Skip to main content

Chelating reagents for flotation of sulphide minerals

  • Chapter

Abstract

Chelating reagents, because of their metal specificity, can function as effective mineral processing reagents.

This is a preview of subscription content, log in via an institution.

Buying options

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Healy T.W., Trahar W.J.. Challenges in mineral sulfide flotation. Challenges in mineral processing, Sastry K.V. ed., AIME, Colorado 1989.

    Google Scholar 

  2. Sutherland K.L. and Wark I.W.. Principles of flotation. Australasian Inst, of Mining metallurgy, Melbourne, 1855.

    Google Scholar 

  3. Rogers J.: Principles of sulfide mineral flotation. Fuerstenau M.C. ed, Froth Flotation, Gaudin A.M. memorial volume, AIME New York 1976.

    Google Scholar 

  4. Poling G.W.: Reactions between thiol reagent and sulfide minerals. Furestenau M.C. ed., Flotation, Gaudin A.M. memorial vol., AIME, New York 1976 pp. 334–363.

    Google Scholar 

  5. Ackerman P.K., Harris G.H., Klimpel R.R. and Aplan F.F.: Evaluation of flotation collectors for copper sulfides and pyrite I. Common Sulphydryl collectors. Int. Min. Proc., 21, 1987 pp. 105–127.

    Article  Google Scholar 

  6. Granville R., Finkelstein N.P. and S.A. Allison. Review of the reactions in the flotation system Galena-Xanthate-Oxygen, Trans. IMM, B, 1972.

    Google Scholar 

  7. Hagihara H. Mono and Multilayer Adsorption of Aqueous Xanthate on Galena Surfaces. J. Phys. Chem., 56, 1952, 616.

    Article  Google Scholar 

  8. Greenler R.G., An Infrared Investigation of Xanthate Adsorption by Lead Sulfide, J. Phys. Chem., 66, 1962, 879.

    Article  Google Scholar 

  9. Leja J., Little L.H. and Poling G.W., Xanthate Adsorption Using Infra-Red Spectroscopy. 1-Oxidized and Sulphidized Copper Substrates. 2-Evaporated lead Sulphide, Galena and Metallic Lead Substrates., Trans. IMM, 72, 1963, 407.

    Google Scholar 

  10. Piante E.C. and Sutherland K.L., Effects of Oxidation of Sulphide Minerals on Their Flotation Properties., Trans. AIME, 183, 1949, 160.

    Google Scholar 

  11. Herd H.H. and Ure W., Surface Chemistry in the Flotation of Galena., J. Phys. Chem. 45, 1941, 93.

    Article  Google Scholar 

  12. Taylor T.C. and Knoll A.F., Action of Alkali Xanthates on Galena., Trans. AIME, 112, 1934, 382.

    Google Scholar 

  13. Sparrow G., Pomianowski A. and Leja J., Soluble Copper Xanthate Complexes. Separation Science 12, 1977, 87.

    Article  Google Scholar 

  14. Gaudin A.M. and Schuhmann R., The action of Potassium n-Amyl Xanthate on Chalcocite., J. Phys. Chem. 40, 1936, 257.

    Article  Google Scholar 

  15. Heyes G.W. and Trahar W.J., Oxidation-Reduction Effects in the Flotation of Chalcocite and Cuprite., Int. J. of Min. Proc., 6, 1979, 229.

    Article  Google Scholar 

  16. Kowal A. and Pomianowski A., Cyclic Voltammetry of Ethyl Kanthate on a Natural Copper Sulphide Electrode., Electroanal. Chem. and Interfac. Electrochem. 46, 1973, 411.

    Article  Google Scholar 

  17. Richardson et al, Electrochemical Flotation of Sulfides: Chalcocite-Ethylxanthate Interaction. Int. J. of Min. Proc., 12, 1984, 87.

    Google Scholar 

  18. Walker G.W., Stout J.V. and Richardson P.E., Electrochemical Flotation of Sulfides: 1. Reactions of Chalcocite in Aqueous solutions. Int. J. Min. Proc. 12, 1984, 55.

    Article  Google Scholar 

  19. Gaudin A.M. and Finkelstein N.P., Interaction in the System PbS-KEX-O2., Nature, 201, 1965, 389.

    Article  Google Scholar 

  20. Finkelstein N.P., Kinetic and Thermodynamic Aspects of the Interaction Between Potassium Ethyl Xanthate and Oxygen in Aqueous Systems., Trans IMM, 76 1967, C51.

    Google Scholar 

  21. Finkelstein N.P., Quantitive Aspects of the Role of Oxygen in the Interaction Between Xanthate and Galena., Separation Science 5, 1970, 227.

    Article  Google Scholar 

  22. Gardener J.R. and Woods R., The Use of A Particulate Bed Electrode for the Electrochemical Investigation of Metal Sulfide Flotation., Aust. J. Chem., 26, 1973, 1635.

    Article  Google Scholar 

  23. Healy T.W. and Moignard M.S.: A review of electrokinetic study of metal sulfides. Fuerstenau M.C. ed., Flotation, Gaudin A.M. memorial vol., AIME N.Y. 1976, p. 275.

    Google Scholar 

  24. Woods R.: Electrochemistry of sulphide flotation. ed. Flotation, Gaudin A.M. memorial vol., Fuerstenau M.C. AIME NY 1976.

    Google Scholar 

  25. Richardson P.E., Monst E.E. Surface stoichiometry of Galena in aqueous electrolytes and its effect on xanthate interactions. Fuerstenau M.C. ed., Flotation, A.M. Gaudin memorial vol., AIME N.Y. 1976.

    Google Scholar 

  26. Nowak P. et al. The applicability of Emf measurements to evaluation of thermodynamic properties of the Cu-S system., J. Electroanal. Chem. 171, 1984, pp. 335–358.

    Article  Google Scholar 

  27. Nowak P., Krauss E., Pomianowski A.. The electrochemical characteristics of the galvanic corrosion of sulfide minerals in short-circuited model galvanic cells., Hydrometallurgy 12, 1984, pp. 95–110.

    Article  Google Scholar 

  28. Barzyk W., Malysa K., and Pomianowski A.. The influence of surface oxidation of chalcocite on its floatability and ethylxanthate sorption., Int. J. Min. Proc., 8, 1981, pp. 17–28.

    Article  Google Scholar 

  29. Chander S.: Oxidation reduction effects in depression of sulphide minerals. A review., Min. Met. Processing, 22, 1985, pp. 26–35.

    Google Scholar 

  30. Luttrell G.M., Joon R.M.. Surface studies of the collectorless flotation of chalcopyrite., Coll. Surf, 12, 1984, pp. 239–254.

    Article  Google Scholar 

  31. Giesekke E.W.. A review of spectroscopic techniques applied to the study of interactions between minerals and reagents in flotation systems., Int. J. Miner. Process., 11, 1983, 19–56.

    Article  Google Scholar 

  32. Kongolo M., Cases J.M., Burreau A. and Predali J.J.. Spectroscopic study of potassium amylxanthate adsorption on finely ground galena. M. Jones and R. Oblatt (Editors), Reagents in the Minerals Industry. IMM, Rome, 1984, pp. 79–87.

    Google Scholar 

  33. Walker G.W., Richardson P.E. and Buckley A.N.. Workshop on the flotation related surface chemistry of sulfide minerals., Int. J.M. Proc. 25, 1989, 155–158.

    Google Scholar 

  34. Little L.M., Poling G.W., Leja J.: IR spectra of xanthates compounds., Can. J. Chem., 39, 1989, 745–754.

    Article  Google Scholar 

  35. Marabini A.M., Cozza C.. Determination of lead ethylxanthate on mineral surface by IR spectroscopy., Spectrochim. Acta, 388, 1983, p. 215.

    Google Scholar 

  36. Mielczarski J. and Leppinen J.: Infrared reflection-absorption spectroscopy study of adsorption of xanthates on copper., Surf. Sci, 187, 1987, pp. 526–538.

    Article  ADS  Google Scholar 

  37. Mielczarski J., Nowak P., Strojek J.W. and Pomianoxski A.. Investigation of the products of ethylxanthate sorption on sulfides by IR-ATR spectroscopy, in J. Laskowski ed. Proc of the XIII Int. Min. Proc. Congress, Warszawa Part. A 1981, pp. 40–131, 1981.

    Google Scholar 

  38. Mielezarski J. In situ ATR-IR spectroscopic study of xanthate sorption an marcasite., Coll. Surf., 17, 1986, 235–248.

    Google Scholar 

  39. Leppinen J.O., Basilio C.I. and Yoon R.H.. FTIR study of thionocarbamate adsorption on sulfide minerals., Coll. Surf., 32, 1988, 113-125.

    Article  Google Scholar 

  40. Leppinen J.O., Basilio C.I. and Yoon R.H. In situ FTIR study of ethylxanthate adsorption on sulfide minerals under conditions of controlled potential., Int. J. Min. Proc., 26, 1989, 259–274.

    Article  Google Scholar 

  41. Johansson L.S., Juhanoja J., Laajalehto K., Suoninen E., Mielczarski J. XPS studies of xanthate adsorption on metals and sulfides., Surf. Interf. Anal., 9, pp. 1986, 501-505.

    Google Scholar 

  42. Termes S.C., Richardson P.E.. Application of FTIR spectroscopy for on situ studies of sphalerite with aqueous solutions of KETX and with diethyldixanthogen., Int. J. Min. Proc., l8, 1986, p. 167–178.

    Article  Google Scholar 

  43. Mielczarski J., XPS study of ethyl xanthate adsorption on oxidized surface of cuprous sulphide., J. Colloid Interface Sci., 120, 1987, 201–209.

    Article  Google Scholar 

  44. Laajalehto K., Johansson L.S., Mielczarski J., Anderson S. and Souninen E.. Electron spectroscopic studies of interaction of xanthate collectors with different substrates. In K.S.E. Forssberg (Editor), Proceedings of the XVI International Mineral Processing Congress, Stockholm, 1988, pp. 691–702.

    Google Scholar 

  45. Mielczarski J. and Minni E.. The adsorption of diethyldithiophasphate on cuprous sulphide., Surf. and Interf. Anal. 6, 1984, 221–226.

    Article  Google Scholar 

  46. Mielczarski J. and Suoninen E.. XPS study of ethylxanthate adsorbed onto cuprous sulphide., Surf and Interf. Anal., 6, 1984, 221–226.

    Article  Google Scholar 

  47. Mielczarski J. and Suoninen E.. XPS study of the oxidation of cuprous sulphide in aerated aqueous solutions., Coll. Surf, 33, 1988, p. 231–237.

    Article  Google Scholar 

  48. Cécile J.S., Bloise R., Barbery G. Galena depression with Chromate ions after flotation with xanthates. A kinetic and spectrometric study in Jones M. ed. Complex sulphide ores. IMM., London, 1980, pp. 159–170.

    Google Scholar 

  49. Predali K.C. et al. XPS study of xanthate adsaption on peprite mineral surfaces., J. Coll Interf. Sci, 103, 1985, n. 1, 1985.

    Google Scholar 

  50. Buckley A.M., Woods R. and Wauterlood H.J. An XPS investigation of the surface of natural sphalerites under flotation related conditions., Int. J. Min. Proc. 26, 1989, 29–49.

    Article  Google Scholar 

  51. Pillai K.C., Young U.Y. and Bankris O.M.. XPS studies of xanthate adsorption auto galena surfaces., Appl. Surf. Sci., 16, 1983, pp. 322–344.

    Google Scholar 

  52. Page P.W. and Hazell L.B. X ray photoelectron spectroscopy (XPS) studies of potassium amylxanthate (KAX) adsorption on precipitated PbS related to galena flotation., Int. J. Min. Proc., 25, 1989, pp. 87–100.

    Article  Google Scholar 

  53. Pillai K.C., Young V.Y. and Bockris Y.O.M. X-ray photoelectron spectroscopy studies of xanthate adsorption on pyrite mineral surfaces., J. Coll. Int. Sci, 103, 1985, pp. 145–153.

    Article  Google Scholar 

  54. Predali J.J., Brion D., Harper J., Pelletier B.. Charactérisation par spectroscopie ESCA des états de surface de mineraux sulfurés fines de Pb-Zu-Cu-Fe lors de la flottation. Proc. of the XIII Int. Min. Proc. Congress, Warsaw part A, 1981, p. 55.

    Google Scholar 

  55. Mielczarski J., Suoninen E. Johansson L.S. and K. Laajalehto An XPS study of adsorption of methyl and amyl-xanthates an copper., Int. J. Min. Proc. 26, 1989, p. 181-191.

    Article  Google Scholar 

  56. Bertil I. Palsson and K.S.E. Forssberg. Computer-assisted calculations of thermodynamic Equilibria in Sphaleritexanthate system., Int. J. Min. Proc., 1989, 26, 223–258.

    Article  Google Scholar 

  57. Bertil I. Palsson and Forssberg RSE, Computer-assisted calculations of thermodynamic Equilibria in the galena — ethylxantate system., Int. J. Min. Proc., 23, 1988, 93–121.

    Article  Google Scholar 

  58. Partyka S., Arnaud M., Lindheimer M.. Adsorption of Ethyl-xanthate onto Galena at low surface coverages., Coll. Surf., 26, 1987, 141–153.

    Article  Google Scholar 

  59. Maillot M., Cécile J.L., Bloise R.. Stability of ethylxanthate ion in neutral and weakly acidic media., Int. J. Min. Proc., 13, 1984, 193–210.

    Article  Google Scholar 

  60. Shimoizaka J. et al. Depression of galena flotation by sulfite or Chromate ion, in Fuerstenau M.C. ed., Flotation, Gaudin A.M. memorial vol., AIME, NY, 1976.

    Google Scholar 

  61. Rinelli G., Marabini A., Alesse A.. Depressing action of permanganate on pyrite and galena flotation. Jones M.J. ed. Complex sulphide ores. Rome IMM, London, 1981, pp. 199.

    Google Scholar 

  62. Popov S.S. et al.. Effect of the depressing agents FeSo4 and NaCN on the surface properties 01 Galena in the flotation system., Int. J. Min. Proc. 24, 1988, 111–123.

    Article  ADS  Google Scholar 

  63. Eigillani D.A. and Fuerstenau M.C.. Mechanisams involved in cyanide depression of pyrite., Trans. AIME, 241, 1968.

    Google Scholar 

  64. Steiningen J.. The depression of sphalerite and pyrite by basic complexes of copper and sulphidryl flotation collectors., Trans. AIME, 1968, p. 34.

    Google Scholar 

  65. Finkelstein N.P. Allison S.A.. The chemistry of activation, deactivation and depression in the flotation of zinc sulphides: a review. Fuerstenau M.C. ed. Flotation, Gaudin A.M. memorial volume, AIME New York, 1976, pp. 414–457.

    Google Scholar 

  66. Ball B., Richard R.S.. The chemistry of pyrite activation and depression. Fuerstenau M.C. and Flotation, Gaudin M.A. memorial volume, AIME, New York, 1976.

    Google Scholar 

  67. Ghiani M., Satta F., Barbaro M. and Passariello B.. Flotation of sphalerite from pyrite by use of copper xanthate and sodium cyanide. Reagents in minerals industry, ed. Jones M. and Oblatt, IMM 1984.

    Google Scholar 

  68. Chander S. Inorganic depressants for sulfide minerals” Reagents in Mineral Technology, P. Somasndaran and B. Moudgil eds., Marcel Dekker, New York, pp. 428–468.

    Google Scholar 

  69. Gutzeit G. Chelate-forming organic compounds as flotation reagents., Trans-AIME 1946, v. 169, p. 272.

    Google Scholar 

  70. Martell A., Calvin M. Chemistry of the metal chelate compounds, Prentice Hall, 1952.

    Google Scholar 

  71. Usoni L., Rinelli G., Marabini A.M.. Chelating agents and fuel oil: A new way to flotation, AIME Centennial Annual Meeting, New York, February 26-March 3, 1971.

    Google Scholar 

  72. Marabini A.M.. Flottazione e flocculazione selettiva., Boll. Ass. Min. Subalpina XIX, n. 3–4, 1982.

    Google Scholar 

  73. Rinelli G., Marabini A.M.. Flotation of zinc and lead oxide-sulphide ores with chelating agents, 10th Int. Min. Proc Congress, IMM, London, 1973.

    Google Scholar 

  74. Marabini A.M. New collector for cassiterite., Trans IMM, Sect. C. vol. 84, 1975, C 177.

    Google Scholar 

  75. Rinelli G., Marabini A.M., Alesse V. Flotation of cassiterite with salycilaldheide as a collector, Flotation, Gaudin A.M. Memorial volume Fuerstenau M.C.ed., vol. 1, 1976, p. 549.

    Google Scholar 

  76. Mangalam V. et al. Zeta potential and flotation studies of chalcopyrite fines with 8-hydroxyquinoline., Coll. Surf., 7, 1983, pp. 209–220.

    Article  Google Scholar 

  77. Marabini A.M., Rinelli G. Flotation of cobalt minerals with chelating agents as collectors., ATB Metallurgie, XXII 1, 1982, p. 17–22.

    Google Scholar 

  78. Marabini A.M., Barbaro M., Ciriachi M. A calculation method for selection of complexing collectors having selective acion an a cation., Trans IMM, Sec C, 92, 1983, CZ0-C26.

    Google Scholar 

  79. Marabini A.M.. Study od adsorption of Salicylaldhiede on cassiterite., Trans. IMM, Sect. C., 87, 1978, C75.

    Google Scholar 

  80. Marabini A.M., Rinelli G.. Development of a specific reagent for rutile flotation., SME Trans., 274, 1983, p. 1822.

    Google Scholar 

  81. Marabini A.M., Alesse V., Barbaro M. New synthetic collectors for selective flotation of zinc and lead oxidized minerals., XVI Int. Min. Proc. Congress, Forssberg ed. Elsevier, Amsterdam Vol. 1988, pp. 1197–1208.

    Google Scholar 

  82. Marabini A.M., Barbaro M., Passariello B. Flotation of cerussite with a synthetic chelating collector., Int. J. Min. Proc., 25, 1989, p. 29.

    Article  Google Scholar 

  83. Marabini A.M., Cases J., Barbaro M., Chelating reagents as collectors and their adsorption mechanism, Challenges in Mineral Processing, Sastry K.V., ed AIME, Colorado, 1989.

    Google Scholar 

  84. Cozza C., Di Castro V., Polzonetti G., Marabini A.M.. An X-Ray Photoelectron Spectroscopy Study of the Interaction of Mercapto-Benzo-Thiazole with cerussite, in press on Int. J. of Min. Proc.

    Google Scholar 

  85. Bornengo G., Marabini A.M. and Alesse V., Italian Patent 22019 A/89, 1989.

    Google Scholar 

  86. Acherman P.K., Harris G.H., Klimpel R.R. and Aplan F.F., Evaluation of flotation collectors for copper sulfides and pyrite. III Effect of Xanthate chain length and branching., Int. J. Min. Proc., 21, 1987 4–156.P

    Google Scholar 

  87. Pradip: Application of chelating agents in mineral processing., Min. Met. Proc., 80; 1988.

    Google Scholar 

  88. Ackerman P.K., Harris G.H., Klimpel R. and Aplan F.F., Effect of alkyl substituents perfomance on thionocarbamates as copper sulphide and pyrite collectors. Reagents in mineral industry, ed. Jones M.J. and Oblatt, IMM, Lond, 1984.

    Google Scholar 

  89. Somasundaran P. and Nagaraj P.R., Chemistry and applications of chelating agents in flotation and flocculation, Reagents in mineral industry, ed. Jones M.J. and Oblatt R., IMM, London, 1984.

    Google Scholar 

  90. Ackerman P.K., Harris G.H., Klimpel R.R. and Aplan F.F., Evaluation of flotation collectors for copper sulfides and pyrite II. Non-sulphydryl collectors., Int. J. Min. Proc., 21, 1987, pp 129–140.

    Article  Google Scholar 

  91. Klimpel R.R., Hansen R.D. and Fee B.S., New collector chemistries for sulfide mineral flotation; SME/AIME, Annual Meeting, Phoenix, Arizona, Jan 25–8, 1988.

    Google Scholar 

  92. Klimpel R.R., Hansen. Recent work on developing new sulfide mineral collectors based on chelation chemistry, SME/AIME Annual Meeting Las Vegas, Nevada, Febr. 27 - March 2, 1989.

    Google Scholar 

  93. Nagaraj D.R., Basilio C. and Yoon R.M.. The chemistry and structure-activity relationships for new sulfide collectors. 118th SME/AIME annual Meeting, Las Vegas, Nevada, Feb. 27 - March 2, 1989.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

P. M. J. Gray G. J. Bowyer J. F. Castle D. J. Vaughan N. A. Warner

Rights and permissions

Reprints and permissions

Copyright information

© 1990 The Institution of Mining and Metallurgy

About this chapter

Cite this chapter

Marabini, A., Barbaro, M. (1990). Chelating reagents for flotation of sulphide minerals. In: Gray, P.M.J., Bowyer, G.J., Castle, J.F., Vaughan, D.J., Warner, N.A. (eds) Sulphide deposits—their origin and processing. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0809-3_7

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-0809-3_7

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6851-2

  • Online ISBN: 978-94-009-0809-3

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics