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Gas-phase organometallic ion photochemistry

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Organometallic Ion Chemistry

Part of the book series: Understanding Chemical Reactivity ((UCRE,volume 15))

Abstract

The combination of Fourier transform ion cyclotron resonance mass spectrometry (FTICRMS) [1–7] with various light sources has proven to be a powerful means of studying the photochemistry of a wide variety of metalcontaining ions. In our laboratory, pulsed laser ionization [8, 9] is used to generate metal ions which are then stored in the ion trap of the FTICRMS where they are permitted to react with background gases [10, 11]. Isolation of the desired ion is readily achieved, followed by light irradiation for variable periods on the order of 1 to 20 s. Light absorption is measured indirectly by monitoring some change in ion intensity. Photodissociation is the most commonly observed process, whereby an ion dissociates following light absorption [12-14]. An alternative process in which the reactivity of an ion is altered following light absorption offers a potentially powerful method for obtaining information at longer wavelengths, at and below the ion dissociation energy [15, 16]. Similarly, multiphoton visible [17, 18] and infrared [19–22] absorption processes take advantage of the long trapping times and relatively slow radiative relaxation rates to effect some change in ion intensity. With these methods, one overcomes the burden of obtaining absorption information from species at 10-17 M. In this chapter we focus on some recent results from our laboratory on simple singly and doubly charged metal-ligand ions in the UV-VIS and in the infrared.

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Authors and Affiliations

  1. H.C. Brown Laboratory of Chemistry, Purdue University, West Lafayette, 47907, USA

    Y. A. Ranasinghe, I. B. Surjasasmita & Ben S. Freiser

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  1. Y. A. Ranasinghe
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  2. I. B. Surjasasmita
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  3. Ben S. Freiser
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Editors and Affiliations

  1. H.C. Brown Laboratory of Chemistry, Purdue University, West Lafayette, Indiana, USA

    Ben S. Freiser

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© 1996 Kluwer Academic Publishers

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Ranasinghe, Y.A., Surjasasmita, I.B., Freiser, B.S. (1996). Gas-phase organometallic ion photochemistry. In: Freiser, B.S. (eds) Organometallic Ion Chemistry. Understanding Chemical Reactivity, vol 15. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0111-7_7

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  • DOI: https://doi.org/10.1007/978-94-009-0111-7_7

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