Abstract
Radicals occur widely in chemistry, playing a vital role in many important liquid, solid-state and gas-phase reactions [1]. A radical is a chemical species containing one or more unpaired electrons and may be either charged (radical cation or radical anion) or uncharged (free radical). A biradical, or diradical, is a species containing two separate free electrons. Because radicals are highly reactive they are generally difficult to isolate and detect, and when they can be isolated they are usually present in very low concentrations, making any direct experimental observation quite demanding.
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Traeger, J.C., Kompe, B.M. (1996). Thermochemical Data for Free Radicals from Studies of Ions. In: Martinho Simões, J.A., Greenberg, A., Liebman, J.F. (eds) Energetics of Organic Free Radicals. Structure Energetics and Reactivity in Chemistry Series (SEARCH series), vol 4. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0099-8_3
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