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Enzyme Chemistry pp 50–94Cite as

Chemical models of selected coenzyme catalyses

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Abstract

An enzyme is born through repeated ‘trial and error’ in nature over an enormous length of time. Active sites of enzymes evolved to allow the enzymes to mediate biological reactions under ambient conditions and thus serve as excellent biological ‘catalysts’. Nevertheless, enzymes have two inevitable limitations when viewed by organic chemists: first, enzymic catalyses are often too specific and do not allow the reactions that organisms do not require and secondly, the catalytic activities appear only under ambient physiological conditions. Although many useful synthetic reactions can be executed using enzymic catalysis (see Chapter 4), reaction conditions as well as enzyme specificity limit the direct applicability of enzymes. Therefore, one has to mimic the essence of the enzymic catalyses in more simplified systems in order to utilize the enzyme-like catalyses in a more versatile manner. This is the primary aim of an enzyme model study. We thus consider that the enzyme model study consists of two main targets: first, exploitation of more versatile, enzyme-like catalysts and secondly, clarification of the reaction mechanisms in more simplified systems.

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Authors
  1. Seiji Shinkai
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Editors and Affiliations

  1. Department of Pure and Applied Chemistry, University of Strathclyde, Glasgow, UK

    Colin J. Suckling (Professor of Organic Chemistry) (Professor of Organic Chemistry)

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Shinkai, S. (1990). Chemical models of selected coenzyme catalyses. In: Suckling, C.J. (eds) Enzyme Chemistry. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1832-0_3

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