Abstract
Research and development of hydrogen and fuel cell technologies are motivated by the same drivers as for other new energy production/conversion/storage options, in particular the increase in greenhouse gas emissions and in sea and land mass temperatures, and peaking of oil production capacity and the technical difficulties and safety issues associated with extracting oil from offshore deep drilling below the seabed, which together lead towards a global requirement for use of lower fossil carbon energy sources. In this context, this chapter outlines actual and potential roles for hydrogen and fuel cell technologies. It provides a short historical perspective of fuel cells and describes fuel cell types and their applications, in particular automotive and stationary fuel cell uses. Directions in fuel cell materials research on electrocatalysts and their supports and electrolyte membranes are described in a final section.
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Abbreviations
- AFC:
-
Alkaline fuel cell
- CO:
-
Carbon monoxide
- CO2 :
-
Carbon dioxide
- DLR:
-
Deutsche Zentrum für Luft- und Raumfahrt (German Aerospace Centre)
- e-:
-
Symbol of electron
- EU:
-
European Union
- EUCAR:
-
European Council for Automotive R&D
- FCHV:
-
Fuel cell hydrogen vehicle
- FCV:
-
Fuel cell vehicle
- Fe/N/C:
-
Iron, nitrogen, carbon catalyst
- H+:
-
Proton (hydrogen nucleus)
- H2 :
-
Hydrogen molecule
- HOPG:
-
Highly oriented pyrolytic graphite
- Hyfleet CUTE:
-
This is a European project comparing the advantages and disadvantages of hydrogen internal combustion engine (ICE) buses with fuel cell buses. CUTE stands for Clean Urban Transport for Europe and the goal of the project is to test and demonstrate hydrogen buses in 10 different cities in Europe, Asia, and Australia to reduce CO2 emissions and move away from fossil fuels.
- IPCC:
-
Intergovernmental Panel on Climate Change
- IPHE:
-
International Partnership for Hydrogen and Fuel Cells in the Economy.
- kW:
-
Kilowatt (SI power unit)
- mb/d:
-
Million barrels per day
- MCFC:
-
Molten carbonate fuel cell
- MEA:
-
Membrane electrode assembly
- OPEC:
-
Organization of the Petroleum Exporting Countries
- PAFC:
-
Phosphoric acid fuel cell
- PCFC:
-
Proton ceramic fuel cell
- PEM:
-
Polymer electrolyte membrane
- PEMFC:
-
Proton exchange membrane fuel cells, also known as polymer electrolyte fuel cells (PEFC)
- PFSA:
-
Perfluorosulfonic acid
- Pt/M:
-
Alloy of platinium with a metal (M)
- Pt:
-
Symbol of platinum
- PURE:
-
Promoting Unst Renewable Energy (Unst is one of the North Isles of the Shetland Islands, Scotland)
- SI:
-
Système International d’unités (International System of units)
- SOFC:
-
Solid oxide fuel cell
- WHFS:
-
Worldwide hydrogen fueling stations
References
Arcella V, Ghielmi A, Tommasi G (2003) High performance perfluoropolymer films and membranes. Ann N Y Acad Sci 984:226–244
Aricò AS, Di Blasi A, Brunaccini G, Sergi F, Dispenza G, Andaloro L, Ferraro M, Antonucci V, Asher P, Buche S, Fongalland D, Hards GA, Sharman JDB, Bayer A, Heinz G, Zandonà N, Zuber R, Gebert M, Corasaniti M, Ghielmi A, Jones DJ (2010) High temperature operation of a solid polymer electrolyte fuel cell stack based on a new ionomer membrane. Fuel Cells 10:1013–1023
Bauer A, Song C, Ignaszak A, Hui R, Zhang J, Chevallier L, Jones D, Roziere J (2010) Improved stability of mesoporous carbon fuel cell catalyst support through incorporation of TiO2. Electrochimica Acta 55:8365–8370
Cavaliere S, Subianto S, Savych I, Jones DJ, Roziere J (2011) Electrospinning: designed architectures for energy conversion and storage devices. Energy Environ Sci 4:4761–4785
Cavaliere-Jaricot S, Etcheberry A, Herlem M, Noel V, Perez H (2007) Electrochemistry at capped platinum nanoparticle Langmuir Blodgett films: a study of the influence of platinum amount and of number of LB layers. Electrochimica Acta 52:2285–2293
Joint Research Centre – EUCAR – CONCAWE (2008) Well to wheels analysis of future automotive fuels and powertrains in the European context. Retrieved 26 Jan 2012, from http://ies.jrc.ec.europa.eu/uploads/media/V3.1%20TTW%20Report%2007102008.pdf
d’Arbigny JB, Taillades G, Marrony M, Jones DJ, Roziere J (2011) Hollow microspheres with a tungsten carbide kernel for PEMFC application. Chem Commun 47:7950–7952
Debe MK, Schmoeckel AK, Vernstrom GD, Atanasoski R (2006) High voltage stability of nanostructured thin film catalysts for PEM fuel cells. J Power Sources 161:1002–1011
DLR (2010) Antares H3: DLR and Lange aviation develop the next generation of fuel-cell powered aircraft. Retrieved 26 Jan 2012, from http://www.dlr.de/en/desktopdefault.aspx/tabid-6216/10226_read-26189/
Earth Systems Research Laboratory (2011) Trends in atmospheric CO2 at Mauna Loa, Hawaii, 2011. Retrieved 26 Jan 2012, from http://www.esrl.noaa.gov/gmd/ccgg/trends/mlo.html
Elezovic NR, Babic BM, Radmilovic VR, Vracar LM, Krstajic NV (2009) Synthesis and characterization of MoOx-Pt/C and TiOx-Pt/C nano-catalysts for oxygen reduction. Electrochimica Acta 54:2404–2409
Friedrich KA, Büchi FN (2008) Fuel cells using hydrogen. In: Züttel A, Borgschule A, Schlapbach L (eds) Hydrogen as a future energy carrier. WILEY-VCH, Weinheim, pp 335–364
Fuel Cells 2000 (2009) Worldwide hydrogen fueling stations. Retrieved 26 Jan 2012, from http://www.fuelcells.org/info/charts/h2fuelingstations.pdf
Gancs L, Kobayashi T, Debe MK, Atanasoski R, Wieckowsk A (2008) Crystallographic characteristics of nanostructured thin-film fuel cell electrocatalysts: a HRTEM study. Chem Mater 20:2444–2454
Gasteiger HA, Baker DR, Carter RN, Gu W, Liu Y, Wagner FT, Yu PT (2010) Electrocatalysis and catalyst degradation challenges in proton exchange membrane fuel cells. In: Stolten D (ed) Hydrogen and fuel cells. WILEY-VCH, Weinheim, pp 1–14
Global Hydrogen Bus Platform. On-site steam reforming. Retrieved 26 Jan 2012, from http://www.global-hydrogen-bus-platform.com/Technology/HydrogenProduction/reforming
Grohs JR, Li Y, Dillard DA, Case SW, Ellis MW, Lai Y-H, Gittleman CS (2010) Evaluating the time and temperature dependent biaxial strength of Gore-Select series 57 proton exchange membrane using a pressure loaded blister test. J Power Sources 195:527–531
Grove WR (1839) On voltaic series and the combination of gases by platinum. Lond Edinb Philos Mag J Sci Ser 3 14:127–130
Grove WR (1842) On a gaseous voltaic battery. Lond Edinb Philos Mag J Sci Ser 3 21:417–420
HyFleet – Clean Urban Transport for Europe. Consulted 26 Jan 2012, from http://www.global-hydrogen-bus-platform.com/Home
International Partnership for Hydrogen and Fuel Cells in the Economy (2009) http://www.iphe.net/resources/demonstration.html
IPCC (2007) IPCC fourth assessment report: climate change 2007 section 2.4: causes of climate change. Retrieved 26 Jan 2012, from http://www.ipcc.ch/publications_and_data/ar4/syr/en/mains2-4.html
IPCC (2009) IPCC expert meeting on detection and attribution related to anthropogenic climate change. Retrieved 26 Jan 2012, from http://www.ipcc.ch/pdf/supporting-material/expert-meeting-detection-anthropogenic-2009-09.pdf
Jaouen F, Proietti E, Lefevre M, Chenitz R, Dodelet J-P, Wu G, Chung HT, Johnston CM, Zelenay P (2011) Recent advances in non-precious metal catalysis for oxygen-reduction reaction in polymer electrolyte fuel cells. Energy Environ Sci 4:114–130
Jones DJ, Rozière J (2008) Advances in the development of inorganic/organic membranes for fuel cell applications. Adv Polym Sci 215:219–264
Joo SH, Choi SJ, Oh I, Kwak J, Liu Z, Terasaki O, Ryoo R (2001) Ordered nanoporous arrays of carbon supporting high dispersions of platinum nanoparticles. Nature (Lond) 412:169–172
Li QF, Jensen JO, Savinell RF, Bjerrum NJ (2009) High temperature proton exchange membranes based on polybenzimidazoles for fuel cells. Prog Polym Sci 34:449–477
Liu J, Suraweera N, Keffer DJ, Cui S, Paddison SJ (2010) On the relationship between polymer electrolyte structure and hydrated morphology of perfluorosulfonic acid membranes. J Phys Chem C 114:11279–11292
Neyerlin KC, Srivastava R, Yu C, Strasser P (1009) Electrochemical activity and stability of dealloyed Pt-Cu and Pt-Cu-Co electrocatalysts for the oxygen reduction reaction (ORR). J Power Sources 186:261–267
Park C-H, Lee C-H, Guiver MD, Lee Y-M (2011) Sulfonated hydrocarbon membranes for medium-temperature and low-humidity proton exchange membrane fuel cells. Prog Polym Sci 36:1443–1498
Peckham TJ, Yang Y, Holdcroft S (2010) Proton exchange membranes. In: Wilkinson DP, Zhang JJ, Hui R, Fergus J, Li X (eds) Proton exchange membrane fuel cells. CRC Press, Boca Raton
Proietti E, Jaouen F, Lefevre M, Larouche N, Tian J, Herranz J, Dodelet J-P (2011) Iron-based cathode catalyst with enhanced power density in polymer electrolyte membrane fuel cells. Nat Commun 2:1427/1–1427/9
Pure Energy Centre (2007) Promoting Unst Renewable Energy (PURE) project – from wind to green fuel. Retrieved 26 Jan 2012, from http://www.pureenergycentre.com/pureenergycentre/Pureprojectcasestudy.pdf
Rabat H, Brault P (2008) Plasma sputtering deposition of PEMFC porous carbon platinum electrodes. Fuel Cells 8:81–86
Rozière J, Jones DJ (2003) Non-fluorinated polymer materials for proton exchange membrane fuel cells. Annu Rev Mater Res 33:503–555
Saha MS, Banis MN, Zhang Y, Li R, Sun X, Cai M, Wagner FT (2009) Tungsten oxide nanowires grown on carbon paper as Pt electrocatalyst support for high performance proton exchange membrane fuel cells. J Power Sources 192:330–335
Schönbein CF (1839) On the voltaic polarization of certain solid and fluid substances. Lond Edinb Philos Mag J Sci Ser 3 14:43–45
Thompsett D (2010) Recent developments in electrocatalyst activity and stability for proton exchange membrane fuel cells. In: Wilkinson DP, Zhang JJ, Hui R, Fergus J, Li X (eds) Proton exchange membrane fuel cells. CRC Press, Boca Raton
Tsuji M, Kubokawa M, Yano R, Miyamae N, Tsuji T, Jun M-S, Hong S, Lim S, Yoon S-H, Mochida I (2007) Fast preparation of PtRu catalysts supported on carbon nanofibers by the microwave-polyol method and their application to fuel cells. Langmuir 23:387–390
Vielstich W, Lamm A, Gasteiger H (eds) (2003) Handbook of fuel cells. Wiley, Chichester
Vielstich W, Harumi Y, Gasteiger HA (eds) (2009) Handbook of fuel cells. Wiley, Chichester
Wang J, Swain GM (2003) Fabrication and evaluation of platinum/diamond composite electrodes for electrocatalysis. J Electrochem Soc 150:E24–E32
Wieser C (2004) Novel polymer electrolyte membranes for automotive applications – requirements and benefits. Fuel Cells 4:245–250
World Energy Outlook (2011) World energy outlook executive summary. Retrieved 26 Jan 2012, from http://www.worldenergyoutlook.org/docs/weo2011/executive_summary.pdf
Wu B, Hu D, Kuang Y, Yu Y, Zhang X, Chen J (2011) High dispersion of platinum-ruthenium nanoparticles on the 3,4,9,10-perylene tetracarboxylic acid-functionalized carbon nanotubes for methanol electro-oxidation. Chem Commun 47:5253–5255
Xie Z, Song C, Wilkinson DP, Zhang JJ (2010) Catalyst layers and fabrication. In: Wilkinson DP, Zhang JJ, Hui R, Fergus J, Li X (eds) Proton exchange membrane fuel cells. CRC Press, Boca Raton
Zhang YM, Li L, Tang JK, Bauer B, Zhang W, Gao HR, Taillades-Jacquin M, Jones DJ, Rozière J, Lebedeva N, Mallant RKAM (2009) Development of covalently cross-linked and composite perfluorosulfonic acid membranes. ECS Trans 25:1469–1472
Zhao J, Jarvis K, Ferreira P, Manthiram A (2011) Performance and stability of Pd-Pt-Ni nanoalloy electrocatalysts in proton exchange membrane fuel cells. J Power Sources 196:4515–4523
Zhou Y, Pasquarelli R, Holme T, Berry J, Ginley D, O’Hayre R (2009) Improving PEM fuel cell catalyst activity and durability using nitrogen-doped carbon supports: observations from model Pt/HOPG systems. J Mater Chem 19:7830–7838
Züttel A (2008) Chapter 1: Introduction. In: Züttel A, Borgschule A, Schlapbach L (eds) Hydrogen as a future energy carrier. WILEY-VCH, Weinheim, pp 1–6
Acknowledgments
The author thanks Surya Subianto for his assistance with the graphics of this chapter. The research leading to these results has received funding from the European Community’s Seventh Framework Programme (FP7/2010-2013) under the call ENERGY-2010-10.2-1: Future Emerging Technologies for Energy Applications (FET) under contract 256821 QuasiDry.
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Jones, D.J. (2013). Introduction to Hydrogen and Fuel Cell Technologies and Their Contribution to a Sustainable Energy Future. In: Saulnier, J., Varella, M. (eds) Global Change, Energy Issues and Regulation Policies. Integrated Science & Technology Program, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6661-7_8
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