Abstract
This paper deals with the behaviour of hydrolyse d Polyacrylamide solutions in the presence of chromium III. First, using potentiometry and spectroscopy, we study the complexation between chromium III and sodium acetate used as a low molecular weight model for the polymer. Then the same methods are applied to investigate the polymer—Cr(III) complexation and the results are discussed in conjunction with the nature of the physical states of the systems. Finally, we perform rheological measurements in the sol—gel transition regime in a range where the number of crosslinking points can be calculated unambiguously.
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Allain, C. and Salomé, L., Polymer Communications, 1987, 28, 109.
Truong, N. D., Galin, J. C., François, J. and Pham, Q. T., Polymer, 1986, 27, 467.
Taube, H., Chem. Rev., 1952, 50, 69.
Klein, J. and Conrad, K., Makromol Chem., 1978, 179, 1635.
Dellien, L., Hall, F. M. and Hepler, L. G., Chem. Rev., 1976, 76, 290.
Elving, P. J. and Zemel, B., J. Am. Chem. Soc., 1957, 79, 1281.
Johnson, H. B. and Reynolds, W. L., Inorg. Chem., 1963, 2, 468.
Finholt, J. E., Caulton, K. G. and Libbey, W. J., J. Am. Chem. Soc., 1964, 3, Notes 1801.
Cotton, F. A. and Wilkinson, G., Advanced Inorganic Chemistry, 4th edn, John Wiley & Sons, New York, 1980.
Sillen, L. G. and Martell, A. E., Stability Constants of Metal-Ion Complexes, Chem. Soc., London, 1964.
Emerson, K. and Graven, W. M., J. Inorg. Nucl. Chem., 1959, 11, 309.
Deutsch, E. and Taube, H., Inorg. Chem., 1968, 7, 1532.
Hall, H. T. and Eyring, H., J. Am. Chem. Soc., 1950, 72, 782.
Chariot, G., Les Réactions Chimiques en Solution, Masson, Paris, 1969.
Tsuchida, E. and Nishide, H., Adv. Polym. Sci., 1977, 24, 1.
Gauthier-Manuel, B., Meyer, B. and Pieranski, P., J. Phys. E: Sci. Instrum., 1984, 17, 1177.
Adam, M. & Delsanti, M., Revue Phys. Appl., 1984, 19, 253.
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© 1988 Elsevier Applied Science Publishers Ltd
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Allain, C., Salomé, L. (1988). Physico-Chemistry of the Hydrolysed Polyacrylamide—Chromium III Interaction in Relation to Rheological Properties. In: Kramer, O. (eds) Biological and Synthetic Polymer Networks. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-1343-1_19
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DOI: https://doi.org/10.1007/978-94-009-1343-1_19
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-7097-3
Online ISBN: 978-94-009-1343-1
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