Abstract
Approximate methods for describing the electrostatic interactions of microparticles with surfaces in liquid phases were compared with exact solutions obtained in bispherical coordinate system. Based on this discussion the equivalent hard particle concept was proposed for characterizing these interactions and adsorption kinetics of spherical and anisotropic particles. Also the more general methods based on the random sequential adsorption (RSA) and sequential brownian dynamics (SBD) were briefly outlined. The theoretical predictions were compared with experimental results obtained for model colloid suspensions (polystyrene latex) using the direct microscope observation technique. The significance of various factors influencing irreversible adsorption kinetics, e.g., particle size, ionic strength, and flow rate was demonstrated. A good agreement between the theoretical models and experimental measurements was confirmed. The structure of the adsorbed layers was also analyzed in terms of experimentally measured pair correlation function g12. It was found that the structure is controlled not only by the surface coverage but also by the transport mechanism of particles to the interface. For a random (diffusion) transport mechanism the 2D analogs of the gas and liquid phases were observed. Under the external force (sedimentation) dominated transport regime the shortrange ordering was found more pronounced. A true 2D crystallization can only be provoked, however, under the action of capillary forces upon drying the adsorbed layer.
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© 1996 Kluwer Academic Publishers
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Adamczyk, Z., Siwek, B., Szyk, L., Warszyński, P. (1996). Interactions of Microparticles with Interfaces: Kinetics and Structure. In: Pelizzetti, E. (eds) Fine Particles Science and Technology. NATO ASI Series, vol 12. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0259-6_2
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DOI: https://doi.org/10.1007/978-94-009-0259-6_2
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