Abstract
No truly specific chelating resin has yet been reported. Even high selectivity for a particular metal is in most cases achievable only under fairly circumscribed conditions, e.g. of pH, ionic strength, nature of the co-ion(s) present, temperature, or absence of other too-strongly competing metal species. Attempts to improve the capability of known selective materials have led to the laboratory synthesis of sorbents many of which would be incapable of economic manufacture in the quantities required for the uses proposed. However, some commercial applications are discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
de Calonne, C.A., “si c’est possible, c’est fait; impossible? ça se fera.” Cex Michelet’s Histoire de la Révolution Françoise, (1847), Vol. 1, part ii, §8, adapted. 1
Arnold, M(atthew), end of Preface to Literature and Dogma, 1883 edn.
Millar, J.R., “Design, Synthesis, & Applications of Chelating Ion-Exchange Resins”, I.R.S.A. Internal Rpt. No. 126, C.N.R., Italy, (1989)
Helfferich, F.G., J. Amer. Chem. Soc., (1962), 84, 3237, 3242.
Sengupta, A. & Roy, T., Ion Exchange for Industry, ed. M. Streat, Ellis Horwood Ltd., Chichester, 1988, 195–203.
see I.A.R.C. Monographs on the Evaluation of the Carcinogenic Risk of Chemicals to Humans, Vols. 1~20, WHO, Lyon, (1972–9)
Bryce-Smith, D., Chem. Brit., (1975), 11, 202–6.
d’ltri, P.A. & F.M., Mercury Contamination; a Human Tragedy, Wiley Interscience, New York, (1977).
Chem. & Ind., (1988), 269, 346.
Aluminium in Food and the Environment, eds. R. Massey & D. Taylor, Royal Society of Chemistry, Letchworth, (1989)
Bryce-Smith, D., Chem. Brit., (1972), 8, 240.
Millar, J.R., Chem. & Ind., 1957, 606–12.
Nickless, G. & Marshall, G.R.. Chromatog. Rev., (1964), 6, 154–190.
Lindsay, D., & Sherrington, D.C., React. Polym., (1985), 3, 327–39.
Warshawsky, A., Israel J. Chem. (1979), 18, 318–24.
Morris. L.R., to Dow Chemical Co., U.S. Pat. 2,875,162 (1959). b) Mock, R.A., Marshall, C.A. & Morris, L.R., to Dow Chemical Co., U.S. Pat. 2,910, 445 (1959)
Rosset, R., Bull. Soc. Chim. France, 1964, pp. 1845 et seq.. 1966, (1), pp. 59 et seq.. b) Rosset, R., D.Sc. thesis, Paris, 6 June 1967, C.N.R.S. no.AO 1490.
c.f. Hering, R., Chelatbildende Ionenaustauscher, Akademie Verlag, Berlin, (1967)
Kressman, R.E., Ion Exchange & its Applications, (discussion, p. 22 ), S.C.I. London, 1955.
Kennedy, J., & Ficken, G.E., J. Appl. Chem., (1958), 8, 465–8.
Manecke, G., & Heller, H., Angew. Chemie, 1960, 72, pp. 532 et seq.
Szczepaniak, W., Chemia Analitycz Warsaw, (1973), 18 (5), 1019–26.
Eccles, H., in Ion Exchange Technology, eds. D. Naden & M. Streat, Ellis Horwood, Chichester ( 1984. 698–708.
Gonzalez-Luque, S., & Streat, M., in Ion Exchange Technology, edited by D. Naden & M. Streat, Ellis Horwood, Chichester ( 1984, 679–689.
Cerny, J.. & Wichterle, O., J. Polymer Sci., (1958), 30, 501–12.
Koster, G., & Schmuckler, G., Anal. Chim. Acta,(1967), 179, pp.38 et seq.
Warshawsky, A. in Ion Exchange & Sorption Processes in Metallurgy, (Critical Reports on Applied Chemistry, Vol. 19, eds. M. Streat & D. Naden, John Wiley, London (1987), 127–65.
Nakamura, Y., J. Chem. Soc. Japan, Ind. Chem. Sect., (1955), 58, 269–73.
Gregor, H.P., Dolar, D., & Hoeschele, G.K., J. Amer. Chem. Soc., (1955), 77, pp. 3675 et seq.
Parrish, J.R., Chem. & Ind., 1956, 137.
Varshawsky, A., in Ion Exchange & Sorption Processes in Metallurgy, (Critical Reports on Applied Chemistry, Vol. 19, eds. M. Streat & D. Naden, John Wiley, London (1987), 166–225.
Grinstead, R.R., J. Metall., (1979), 31, 13–16.
Gold, H., Czupryna, G., Levy, R.D., Calmon, C., & Gross, R.L., in Metals Speciation, Separation & Recovery, eds. R. Paterson & R. Passino, Lewis Publishers, Chelsea MI. (1987), 619–645.
see Reference 26.
Kennedy, D.C., Becker, A.P., & Worcester, A.A., in Metals Speciation, Separation & Recovery, eds. R. Paterson & R. Passino, Lewis Publishers, Chelsea MI, (1987), 593–613.
Booker, N.A. & Streat, M., in Ion Exchange for Industry, ed. M. Streat, Ellis Horwood, Chichester (1988), 617–31.
Anderson, R.E., in A.I.Ch.E Symposium Series, (1975), 71 (152), pp.236 et seq.
Millar, J.R. & Kressman, T.R.E., Brit. Pat. 812,815 (29 Apr. 1959 ).
Petruzzelli, D., Millar, J.R., & Tiravanti, G., unpublished work.
Higgins, I.R. & Messing. A.F., ORNL-2491 (1958), see NucL Sci. Abstr. (1959). 13, 68.
Hodgkin, J.H., & Eibl, R., React. Polym., (1985), 3, 83–89.
Idem, ibid., (1986), 4, 285–91.
Tiravanti, G., Petruzzelli, O., Liberti, L., & Passino, R.,(paper “Specific Resins for Metal Ion Separation; The Cr(III), Fe(III ), AI(III) System”, this volume 1990 ).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1990 Elsevier Science Publishers Ltd
About this chapter
Cite this chapter
Millar, J.R., Petruzzelli, D., Tiravanti, G. (1990). Some Problems in the Use of Chelating Resins for Environmental Protection from Toxic Metals. In: Williams, P.A., Hudson, M.J. (eds) Recent Developments in Ion Exchange. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0777-5_32
Download citation
DOI: https://doi.org/10.1007/978-94-009-0777-5_32
Publisher Name: Springer, Dordrecht
Print ISBN: 978-94-010-6836-9
Online ISBN: 978-94-009-0777-5
eBook Packages: Springer Book Archive