Abstract
The existence of surface shifts in core level binding energies of transition metal carbide and nitride surfaces is reviewed in this article. The shifts are of interest since they can provide information about the surface electronic properties of materials and, if large enough, can be used as probes of surface properties and reactions. Since no ab initio calculations of surface shifts for these compounds yet exist, the experimental results are compared with those predicted using a simple thermochemical model. That the surface shifts are large enough for a variety of surface investigations is shown and exemplified. Interesting possibilities for the future are discussed.
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References
K. Schwarz. CRC Critical Reviews in Solid State and Materials Sciences, 13, 11 (1987); and references therein.
A. Neckel. Int.. J. Quantum Chem., 23, 1317 (1983).
L.I. Johansson and C.G. Larsson. Angle Resolved Photoemission, S.D. Kevan, Ed., (Springer, 1992), Chap. 8; and references therein.
L.I. Johansson. Surf Sci. Reports, in press.
D. Spanjaard, C. Guillot, M.C. Desjonquèrès, G. Trèglia and J. Lacante. Surf. Sci. Reports, 5(1/2), (1985).
E. Wimmer, A. Neckel and A.J. Freeman. Phys. Rev., B 31, 2370 (1985).
R.A. Bartynski, S. Yang, S.L. Hulbert, C.-C. Kao, M. Weibert and D.M. Zehner. Phys. Rev. Letters, 68, 2247 (1992).
See for example, D.P. Woodruff. Photoelectron Diffraction. In: Angle Resolved Photoemission, S.D. Kevan, Ed., Springer, 1992.
B. Johansson and N. Martensson. Phys. Rev., B 21, 4427 (1980).
A. Nilsson, B. Ericksson, N. Martensson, J.N. Andersen and J. Onsgaard. Phys. Rev., B 38, 10357 (1988).
M.P. Seah and W.A. Dench. Surf, and Interface Analysis, 1, 2 (1979).
G.R. Gruzalski, D.M. Zehner, J.R. Noonan, H.L. Davis, R.A. DiDio and K. Müller. J. Vac. Sci. Technol. A7, 2054 (1989).
L.I. Johansson, K.L. Håkansson, P.L. Wincott, D.S.L. Law and J.E. Inglesfield. Phys. Scripta., 41, 565 (1990).
G.R. Gruzalski, S.-C. Lui, D. Heskett, X. Shi and D.M. Zehner. National Synchrotron Light Source, Annual Report 1991, Vol II BNL 52317.
J.N. Andersen, O. Björneholm, A. Sandell, R. Nyholm. J. Forsell, L. Thånell, A. Nilsson and N. Mårtensson. Synchr. Radiat. News., 4, 21 (1991).
K.L. Håkansson, L.I. Johansson, M. Hammar and M. Göthelid. Phys. Rev. B 47, 10769 (1993).
K.L. Håkansson, H.I.P. Johansson and L.I. Johansson. Phys. Rev., B 48, 2623 (1993).
L.L Johansson, H.I.P. Johansson and K.L. Håkansson. Phys. Rev., B48, 14520 (1993).
K.L. Håkansson, H.I.P. Johansson and L.L Johansson. Phys. Rev., B 49, 2035 (1994).
L.L Johansson and H.I.P. Johansson. To be published.
M. Aldén, H.L. Skriver and B. Johansson. Phys. Rev. Lett., 71, 2449 (1993).
B. Johansson and M. Mårtensson. Helv. Phys. Acta, 56, 405 (1983).
A. Ferna’ndez Guillermet and G. Grimvall. Phys. Rev., B 40 10582 (1989).
J. Häglund, G. Grimvall, T. Jarlborg and A. Ferna’ndez Guillermet. Phys. Rev., B 43, 14400 (1991).
A. Ferna’ndez Guillermet, J. Haglund and G. Grimvall. Phys. Rev., B 45, 11557 (1992) and
A. Ferna’ndez Guillermet, J. Haglund and G. Grimvall. Phys. Rev., B 48, 11673 (1993).
J.R. Noonan, H.J. Davies, and G.R. Gruzalski. J. Vac. Sci. Technol., A5, 787 (1987).
Y. Gauthier, Y. Joly, J. Rundgren, L.I. Johansson and P. Wincott. Phys. Rev., B 42, 9328 (1990).
D.L. Price, J.M. Wills and B.N. Cooper. Phys. Rev., B 48, 15301 (1993).
C.O. de Gonzalez and A.E. Garcia. Surf Sci., 193, 305 (1988), and
P. Sen, D.D. Sarma, R.C. Budhani, K.L. Chopra and C.N.R. Rao. J. Phys., F 14, 565 (1984).
F.J. Himpsel, J.F. Morar, F.R. McFeely, R.A. Pollak and G. Hollinger. Phys. Rev., B 30, 7236 (1984); and references therein.
B.S. Itchkawitz, P.F. Lyman, G.W. Ownby and D.M. Zehner. Surf. Sci., 318, 395 (1994).
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© 1996 Chapman & Hall
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Johansson, L.I. (1996). Surface shifts in core level energies of transition metal carbides and nitrides. In: Oyama, S.T. (eds) The Chemistry of Transition Metal Carbides and Nitrides. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1565-7_25
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DOI: https://doi.org/10.1007/978-94-009-1565-7_25
Publisher Name: Springer, Dordrecht
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