Abstract
Alternating copolymers of acrylics and olefins can be synthesized at -70°C in dichloromethane by using acrylic monomers complexed with alkylaluminum halides; monomer conversion as well as molecular weights are controllable parameters by varying the composition of the reacting system and the reaction conditions. The copolymers exhibit unusual material properties and seem to be interesting materials in view of the development of new areas of technological application.
This is a preview of subscription content, log in via an institution to check access.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
M. Hirooka, H. Yabuuchi, S. Moritan, S. Kawasumi, K. Nakaguchi, J. Polym. Sci., Polym. Lett. B 5, 47 (1967).
M. Hirooka, H. Yabuuchi, S. Kawasumi, K. Nakaguchi, J. Polym. Sci., Polym. Chem. Ed. 11, 1281 (1973).
H. Hirai, J. Polym. Sci. Macromol. Rev. 11, 47 (1976).
C. H. Bamford, X. Han, R. J. Malley, Plaste Kautschuk 29, 137 (1982).
C. D. Eisenbach, U. Bülow, U. Daum, H. Fischer, B. Ulmschneider, Angew. Makromol. Chemie 145/146, 125 (1986).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1988 Elsevier Applied Science Publishers Ltd.
About this chapter
Cite this chapter
Eisenbach, C.D. (1988). Alternating Copolymers Via Complexed Monomers. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—2. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1361-5_11
Download citation
DOI: https://doi.org/10.1007/978-94-009-1361-5_11
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7106-2
Online ISBN: 978-94-009-1361-5
eBook Packages: Springer Book Archive