Abstract
Adsorption of ions in colloidal suspensions plays an important role in science, technology, and every day life. In the cooling water system of a nuclear power plant, depending on the physico-chemical conditions, radioactive cobalt is either dissolved or sorbed on colloidal magnetite and hematite corrosion products particles [1]. The extent of the contamination of surface waters due to a uranium mine and mill greatly depends on the content of natural colloids in these waters to which uranium, radium, and other members in the decay chain are attached [2]. Release of chromium from leather industry is subject of similar phenomena [3]. There is no need to mention that the transport of other pollutants and their uptake by living organisms is governed by sorption equilibria at suspended particles of naturally occurring colloids, mainly being hydrated oxides [4].
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References
Honda, T., Izumiya, M., and Minato A. (1984) Radiation buildup on stainless steel in a boiling water reactor environment, Nucl. Technol, 64, 35–42.
Beneš, P., Borovec, Z., and Strejc P. (1985) Interaction of radium with freshwater sediments and their mineral compounds, J. Radioanal. Nucl. Chem., 89, 339–351.
Musić, S., Ristić, M., and Tonković M. (1986) Sorption of chromium(VI) on hydrous iron particles, Z. Wasser-Abwasser-Forsch., 19, 186–196.
Lieser, K.H., Ament, A., Hill, R., Singh, R.N., Stigl, U., and Thybusch, B. (1990) Colloids in groundwater and their influence on migration of trace elements and radionuclides, Radiochim. Acta, 49, 83–100.
Dzombak, D.A., and Morel, F.M.M. (1989) Surface Complexation Modeling, A Wiley-Interscience Publication, John Wiley & Sons, New York, USA.
Kallay, N. and Žalac, S. (1994) Enthalpy of interfacial charging of metal oxide/water systems, Croat. Chim. Acta 67, 467–479.
Kobal, I., Hesleitner, P., and Matijević, E. (1988) Adsorption at solid/liquid interfaces. 6. Interactions of Co2+ ions with spherical hematite particles, Colloids Surfaces, 33, 167–174.
Hesleitner, P., Babić, D., Kallay, N., and Matijević E. (1987) Adsorption at solid/solution interfaces. 3. Surface charge and potential of colloidal hematite, Langmuir, 3, 815.
Morel, F.M.M., Yeasted, J.V., and Westall, J.C. (1981) Adsorption models: a mathematical analysis in the framework of general equilibrium calculation in Adsorption of Inorganics at Solid-Liquid Interfaces (M.A. Anderson and A.J.Rubin, Eds.), Ann Arbor Science, Michigan, USA, pp. 263.
Tewari, P.H., Campbell, A.B., and Lee, W. (1972) Adsorption of Co2+ by oxides from aqueous solutions, Can. J. Chem., 50, 1642–1648.
Hayes, K.F., and Leckie, J.O. (1987) Modeling ionic strength effects on cation adsorption at hydrous oxide/solution interface, J. Colloid Interface Sci. 115, 564–572.
Blesa., M.A., and Kallay, N. (1988) The metal oxide–electrolyte solution interface revisited, Adv. Colloid Interface Sci., 28, 111–134.
Westall, J.C., and Morel, F.M.M. (1977) FITEQL: A general algorithm for the determination of metal-ligand complex stability constants from experimental data, Technical Note 19, Ralph M. Parsons Laboratory, Department of Civil Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA.
Westall, J.C., Zachary, J.L., and Morel, F.M.M. (1976) MINEQL: A computer program for the calculation of chemical equilibrium composition of aqueous systems, Technical Note 18, Ralph M. Parsons Laboratory, Department of Civil Engineering, Massachusetts Institute of Technology, Cambridge, Massachusetts, USA.
Westall, J.C. (1982) FITEQL: A program for the determination of chemical equilibrium constants from experimental data, Technical Report, Chemistry Department, Oregon State University, Corvallis, Oregon, USA.
Trkov, A., Ogrinc, N., and Kobal, I. (1992) Modeling surface complexation at the colloid/electrolyte interface, Computers Chem., 16, 341–344.
Schindler, P.W. (1981) Surface complexes at the oxide/water interfaces in Adsorption of Inorganics at Solid-Liquid Interfaces (M.A. Anderson and A.J.Rubin, Eds.), Ann Arbor Science, Michigan, USA, pp.l.
Davis, J.A., and Leckie, J.O. (1978) Surface ionization and complexation at the oxide/water interface. II. Surface properties of amorphous iron oxyhydroxide and adsorption of metal ions, J.Colloid Interface Sci., 67, 90–107.
Yates, D.E., Levine, S., and Healy T.W. (1974) Site-binding model of the electrical double layer at the oxide/water interface J.Chem.Soc. Faradayl, 70, 1807.
Davis, J.A., James, R.O., and Leckie, J.O. (1978) Surface ionization and complexation at the oxide/water interface. I. Computation of electrical double layer properties in simple electrolytes J.Colloid Interface Sci., 63, 480–499.
Sprycha, R., Kosmulski, M., and Szczypa, J. (1989) Ionic components of charge on oxides, J. Colloid Interface Sci., 128, 88–95.
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© 1996 Kluwer Academic Publishers
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Ogrinc, N., Kobal, I., Matijević, E., Kallay, N. (1996). Adsorption of Cations on Colloidal Oxide Particles. Cobalt Ions on Hematite. In: Pelizzetti, E. (eds) Fine Particles Science and Technology. NATO ASI Series, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0259-6_7
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DOI: https://doi.org/10.1007/978-94-009-0259-6_7
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