Abstract
The phase separation of polymer-solvent systems is detected by means of dynamic light scattering with a much higher sensitivity than with other methods in use up to now. The spinodal temperature can be determined from the extrapolation of the temperature dependence of the translational diffusion coefficient D at constant composition. The extrapolation of D to zero concentration leads to the mobility of the polymer.
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© 1990 Elsevier Science Publishers Ltd
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Philipps, T., Borchard, W. (1990). Light Scattering Measurements in the System Polystyrene-Cyclohexane Near the Miscibility Gap. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0767-6_4
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DOI: https://doi.org/10.1007/978-94-009-0767-6_4
Publisher Name: Springer, Dordrecht
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