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New Cross-Linked Layered Tin Phosphate Exchangers

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Recent Developments in Ion Exchange

Abstract

A new class of composite inorganic exchangers has been prepared by the intercalation and calcination of highly polymerised Cr3+ polyhydroxide species into α-tin phosphate. The materials have free heights of 6.7 and 7.6 Å and surface areas of 198- and 219 m2 g-1. There is some saturation of potential exchange sites by the chromia pillars. Nevertheless, cation exchange capacities for Co2 +, Ni2+, Cu2+, and Pr3+ are still relatively high. They are promising as selective ion exchangers.

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Author information

Authors and Affiliations

  1. Departamento de Quimica Inorganica, Universidad de Malaga, Apartado 59, 29080, Malaga, Spain

    Pedro Maireles-Torres, Pascual Olivera-Pastor, Enrique Rodriguez-Castellon & Antonio Jimenez-Lopez

  2. I.T.S.E., Area della Ricerca di Roma, C.N.R., C.P. 10, Monterotondo Stazione, 00016, Roma, Italy

    Anthony A. G. Tomlinson

Authors
  1. Pedro Maireles-Torres
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  2. Pascual Olivera-Pastor
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  3. Enrique Rodriguez-Castellon
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  4. Antonio Jimenez-Lopez
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  5. Anthony A. G. Tomlinson
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Editor information

Editors and Affiliations

  1. Research Division, The North East Wales Institute, Deeside,Clwyd, Wales, UK

    P. A. Williams

  2. Chemistry Department, University of Reading, Whiteknights, Reading, UK

    M. J. Hudson

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© 1990 Elsevier Science Publisher Ltd

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Maireles-Torres, P., Olivera-Pastor, P., Rodriguez-Castellon, E., Jimenez-Lopez, A., Tomlinson, A.A.G. (1990). New Cross-Linked Layered Tin Phosphate Exchangers. In: Williams, P.A., Hudson, M.J. (eds) Recent Developments in Ion Exchange. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0777-5_10

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  • DOI: https://doi.org/10.1007/978-94-009-0777-5_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6836-9

  • Online ISBN: 978-94-009-0777-5

  • eBook Packages: Springer Book Archive

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