Skip to main content
SpringerLink
Log in
Book cover

Hydrothermal Reactions for Materials Science and Engineering pp 168–171Cite as

Hydrothermal crystal growth of perovskite-type fluorides

  • Chapter

  • 589 Accesses

Abstract

Single crystals of perovskite-type fluorides were grown from potassium fluoride and di-valent metal chloride solutions by a hydrothermal method under a temperature gradient, at maximum temperature 600° C and pressure 98 MPa. Single-crystal cubes of KMnF3, KFeF3, KCoF3 and KZnF3, of cube edge sizes ranging from 0.2 to 2.0 mm, were grown. Crystals of KNiF3 grew in rectangular prisms and those of KCdF3 in anhedral form. Single crystals of KCuF3 were grown in pure water from co-precipitated KCuF3 powder. KMgF3 crystals were not grown by this method.

This is a preview of subscription content, log in via an institution.

Chapter
USD   29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD   84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD   109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Learn about institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. K. Hirakawa, K. Hirakawa and T. Hashimoto, J. Phys. Soc. Japan 15 (1960) 2063.

    Article  CAS  Google Scholar 

  2. K. Knox, Acta Cryst. 14 (1961) 583.

    Article  CAS  Google Scholar 

  3. Y. Suemune and H. Ikawa, J. Phys. Soc. Japan 19 (1964) 1686.

    Article  CAS  Google Scholar 

  4. W. W. Holloway and M. Kestigian, J. Chem. Phys. 45 (1966) 639.

    Article  CAS  Google Scholar 

  5. K. Gesi, J. D. Axe and G. Shirane, Phys. Rev. B5 (1972) 1033.

    Google Scholar 

  6. E. S. Svensson, W. J. L. Buyers, T. M. Holden, R. A. Cowley and R. W. H. Stevenson, Canadian J. Phys. 47 (1969) 1983.

    Article  CAS  Google Scholar 

  7. R. H. Rose, J. E. Rhoads and L. E. Halliburton, Phys. Rev. B14 (1976) 3583.

    Google Scholar 

  8. H. Takeuchi, K. Horai and M. Arakawa, J. Phys. Soc. Japan 46 (1979) 18.

    Article  CAS  Google Scholar 

  9. R. Leckebusch, J. Crystal Growth 23 (1974) 74.

    Article  CAS  Google Scholar 

  10. B. J. Garrard, B. M. Wanklyn and S. H. Smith, J. Crystal Growth 22 (1974) 169.

    Article  CAS  Google Scholar 

  11. B. M. Wanklyn, J. Crystal Growth 5 (1969) 279.

    Article  CAS  Google Scholar 

  12. M. Safa, B. K. Tanner, B. J. Garrard and B. M. Wanklyn, J. Crystal Growth 39 (1977) 243.

    Article  CAS  Google Scholar 

  13. R. Leckebusch, Fortshr. Miner. 55 (1977) 9.

    CAS  Google Scholar 

  14. D. Skrzypek, P. Jakubowski, A. Ratuszna and A. Chezkowski, J. Crystal Growth 48 (1980) 475.

    Article  CAS  Google Scholar 

  15. S. Hirano, K. Yanagisawa and S. Sōmiya, J. Crystal Growth 48 (1980) 475., to be published.

    Article  Google Scholar 

Download references

Author information

Author notes

  1. Shin-Ichi Hirano

    Present address: Synthetic Crystal Research Laboratory, Faculty of Engineering, Nagoya University, 1 Furo-cho, Chikusa, Nagoya, 464, Japan

Authors and Affiliations

  1. Laboratory for Hydrothermal Syntheses, Research Laboratory of Engineering Materials and Department of Material Science and Engineering, Tokyo Institute of Technology, Nagatsuta, Midori, Yokohama, 227, Japan

    Shigeyuki Sōmiya, Shin-Ichi Hirano, Masahiro Yoshimura & Kazumichi Yanagisawa

Authors
  1. Shigeyuki Sōmiya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shin-Ichi Hirano
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Masahiro Yoshimura
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Kazumichi Yanagisawa
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. The Nishi-Tokyo University, Japan

    Shigeyuki Sōmiya

Rights and permissions

Reprints and permissions

Copyright information

© 1989 Elsevier Science Publishers Ltd

About this chapter

Cite this chapter

Sōmiya, S., Hirano, SI., Yoshimura, M., Yanagisawa, K. (1989). Hydrothermal crystal growth of perovskite-type fluorides. In: Sōmiya, S. (eds) Hydrothermal Reactions for Materials Science and Engineering. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0743-0_26

Download citation

  • DOI: https://doi.org/10.1007/978-94-009-0743-0_26

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-94-010-6819-2

  • Online ISBN: 978-94-009-0743-0

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics

Search

Navigation