Abstract
The effectiveness of a laser Raman microprobe, with a two micron spot size and 1–2 micron probe depth, to provide microcompositional information about corrosion scales has been assessed by the examination of 20%Cr/25%Ni/Nb and 20%Cr/25%Ni/Nb + 0.13%Ce stainless steels oxidised in carbon dioxide based gases. For the first time it has proved possible to establish the unidirectional variation in the constituent phases of a thin (≤ 1 micron) oxide scale and also to identify precisely the nature of the oxide layers comprising thicker (≥ 8 micron) scales.
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© 1997 ECSC, EEC, EAEC, Brussels and Luxembourg
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Bennett, M.J., Graves, P.R., Hawes, R.W.M. (1997). The Laser Raman Microprobe — A New Technique for the Identification of Corrosion Scale Constituents. In: Marriott, J.B., Merz, M., Nihoul, J., Ward, J. (eds) High Temperature Alloys. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1347-9_19
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DOI: https://doi.org/10.1007/978-94-009-1347-9_19
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7099-7
Online ISBN: 978-94-009-1347-9
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