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Characterization of Ionic Oligomers Formed During the Emulsion Polymerization of Butadiene by Means of Isotachophoresis

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Integration of Fundamental Polymer Science and Technology—4

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Abstract

The end products of several emulsion polymerizations of butadiene with potassium persulfate as initiator were analyzed by means of isotachophoresis. The results were compared with the analyses of model compounds. The isotachopherograms of the products of surfactant free emulsion polymerizations as well as of polymerization with dresinate 214 as surfactant show oligomers with one or two sulfate end groups and up to 5 monomeric units.

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Author information

Authors and Affiliations

  1. Laboratory of Polymer Chemistry, Eindhoven University of Technology, P.O.Box 513, 5600 MB, Eindhoven, The Netherlands

    J. L. Ammerdorffer, C. G. Pijls, A. A. Lemmens & A. L. German

Authors
  1. J. L. Ammerdorffer
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  2. C. G. Pijls
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  3. A. A. Lemmens
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  4. A. L. German
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Editor information

Editors and Affiliations

  1. Eindhoven University of Technology, Eindhoven, The Netherlands

    P. J. Lemstra

  2. DSM-Research, Geleen, The Netherlands

    L. A. Kleintjens

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© 1990 Elsevier Science Publishers Ltd

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Ammerdorffer, J.L., Pijls, C.G., Lemmens, A.A., German, A.L. (1990). Characterization of Ionic Oligomers Formed During the Emulsion Polymerization of Butadiene by Means of Isotachophoresis. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0767-6_21

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  • DOI: https://doi.org/10.1007/978-94-009-0767-6_21

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6831-4

  • Online ISBN: 978-94-009-0767-6

  • eBook Packages: Springer Book Archive

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