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Heteropoly Compounds as Ammoxidation Catalysts

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Abstract

This chapter gives an overview of the work carried out in our group on the application of various forms of heteropoly acids (HPAs) for ammoxidation of methylpyrazine (MP). It starts with a general description of HPAs, ammonium salts of HPA, and the metal substituted HPAs (combinedly called as heteropoly compounds, HPCs). The various methods adopted for the synthesis of these compounds have been described. The HPCs have also been dispersed on different supports, and the methodology of their preparation is presented. Different characterization techniques have been used to determine their physicochemical properties. The reactivity of the catalysts is evaluated for the ammoxidation of 2-methylpyrazine (MP) to 2-cyanopyrazine (CP). The enhanced thermal stability and activity of the supported systems compared with those of the bulk ones are highlighted. Two new methods – one for the preparation of catalysts by in situ synthesis of the ammonium salt of heteropoly acid on supports and the other for the determination of dispersion of HPC on the support by FTIR technique – developed in our laboratory are introduced. Finally, correlations drawn between the activity and selectivity with the physicochemical properties of HPCs are presented.

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Acknowledgments

Thanks are due to Director, CSIR-Indian Institute of Chemical Technology, Hyderabad, for permitting to carry out the work. The authors are thankful to Dr. I Suryanarayana for his help in the interpretation of NMR results.

Author information

Authors and Affiliations

  1. Chemistry Department, Faculty of Science, King Abdulaziz University, 80203, Jeddah, 21533, Saudi Arabia

    K. Narasimha Rao

  2. Solid State and Structural Chemistry Unit, Indian Institute of Science, Bangalore, 560012, India

    Ch. Srilakshmi

  3. Senior Research Associate, Center for Applied Catalysis, Seton Hall University, South Orange, New Jersey, 07079, USA

    K. Mohan Reddy

  4. I & PC Division, Indian Institute of Chemical Technology, Hyderabad, 500607, India

    B. Hari Babu, N. Lingaiah & P. S. Sai Prasad

Authors
  1. K. Narasimha Rao
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  2. Ch. Srilakshmi
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  3. K. Mohan Reddy
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  4. B. Hari Babu
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  5. N. Lingaiah
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  6. P. S. Sai Prasad
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Corresponding author

Correspondence to P. S. Sai Prasad .

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Editors and Affiliations

  1. Department of Chemistry, Maharaja Sayajirao University of Baroda, Gujarat, India

    Anjali Patel

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Rao, K.N., Srilakshmi, C., Reddy, K.M., Babu, B.H., Lingaiah, N., Prasad, P.S.S. (2013). Heteropoly Compounds as Ammoxidation Catalysts. In: Patel, A. (eds) Environmentally Benign Catalysts. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6710-2_2

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