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Phase transfer catalysis of uncharged species

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Handbook of Phase Transfer Catalysis

Abstract

The principal mechanism of quaternary ammonium phase transfer catalysis (PTC) is based on extraction via a stoichiometric anion-exchange process [1,2]. However, a secondary mechanism has been observed in several systems where the extraction is the outcome of nonstoichiometric hydrogen-bonded complex formed between the substrate and the anion of the quaternary ammonium ion pair (equation 16.1).

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  1. Y. Sasson
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  2. R. Neumann
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  1. Casali Institute of Applied Chemistry, The Hebrew University of Jerusalem, Israel

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Sasson, Y., Neumann, R. (1997). Phase transfer catalysis of uncharged species. In: Sasson, Y., Neumann, R. (eds) Handbook of Phase Transfer Catalysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0023-3_16

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  • DOI: https://doi.org/10.1007/978-94-009-0023-3_16

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