in Ion Beam Modification of Surfaces: Fundamentals and Applications, edited by O. Auciello and R. Kelly (Elsevier, Amsterdam, 1984), Chap. 8.
J. A. Mucha, V. M. Donnelly, D. L. Flamm, and L. M. Webb, J. Phys. Chem., 85, 3529 (1981).
K. R. Ryan and I. C. Plumb, Plasma Chemistry and Plasma Processing 4, 141 (1984).
D. A. Danner and D. W. Hess, J. Appl. Phys., 59, 940 (1986).
J. W. Coburn, Plasma Chemistry and Plasma Processing, 2, 1 (1982);
H. F. Winters, J. Vac. Sci. Technol. B3, 9 (1985).
W. R. Harshbarger, R. A. Porter, T. A. Miller, and P. Norton, Applied Spectroscopy, 31, 201 (1977);
Flamm, J. Appl. Phys. 49, 3796 (1978).
V. M. Donnelly, D. L. Hamm, W. C. Dautremont-Smith, and D. J. Werder, J. Appl. Phys. 55, 242 (1984).
R. A. Gottscho and V. M. Donnelly, J. Appl. Phys., 56, 245 (1984).
V. M. Donnelly, D. L. Hamm, and R. H. Bruce, J. Appl. Phys. 58, 2135 (1985).
D. L. Hamm and V. M. Donnelly, J. Appl. Phys., 59, 1052 (1986).
A. L. Cappelli, R. A. Gottscho, and T. A. Miller, Plasma Chemistry and Plasma Processing, 5, 317 (1985).
W. Benesch and E. Li, Optics Letters 9, 338 (1984).
V. M. Donnelly and D. L. Hamm, J. Appl. Phys. 51, 5273 (1980).
D. L. Hamm, V. M. Donnelly, and J. A. Mucha, J. Appl. Phys., 52, 3633 (1981).
V. M. Donnelly and D. L. Hamm, U.S. Patent 4,377,436, Mar. 22, 1983.
M. Suto, M. J. Mitchell, L. C. Lee, and T. J. Chuang, Topical Meeting on Microphysics of Surfaces, Beams, and Adsorbates, Sante Fe NM, Feb. 16–18, 1987, paper TuB3-l.
O. Krogh, T. Widser, and B. Chapman, J. Vac. Sci. Technol. A4, 1796 (1986).
G. Scheller, R. A. Gottscho, and T. Intrator, J. Appl. Phys., in press.
J. W. Coburn and M. Chen, J. Appl. Phys. 51, 3134 (1980).
R. d’Agostino, F. Cramarossa, S. DeBenedictus, and G. Ferraro, J. Appl.. Phys. 52, 1259 (1981).
R. d’Agostino, F. Cramarossa, and S. DeBenedictus, Plasma Chem. Plasma Proc., 2, 213 (1982).
R. d’Agostino, F. Cramarossa, S. De Benedictus and G. Ferraro, Plasma Chem. Plasma Proc. 4, 163 (1984).
D. E. Ibbotson, D. L. Flamm, and V. M. Donnelly, J. Appl. Phys. 54, 5974 (1983).
L. Brown, V. M. Donnelly, and V. R. McCrary, Plasma Chem. and Plasma Processing, 7, 395 (1987).
B. J. Curtis and H. J. Brunner, J. Electrochem. Soc. 127, 234 (1978).
E. O. Degenkolb, C. J. Mogab, M. R. Goldrick, and J. R. Griffiths, Appl. Spectros. 30, 520 (1976).
W. R. Harshbarger, R. A. Porter, T. A. Miller, and P. Norton, Appl. Spectrosc. 31, 201 (1977).
V. M. Donnelly, D. L. Flamm, C. W. Tu, and D. E. Ibbotson, J. Electrochem. Soc., 129, 2533 (1982).
T. Hamasaki, M. Hirose, and Y. Osaka, Proc. 7th ICVM, 1982, Tokyo, Japan, p. 432.
H. U. Poll, D. Hinze, and H. Schlemm, Appl. Spectros., 36, 445 (1982);
H. U. Poll and H. Schlemm, Beiträge, aus der Plasma physik 22, 195 (1982);
H. U. Poll, M. Arzt, and K. H. Wickleder, Eur. Polym. J. 12, 505 (1976).
T. A. Cleland and D. W. Hess, Conference on Emerging Technologies in Materials, Minneapolis, MN, Aug. 18–20, 1987; Plasma Chem. Plasma Proc., 7, 379 (1987).
R. A. Gottscho, G. P. Davis, and R. H. Burton, J. Vac. Sci. Technol. A1, 622 (1983).
R. A. Gottscho, G. P. Davis, and R. H. Burton, Plasma Chem. Plasma Proc., 3, 193 (1983).
C. A. Moore, G. P. Davis, and R. A. Gottscho, Phys. Rev. Lett., 52, 538 (1984).
R. A. Gottscho and M. L. Mandich, J. Vac. Sci. Technol. A3, 617 (1985).
K. Ninomiya, K. Suzuki, S. Nishimatsu, and O. Okada, J. Vac. Sci. Technol. A4, 1791 (1986).
P. J. Hargis, Jr. and M. J. Kushner, Appl. Phys. Lett. 40, 779 (1982).
Y. Matsumi, T. Hayashi, H. Hoshikawa, and S. Komiya, J. Vac. Sci. Technol. A4, 1786 (1986).
V. M. Donnelly, D. L. Flamm, and G. Collins, J. Vac. Sci. Technol. 21, 817 (1982).
R. A. Gottscho, R. H, Burton, D. L. Flamm, V. M. Donnelly, and G. P. Davis, J. Appl. Phys. 55, 2707 (1984).
W. K. Bischel, B. E. Perry, and D. R. Crosley, Chem Phys. Lett. 82, 85 (1981).
L. F. DiMauro, R. A. Gottscho and T. A. Miller, J. Appl. Phys. 56, 2007 (1984).
M. Heaven, T. A. Miller, R. R. Freeman, J. White, J. Bokar, Chem. Phys. Lett., 86, 458 (1982).
Y. Matsumi, S. Toyoda, T. Hayashi, M. Miyamma, H. Yopshikawa, and S. Komiya, J. Appl. Phys. 60, 4102 (1986).
R. B. Wright, M. J. Pellin, and D. M. Gruen, Surf. Sci. 110, 151 (1981).
R. B. Wright, M. J. Pellin, and D. M. Gruen, J. Vac. Sci. Technol. 20, 510 (1982).
W. Husinsky, J. Vac. Sci. Technol. B3, 1546 (1985).
J. E. Lawler, D. K. Doughty, and S. Salin, Abs. no. K6, 37th Gaseous Electronics Conference, Univ. of Colorado, (Oct. 9–12, 1984), published by the American Physical Society.
D. K. Doughty, S. Salin, and J. E. Lawler, Appl. Phys. Lett. 103A, 41 (1984);
D. K. Doughty and J. E. Lawler, Appl. Phys. Lett. 45, 611 (1984).
B. N. Ganguly and A. Garscadden, Appl. Phys. Lett. 46, 540 (1985).
P. J. Hargis, Jr., Appl. Opt. 20, 149 (1981).
K. E. Greenberg and P. J. Hargis, CLEO, 1987.
McDonald, J. R. (1980), in Laser Probes for Combustion Chemistry, ed. Crosley, D. R. (American Chemical Society Symposium Series 134), pp. 19–58.
Tolles, W. M., Nibler, J. W., McDonald, J. R., and Harvey, A. B. (1977) App. Spect., 31, 253.
Nibler, J. W. and Knighten, G. V. (1977), in Topics in Current Physics, ed. Weber A. (Springer Verlag, Struttgart, Germany), Ch. 7.
Druet, S. and Taran, J. P. (1979), in Chemical and Biological Applications of Lasers, ed. Moire, C. B. (Academic Press, New York).
Hata, N., Matsuda, A., Tanaka, K., Kajiyama, K., Moro, N., and Sajiki, K. (1983) Japan. J. Appl. Phys. 22, L.1.
S. C. Foster and A. R. W. McKellar, J. Chem. Phys. 81, 3424 (1984).
A. S. Pine, J. Opt. Soc. Am. 64, 1683 (1974);
A. S. Pine, J. Opt. Soc. Am. 66, 97 (1976).
J. K. G. Watson, S. C. Foster, A. R. W. McKellar, P. Bernath, T. Amano, F. S. Pan, M. W. Crofton, R. S. Altman, and T. Oka, Can J. Phys. 62, 1875 (1984).
C. S. Gudeman, M. H. Begemann, J. Pfaff and R. J. Saykally, Phys. Rev. Lett. 50, 727 (1983).
A. C. Stanton and C. E. Kolb, J. Chem. Phys., 72, 6637 (1980);
G. A. Laguna and W. H. Beatile, Chem. Phys. Lett. 88, 439 (1982).
M. Dagenais, J. W. C. Johns, and A. R. W. McKeller, Can. J. Phys. 54, 1438 (1976);
D. B. Davis and D. K. Russell, Chem. Phys. Lett. 67, 440 (1979).
J. Wormhoudt, A. C. Stanton, A. D. Richards, and H. H. Sawin, Mat. Res. Soc. Symp. Proc., Vol. 68, 115, (1986).
P. Rabinowitz, B. N. Perry, and N. Levinos, IEEE J. Quantum Electronics, QE-22, 797 (1986).
A. L. Harris, J. K. Brown, M. Berg, and C. B. Harris, Opt. Lett. 9, 47 (1984).
D. C. Hanna, M. A. Yuratich, and D. Cotter, Nonlinear Optics of Free Atoms and Molecules, Springer Series in Optical Sciences, Vol. 17 (Springer-Verlag, New York 1979).
D. S. Bethune, A. J. Schell-Sorokin, M. M. T. Loy, J. R. Lankard, P. P. Sorokin, Adv. in Laser Spectroscopy, Vol. 2, ed. by B. A. Garetz and J. R. Lombardi (Wiley, New York 1983) pp. 1–43.
A. L. Harris, unpublished work.
C. Kenty, Phys. Rev. 80,95 (1950).
K. W. Meissner and W. F. Miller, Phys. Rev. 92, 896 (1953).
D. K. Doughty and J. E. Lawler, Phys. Rev. A, 28, 773 (1983).
R. Walkup, R. W. Dreyfus, and Ph. Arouris, Phys. Rev. Lett., 50, 1846 (1983).
R. A. Gottscho and G E. Gaebe, J. Vac. Sci. Technol., A4, 1795 (1986).
Handbook of thin film technology, ed. L. I. Maissel and R. Glang, McGraw Hill, New York, 1970, p 11–22
R. H. Muller, Surf. Sci. 56, 19 (1976).
B. Drevillon, J. Perrin, R. Marbot, A. Violet, and J. L. Dalby, Rev. Sci. Instrum. 53, 969 (1982).
G. E. Jellison, Jr. and D. H. Lowndes, Appl. Phys. Lett., 47, 718 (1985).
D. E. Aspnes and R. P. H. Chang, Mat. Res. Soc. Symp. Proc. 29, 217 (1984).
F. Hottier and J. B. Theeten, J. Cryst. Growth, 48, 644 (1980).
A. M. Antoine, B. Drevillon, and P. Roca I. Cabarrocas, Mater. Res. Soc. Symp., Vol 75, 1987.
Y. R. Shen, J. Vac. Sci. Technol. B3, 1464 (1985).
T. F. Heinz, M. M. T. Loy, W. A. Thompson, Phys. Rev. Lett., 54, 63 (1985);
T. F. Heinz, M. M. T. Loy, W. A. Thompson, J. Vac. Sci. Technol. B3, 1467 (1985).
A. Mitchell, R. A. Gottscho, S. J. Pearton, G. R. Scheller, and S. W. Downey, Proceedings of the Ninth International Symposium on Plasma Chemistry, Pugnochiuoso, Italy, 1989.
A. Otto, Surf. Sci. 117, 330 (1982).
J. M. Stencel, D. M. Noland, E. B. Bradley, and C. A. Frenzel, Rev. Sci. Instrum. 49, 1163 (1978).
J. M. Stencel and E. B. Bradley, J. Raman Spectros. 8, 203 (1979); Spectros. Lett., 11, 563 (1978).
D. V. Murphy and S. R. J. Brueck, Opt. Lett. 8, 494 (1983).
Vibrations at Surfaces 1985, ed. D. A. King, N. V. Richardson, and S. Holloway, Elsevier, Amsterdam, 1986.
M. A. Chesters, J. Electron Spectros. and Related Phenomena, 38, 123 (1986).
V. M. Bermudez, J. L. Hylden, and J. E. Butler, J. Electron Spectros. and Related Phenomena, 38, 143 (1986).
M. A. Chesters, J. Electron Spectros. and Related Phenomena, 38, 123 (1986).
W. C. M. Claassen and J. Dieleman, Topical Meeting on Microphysics of Surfaces, Beams, and Adsorbates, Sante Fe, NM, Feb. 16–18, 1987, TuB4-l.
S. W. Downey, A. Mitchell, and R. A. Gottscho, J. Appl. Phys., 63, 5280 (1988).
G. S. Selwyn, B. D. Ai, and J. Singh, Appl. Phys. Lett., 52, 1953 (1988).
A. Mitchell, R. A. Gottscho, S. J. Pearton, G. R. Scheller, and B. L. Preppernau, to be published.
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Donnelly, V.M. (1990). Optical Diagnostic Techniques for Low Pressure Plasma Processing. In: Auciello, O., Gras-Marti, A., Valles-Abarca, J.A., Flamm, D.L. (eds) Plasma-Surface Interactions and Processing of Materials. NATO ASI Series, vol 176. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1946-4_3
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DOI: https://doi.org/10.1007/978-94-009-1946-4_3
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