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Organometallic reactions under phase transfer conditions

  • Chapter
Handbook of Phase Transfer Catalysis

Abstract

Homogeneous catalysis with metal complexes provides mild and selective routes to a variety of valuable chemicals from basic organic precursors. An important advantage of such routes over heterogeneous systems is that selectivity is achieved by changing the coordination sphere of the metal. However, the sensitivity of the catalyst or its precursor to air or moisture and problems associated with the separation of the organic products from the active catalyst often constitute a major economic barrier to commercial applications. One solution to the problem may be found in supported catalysts, which have long been known to combine the advantages of homogeneous and heterogeneous systems.

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Abbreviations

Aliquat 336:

methyltrioctylammonium chloride (technical grade)

bipy:

2,2′-bipyridine

Bz:

benzyl group

Bu:

butyl group

cod:

cyclooctadiene

CTAB:

cetyltrimethylammonium bromide

CPC:

cetylpyridinium chloride

C7h8 :

toluene

dba:

dibenzylideneacetone

dppm:

l,2-bis(diphenylphosphino)methane

diphos:

l,2-bis(diphenylphosphino)ethane

Hex:

hexyl group

OAc:

acetoxy group or acetate anion

o-phen:

1,10-phenanthroline

PEG:

poly(ethylene glycol)

py:

pyridine

TBAB:

tetrabutylammonium bromide

TDA-1:

tris(3,6-dioxaheptyl)amine

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  1. Casali Institute of Applied Chemistry, The Hebrew University of Jerusalem, Israel

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Amer, I. (1997). Organometallic reactions under phase transfer conditions. In: Sasson, Y., Neumann, R. (eds) Handbook of Phase Transfer Catalysis. Springer, Dordrecht. https://doi.org/10.1007/978-94-009-0023-3_10

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  • DOI: https://doi.org/10.1007/978-94-009-0023-3_10

  • Publisher Name: Springer, Dordrecht

  • Print ISBN: 978-0-7514-0258-2

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