Abstract
Ultrafast fluorescence spectroscopy has been used to study two processes: (i) the transient solvation of electronically excited coumarin probes and (ii) the solvent mediated excited state intramolecular electron (charge) transfer of 9,9′—bianthryl and related compounds. The solvation measurements have been analyzed in terms of contemporary theory to gain insight on the molecular aspects of microscopic motion in polar liquids. The excited state electron transfer (et) examples are well modeled by an electronically adiabatic approach, employing an “outer sphere” generalized Langevin equation description of motion along the et reaction coordinate. The relationship between solvation and electron transfer dynamics is discussed.
Keywords
- Propylene Carbonate
- Solvation Dynamic
- Mean Spherical Approximation
- Generalize Langevin Equation
- Average Relaxation Time
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W. R. Ware, S. K. Lee, G. J. Brandt and P. P. Chow, J. Chem. Phys. 54, 4729 (1971).
R. P. DeToma and L. Brand, Chem. Phys. Lett. 47, 231 (1977).
Y. T. Mazurenko and V. S. Udaltsov, Opt. Spectrosc. 45, 765 (1978)
Y. T. Mazurenko and V. S. Udaltsov, Opt. Spektrosk. 45, 909 (1978).
L. A. Hallidy and M. R. Topp, Chem. Phys. Lett. 48, 40 (1977).
S. L. Shapiro and K. R. Winn, Chem. Phys. Lett. 71, 440 (1980).
T. Okamura, M. Sumitani and K. Yoshihara, Chem. Phys. Lett. 94, 339 (1983).
M. Maroncelli and G. R. Fleming, J. Chem. Phys. 86, 6221 (1987);
E. W. Castner Jr., M. Maroncelli, and G. R. Fleming, J. Chem. Phys. 86, 1090 (1987).
V. Nagarajan, A. M. Brearley, T. J. Kang and P. F. Barbara, J. Chem. Phys. 86, 3183 (1987).
A. Declémy and C. Rullière, Chem. Phys. Lett. 145, 262 (1988);
A. Declémy and C. Rullière, Chem. Phys. Lett. 146, 1 (1988);
A. Declémy, C. Rullière and Ph. Kottis, Chem. Phys. Lett. 133, 448 (1987);
C. Rullière, Z. R. Grabowski and J. Dobkowski, Chem. Phys. Lett. 137, 408 (1987).
S.-G. Su and J. D. Simon J. Phys. Chem. 91, 2693 (1987).
S. Kinoshita, N. Nishi and T. Kushida, Chem. Phys. Lett. 134, 605 (1987).
H. E. Lessing and M. Reichert, Chem. Phys. Lett. 46, 111 (1976).
A. M. Brearley, A. J. G. Strandjord, S. R. Flom and P. F. Barbara, Chem. Phys. Lett. 113, 43 (1985).
S. R. Meech, D. V. O’Connor, D. Philips and A. G. Lee, J. Chem. Soc., Faraday Trans 2, 79, 1563, (1983).
M. A. Kahlow, T. J. Kang and P. F. Barbara, J. Phys. Chem. 91, 6452 (1987).
M. A. Kahlow, T. J. Kang and P. F. Barbara, J. Chem. Phys. 88, 2372 (1988).
M. A. Kahlow, W. Jarzçba, T. J. Kang and P. F. Barbara, J. Chem. Phys. 90, 151, (1989).
W. Jarzeba, G. C. Walker, A. E. Johnson, M. A. Kahlow and P. F. Barbara, J. Phys. Chem. 92, 7039 (1988).
L. Onsager, Can. J. Chem. 55, 1819 (1977).
J. Hubbard and L. Onsager, J. Chem. Phys. 67, 4850 (1977).
M. Rao and B. J. Berne, J. Phys. Chem. 85, 1498 (1981).
D. Calef and P. G. Wolynes, J. Chem. Phys. 78, 4145 (1983).
P. G. Wolynes, J. Chem. Phys. 86, 5133 (1987).
V. Friedrich and D. Kivelson, J. Chem. Phys. 86, 6425 (1987).
R. F. Loring and S. Mukamel, J. Chem. Phys. 87, 1272 (1987);
R. F. Loring, Y. J. Yan, and S. Mukamel, J. Phys. Chem. 91, 1302 (1987).
I. Rips, J. Klafter and J. Jortner, J. Chem. Phys. 88, 3246 (1988).
A. L. Nichols III and D. F. Calef, J. Chem. Phys. 89, 3783, (1988).
I. Rips, J. Klafter and J. Jortner, J. Chem. Phys. 89, 4288 (1988).
M. Maroncelli and G. R. Fleming, J. Chem. Phys. 89, 875 (1988).
E. W. Castner, Jr, G. R. Fleming, B. Bagchi and M. Maroncelli, J. Chem. Phys. 89, 3519 (1988).
E. W. Castner, Jr., G. R. Fleming and B. Bagchi, Chem. Phys. Lett. 143, 270 (1988);
E. W. Castner, Jr., B. Bagchi and G. R. Fleming, Chem. Phys. Lett. 148, 269 (1988).
A. Chandra and B. Bagchi, J. Chem. Phys. in press.
A. Chandra and B. Bagchi, Chem. Phys. Lett. 151, 47 (1988).
B. Bagchi and A. Chandra, Chem. Phys. Lett, in press.
A. Chandra and B. Bagchi, J. Chem. Phys. in press.
R. A. Marcus, J. Chem. Phys. 38, 1858 (1963);
R. A. Marcus, J. Chem. Phys. 43, 1261 (1965).
C. J. F. Böttcher and P. Bordewijk, Theory of Electronic Polarization, Elsevier, Amsterdam, 1978, Vol. 2.
N. G. Bakshiev, Opt. Spectrosc. 16, 446 (1964)
N. G. Bakshiev, Opt. Spektrosk. 16, 821 (1964) and earlier papers in this series.
Y. T. Mazurenko and N. G. Bakshiev, Opt. Spectrosc. 28, 490 (1970)
Y. T. Mazurenko and N. G. Bakshiev, Opt. Spektrosk. 28, 905 (1970).
Y. T. Mazurenko and V. S. Udaltsov, Opt. Spectrosc. 44, 417 (1978)
Y. T. Mazurenko and V. S. Udaltsov, Opt. Spektrosk. 44, 714 (1978).
Y. T. Mazurenko, Opt. Spectrosc. 48, 388 (1980)
Y. T. Mazurenko, Opt. Spektrosk. 48, 704 (1980).
J. D. Simon, Acc. Chem. Res. 21, 128 (1988).
B. Bagchi, D. W. Oxtoby and G. R. Fleming, Chem. Phys. 86, 257 (1984).
G. van der Zwan and J. T. Hynes, J. Phys. Chem. 89, 4181 (1985).
H. L. Friedman, J. Chem. Soc., Faraday Trans. 2, 79, 1465 (1983).
H. Sumi and R. A. Marcus, J. Chem. Phys. 84, 4272 (1986).
M. Maroncelli and G. R. Fleming, J. Chem. Phys. 89, 5044 (1988);
M. Maroncelli, E. W. Caster, Jr., B. Bachi, and G. R. Fleming, Faraday Discuss. Chem. Soc., 85, 1 (1988).
O. A. Karim, A. D. J. Haymet, M. J. Banet and J. D. Simon, J. Phys. Chem. 92, 3391 (1988).
D. B. Siano and D. E. Metzler, J. Chem. Phys. 51, 1856 (1969).
W. Jarzęba, G. C. Walker, A. E. Johnson and P. F. Barbara, in preparation (C 153).
G. C. Walker, W. Jarzęba, A. E. Johnson, and P. F. Barbara, in preparation (C 343).
S. Engström, B. Jönsson and R. W. Impey, J. Chem. Phys. 80, 5481 (1984).
L. D. Zusman, Chem. Phys. 49, 295 (1980);
L. D. Zusman, Chem. Phys. 80, 29 (1983);
L. D. Zusman, Chem. Phys. 119, 51 (1988);
G. Van der Zwan and J. T. Hynes, J. Chem. Phys. 76, 2993 (1982);
J. T. Hynes, J. Phys. Chem. 90, 3701 (1986);
D. F. Calef and P. G. Wolynes, J. Phys. Chem. 87, 3387 (1983);
H. Sumi and R. A. Marcus, J. Chem. Phys. 84, 4894 (1986);
W. Nadler and R. A. Marcus, J. Chem. Phys. 86, 3906 (1987);
I. Rips and J. Jortner, J. Chem. Phys. 87, 2090 (1987);
I. Rips and J. Jortner, J. Chem. Phys. 87, 6513 (1987);
I. Rips and J. Jortner, J. Chem. Phys. 88, 818 (1988);
I. Rips and J. Jortner, Chem. Phys. Lett. 133, 411 (1987);
M. Sparpaglione and S. Mukamel, J. Chem. Phys. 88, 3266 (1988);
M. Sparpaglione and S. Mukamel, J. Chem. Phys. 88, 1465 (1988);
M. D. Newton and H. L. Friedman, J. Chem. Phys. 88, 4460 (1988);
I. Rips and J. Jortner, Chem. Phys. Lett. 133, 411 (1987);
G. E. McManis, A. K. Mishra, and M. J. Weaver, J. Chem. Phys. 86, 5550 (1987);
A. Warshel and J-K. Hwang, J. Chem. Phys. 84, 4938 (1986);
J-K. Hwang, S. Creighton, G. King, D. Whitney, and A. Warshel, J. Chem. Phys., in press;
M. Morillo and R. I. Cukier, J. Chem. Phys., in press;
J. Jortner and M. Bixon, J. Chem. Phys. 88, 167 (1988);
I. Rips, K. Klafter, and J. Jortner, Proc. IPS-7, Chicago, 1988, Elsevier Science Publishers, Amsterdam.
R. A. Marcus, J. Chem. Phys. 24, 966 (1956);
R. A. Marcus, J. Chem. Phys. 24, 979 (1956);
R. A. Marcus, Ann. Rev. Phys. Chem. 15, 155 (1964);
V. G. Levich and R. R. Dogonadze, Dokl. Akad. Nauk. SSSR 124, 123 (1959).
J. Ulstrup, “Charge Transfer Processes in Condensed Media”, Springer Verlag, Berlin, 1079.
A. Mozumder, J. Chem. Phys. 50, 3153, (1969).
A. Mozumder, J. Chem. Phys. 50, 3162 (1969).
E. M. Kosower and D. Huppert, Ann. Rev. Phys. Chem. 37, 127 (1986).
T. J. Kang, M. A. Kahlow, D. Giser, S. Swallen, V. Nagarajan, W. Jarzęba and P. F. Barbara, J. Phys. Chem. 92, 6800 (1989).
D. W. Anthon and J. H. Clark, J. Phys. Chem. 91, 3530 (1987).
F. Schneider and E. Lippert, Ber. Bunsenges. Physik. Chem. 72, 1155 (1968);
F. Schneider and E. Lippert, Ber. Bunsenges. Physik. Chem. 74, 624 (1970).
E. M. Kosower, K. Tanizawa, Chem. Phys. Lett. 16, 419 (1972).
N. Nakashima, M. Murakawa, and N. Mataga, Bull. Chem. Soc. Japan, 49, 854 (1976).
W. Rettig and M. Zander, Ber. Bunsenges. Phys. Chem. 87, 1143 (1983);
M. Zander and W. Rettig, Chem. Phys. Lett. 110, 610 (1984);
N. Mataga, H. Yao, T. Okada, and W. Rettig, J. Phys. Chem. 93, 3383 (1989).
W. Baumann, E. Spohr, A. Bischhof, W. Liptay, J. Luminescence, 37, 227 (1987)
R. J. Visser, P. C. M. Weisenborn, P. J. M. van Kan, B. H. Hvizer, C. A. G. O. Varma, J. M. Warman, and M. P. de Haas, J. Chem. Soc. Faraday Trans. 2, 81, (1985).
R. J. Visser, P. C. M. Weisenborn, P. J. M. van Kan, B. H. Hvizer, C. A. G. O. Varma, J. M. Warman, and M. P. de Haas, J. Chem. Soc. Faraday Trans. 2, 689 (1985).
D. B. Toublanc, and R. W. Fessenden and A. Hitachi, J. Phys. Chem. 93, 2893, 1989.
K. Yamasaki, K. Arita, O. Kasimoto, and K. Hara, Chem. Phys. Lett. 123, 277 (1986).
R. L. Khundkar, A. H. Zewail, J. Chem. Phys. 86, 1302 (1986).
T. J. Kang, W. Jarzeba, T. Fonseca, P. F. Barbara, to be submitted.
Z. R. Grabowski, K. Rotkiewicz, A. Siemiarczuk, D. J. Cowley, and W. Baumann, Nouv. J. Chimie 3, 443 (1979).
T. Fonseca, J. Chem. Phys. in press.
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Barbara, P.F., Kang, T.J., Jarzeba, W., Fonseca, T. (1990). Solvation Dynamics and Ultrafast Electron Transfer. In: Jortner, J., Pullman, B. (eds) Perspectives in Photosynthesis. The Jerusalem Symposia on Quantum Chemistry and Biochemistry, vol 22. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0489-7_21
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DOI: https://doi.org/10.1007/978-94-009-0489-7_21
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