Abstract
Bismuth nanowire arrays configured on devices where they are capped with a transparent indium tin oxide electrode generate electric power when exposed to light. The arrays feature poor optical reflectivity and, possibly, light trapping. We show experimental results that indicate that the arrays respond to illumination owing to the thermoelectric conversion of heat absorbed at the surface. The unique features of the energy pathway are manifested through a strong temporal and photon wavelength dependence of the photoresponse. Energy conversion in thermoelectrics with light trapping surfaces is a path to fast infrared light detection and across-the-spectrum solar energy harvesting.
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References
Borca-Tasciuc DA et al (2001) Thermal characterization of nanowire array in alpha-Al(2)O(3) matrix. MRS Proc 703:V2.7
Borca-Tasciuc DA et al (2004) Thermal properties of electrodeposited bismuth telluride nanowires embedded in amorphous alumina. Appl Phys Lett 85:6001
Fan RH (2012) Transparent metals for ultrabroadband electromagnetic waves. Adv Mat 24:1980
Foss Jr C, Tierney M, Martin MR (1992) Template-synthesis of infrared-transparent metal microcylinders: Comparison of optical properties with the predictions of effective medium theory. J Phys Chem 96:9001
Gabor NM (2011) Hot carrier assisted intrinsic photoresponse in graphene. Science 334:648
Garnett E, Yang P (2010) Nano Lett 10:1082
Hochbaum AI et al (2008) Enhanced thermoelectric performance of rough silicon nanowires. Nature 451:163
Huber TE et al (2011) Surface state band mobility and thermopower in semiconducting bismuth nanowires. Phys Rev B 83:235414
Huber TE et al (2012) Thermoelectric prospects of nanomaterials with spin-orbit surface bands. J Appl Phys 111:043709
Kelzenberg MD et al (2010) Enhanced absorption and carrier collection in Si wire arrays for photovoltaic applications. Nat Mater 9:239
Lawrance R, Bube R (1968) Photothermoelectric and thermally stimulated thermoelectric effects: Techniques in photoelectronic analysis. Appl Phys 39:1807
Nolas GS, Sharp J, Goldsmid HJ (2001) Thermoelectrics: basic principles and new materials developments. Springer, Heildelberg
Parker WJ et al (1961) Flash method of determining thermal diffusivity, heat capacity, and thermal conductivity. J Appl Phys 32:1679
St-Antoine BC, Menard D, Martel R (2011) Single-walled carbon nanotube thermopile for broadband light detection. Nano Lett 11:609
Sze SM (1981) Physics of semiconductor devices, 2nd edn. Wiley, London
Takahashi K et al (2012) Light-induced off-diagonal thermoelectric effect via indirect optical heating of incline-oriented Ca(x)CoO(2). Appl Phys Lett 100:18197
Tritt et al (2008) Thermoelectrics: Direct solar thermal energy conversion. Mater Res Soc Bull 33:366-369
Wu C-Y et al (2010) Free-electronlike diffusive thermopower on indium tin oxide thin films. JÂ Appl Phys 108:123708
Xu X et al (2010) Photo-thermoelectric effect at the graphene interface junction. Nano Lett 10:562
Yao Y et al (2008) Optical negative refraction in bulk metamaterials of nanowires. Science 321:930
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Huber, T., Scott, R., Johnson, S., Brower, T., Nikolaeva, A., Konopko, L. (2013). Thermoelectric Nanowire Arrays Response to Illumination. In: Egger, R., Matrasulov, D., Rakhimov, K. (eds) Low-Dimensional Functional Materials. NATO Science for Peace and Security Series B: Physics and Biophysics. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6618-1_17
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DOI: https://doi.org/10.1007/978-94-007-6618-1_17
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