Skip to main content

Abstract

The “bridging” function for connecting dilute and concentrated regimes in polymer solution thermodynamics has heretofore been applied only to poor solvents and two-phase systems. A comparison of the bridging treatment in an athermal solution (good-solvent system) with a modern cross-over formula due to Ohta and Oono shows that the former gives a rather satisfactory representation of the osmotic pressure.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Flory, P.J., J. Chem. Phys., 1945, 13, 453.

    Article  CAS  Google Scholar 

  2. Flory, P.J. Principles of Polymer Chemistry, Cornell University Press, Ithaca, 1953, Chaps. VII and XII.

    Google Scholar 

  3. Flory, P.J., J. Chem. Phys., 1942, 10, 51.

    Article  CAS  Google Scholar 

  4. Huggins, M.L., Ann. N.Y. Acad. Sci., 1942, 41, 1.

    Article  Google Scholar 

  5. Staverman, A.J., Rec. trav. chim., 1941, 60, 640.

    Article  CAS  Google Scholar 

  6. McMillan, W.G., and Mayer, J.E., J. Chem. Phys., 1945, 13, 276.

    Article  CAS  Google Scholar 

  7. Zimm, B.H., J. Chem. Phys., 1946, 14, 164.

    Article  CAS  Google Scholar 

  8. Flory, P.J., and Krigbaum, W.R., J. Chem. Phys., 1950, 18, 1086.

    Article  CAS  Google Scholar 

  9. Casassa, E.F., and Markovitz, H., J. Chem. Phys., 1958, 29, 493.

    Article  CAS  Google Scholar 

  10. Yamakawa, H., Modern Theory of Polymer Solutions, Harper & Row, New York, 1971, Chap. IV.

    Google Scholar 

  11. Fixman, M., J. Chem. Phys., 1960, 33, 370.

    Article  CAS  Google Scholar 

  12. Fixman, M., and Peterson, J.M., J. Amer. Chem. Soc., 1964, 86, 3524.

    Article  CAS  Google Scholar 

  13. Edwards, S.F., Proc. Phys. Soc. (London), 1966, 88, 265.

    Article  CAS  Google Scholar 

  14. Koningsveld, R., Stockmayer, W.H., Kennedy, J.W., and Kleintjens, L., Macromolecules, 1974, 7, 73.

    Article  CAS  Google Scholar 

  15. Chapela, G., and Rowlinson, J.S., J. Chem. Soc., Faraday I, 1974, 70, 584.

    Article  CAS  Google Scholar 

  16. Benedict, M., Webb, G.B., and Rubin, L.C., J. Chem. Phys., 1940, 8, 334.

    Article  CAS  Google Scholar 

  17. DePablo, J.J., and Prausnitz, J.M., A.I. Ch. E. Journal, 1988.

    Google Scholar 

  18. Breitenbach, J.W., and Wolf, B.A., Makromol. Chem., 1967, 108, 263.

    Article  CAS  Google Scholar 

  19. Kleintjens, L.A., Koningsveld, R., and Stockmayer, W.H., Brit. Polym. J, 1976, 8, 144.

    Article  CAS  Google Scholar 

  20. Irvine, P., and Gordon, M., Macromolecules, 13, 761.

    Google Scholar 

  21. DeGennes, P.G., Scaling Concepts in Polymer Physics, Cornell University Press, Ithaca, 1979, Chap. III.

    Google Scholar 

  22. DesCloizeaux, J., J. Phys. (Les Ulis, Fr.), 1981, 42, 635.

    Article  CAS  Google Scholar 

  23. Noda, I., Higo, Y., Ueno, N., and Fujimoto, T., Macromolecules, 1984, 17, 1055.

    Article  CAS  Google Scholar 

  24. DesCloizeaux, J., J. Phys. (Les Ulis, Fr.), 1981, 42, 635.

    Article  CAS  Google Scholar 

  25. Knoll, A., Schafer, L., and Witten, T.A., J. Phys. (Les Ulis, Fr.), 1981, 42, 767.

    Article  CAS  Google Scholar 

  26. Schafer, L., Macromolecules, 1982, 15, 652.

    Article  Google Scholar 

  27. Ohta, T., and Oono, Y., Phys. Lett. A, 1982, 89A, 460.

    Article  CAS  Google Scholar 

  28. Muthukumar, M., and Edwards, S.F., J. Chem. Phys., 1982, 76, 2720.

    Article  CAS  Google Scholar 

  29. Schulz, G.V., and Stockmayer, W.H., Makromol. Chem., 1986, 187, 2235.

    Article  CAS  Google Scholar 

  30. Hager, B.L., Berry, G.C., and Tsai, H.-H., J. Polym. Sci., Polym. Phys. Ed., 1987, 25, 387.

    Article  CAS  Google Scholar 

  31. Miller, A.R., Proc. Cambridge Philos. Soc., 1939, 38, 109.

    Article  Google Scholar 

  32. Guggenheim, E.A., Proc. Roy. Soc., London, A 1944, 183, 203.

    Article  CAS  Google Scholar 

  33. Kurata, M., Ann. N.Y. Acad. Sci., 1961, 89, 635.

    Article  CAS  Google Scholar 

  34. Freed, K.F., and Bawendi, M.G., J. Phys. Chem., 1989, 93, 2194.

    Article  CAS  Google Scholar 

  35. Bellemans, A., and DeVos, E., IUPAC Symposium on Macromolecules, Helsinki, 1972.

    Google Scholar 

  36. Madden, W.G., private communication, 1989.

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1990 Elsevier Science Publishers Ltd

About this chapter

Cite this chapter

Stockmayer, W.H. (1990). Bridging Treatment of Polymer Solutions In Good Solvents. In: Lemstra, P.J., Kleintjens, L.A. (eds) Integration of Fundamental Polymer Science and Technology—4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0767-6_1

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-0767-6_1

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6831-4

  • Online ISBN: 978-94-009-0767-6

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics