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Determination of Binodal and Spinodal Points by Means of the Pressure Pulse Induced Critical Scattering Method

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Integration of Fundamental Polymer Science and Technology—2

Abstract

Thermodynamic properties of polymer-solvent systems can be determined near the miscibility gap in the temperature(T)- pressure(P)-concentration(y) phase diagram with the pressure pulse induced critical scattering method, which was developed by the authors. It is shown that turbidity corrections of the experimental determined light scattering intensities in the critical region of the binodal plane are necessary, because only the light scattering intensities without attenuation are of thermodynamic relevance.

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REFERENCES

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Author information

Authors and Affiliations

  1. Angewandte Physikalische Chemie der Universität, GH, Duisburg, Germany

    F. Kiepen & W. Borchard

Authors
  1. F. Kiepen
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  2. W. Borchard
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Editor information

Editors and Affiliations

  1. Eindhoven University of Technology, Eindhoven, The Netherlands

    P. J. Lemstra

  2. DSM-Research, Geleen, The Netherlands

    L. A. Kleintjens

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© 1988 Elsevier Applied Science Publishers Ltd.

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Kiepen, F., Borchard, W. (1988). Determination of Binodal and Spinodal Points by Means of the Pressure Pulse Induced Critical Scattering Method. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—2. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1361-5_33

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  • DOI: https://doi.org/10.1007/978-94-009-1361-5_33

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-7106-2

  • Online ISBN: 978-94-009-1361-5

  • eBook Packages: Springer Book Archive

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