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Dynamical Flexibility in the Periodic Zn6Sc 1/1-Approximant

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Aperiodic Crystals

Abstract

Using quasielastic neutron scattering (QENS) and molecular dynamics (MD) simulations, dynamical disorder was shown to be present in the Zn6Sc cubic 1/1-approximant to Tsai type quasicrystals. This dynamical disorder originates from reorientations of the innermost tetrahedron shell inside the Tsai type clusters’ building blocks. To enable such a rotational motion inside a close-packed alloy, a unique dynamical flexibility is necessary. We present a study of the tetrahedron dynamics with respect to this structural flexibility.

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References

  1. Euchner H, de Boissieu M, Schober H, Rols S, Ishimasa T, Tamura R, Yamada T, Mihalkovic M (2012) J Phys Condens Matter

    Google Scholar 

  2. Janssen T, Chapuis G, de Boissieu M (2007) Aperiodic crystals. From modulated phases to quasicrystals. Oxford University Press, Oxford

    Book  Google Scholar 

  3. Takakura H, Gomez CP, Yamamoto A, de Boissieu M, Tsai AP (2007) Nat Mater 6:58

    Article  CAS  Google Scholar 

  4. de Boissieu M, Francoual S, Mihalkovic M, Shibata K, Baron AQR, Sidis Y, Ishimasa T, Wu D, Lograsso T, Regnault LP, Gähler F, Tsutsui S, Hennion B, Bastie P, Sato TJ, Takakura H, Currat R, Tsai AP (2007) Nat Mater 6:977

    Article  Google Scholar 

  5. Gomez CP, Lidin S (2003) Phys Rev B 68:024203

    Article  Google Scholar 

  6. Lin QS, Corbett JD (2004) Inorg Chem 43:1912

    Article  CAS  Google Scholar 

  7. Tamura R, Murao Y, Takeuchi S, Ichihara M, Isobe M, Ueda Y (2002) Jpn J Appl Phys 41:L524

    Article  CAS  Google Scholar 

  8. Tamura R, Edagawa K, Aoki C, Takeuchi S, Suzuki K (2003) Phys Rev B 68:174105

    Article  Google Scholar 

  9. Tamura R, Nishimoto K, Takeuchi S, Edagawa K, Isobe M, Ueda Y (2005) Phys Rev B 71:092203

    Article  Google Scholar 

  10. Yamada T, Tamura R, Muro Y, Motoya K, Isobe M, Ueda Y (2010) Phys Rev B 82:134121

    Article  Google Scholar 

  11. Ishimasa T, Kasano Y, Tachibana A, Kashimoto S, Osaka K (2007) Philos Mag 87:2887

    Article  CAS  Google Scholar 

  12. Ishii Y, Fujiwara T (2001) Phys Rev Lett 87(20):206408

    Article  CAS  Google Scholar 

  13. Nozawa K, Ishii Y (2008) J Phys Condens Matter 20:315206

    Article  Google Scholar 

  14. Hatakeyama T, Nozawa K, Ishii Y (2008) Z Kristallogr 223:830

    Article  CAS  Google Scholar 

  15. Mihalkovic M, Henley CL (2011) Philos Mag 91:2548

    Article  CAS  Google Scholar 

  16. Yamada T, Euchner H, Tamura R, de Boissieu M (2012) In preparation

    Google Scholar 

  17. Bee M (1988) Quasielastic neutron scattering: principles and applications in solid state chemistry, biology and materials science. Hilger, Bristol

    Google Scholar 

  18. Stadler J, Mikulla K, Trebin HR (1997) Int J Mod Phys C 8:1131

    Article  Google Scholar 

  19. Euchner H, Mihalkovic M, Gahler F, Johnson MR, Schober H, Rols S, Suard E, Bosak A, Ohhashi S, Tsai AP, Lidin S, Gomez CP, Custers J, Paschen S, de Boissieu M (2011) Phys Rev B 83:144202

    Article  Google Scholar 

  20. Lyonnard S, Coddens G, Calveyrac D, Gratias D (1996) Phys Rev B 53:31050

    Article  Google Scholar 

  21. Edagawa K, Suzuki K, Takeuchi S (2000) Phys Rev Lett 85(8):1674

    Article  CAS  Google Scholar 

  22. Abe E, Pennycook SJ, Tsai AP (2003) Nature 421:347

    Article  CAS  Google Scholar 

  23. de Boissieu M, Currat R, Francoual S (2008) In: Fujiwara T, Ishii Y (eds) Handbook of metal physics: quasicrystals, vol 107. Elsevier Science, Amsterdam

    Google Scholar 

  24. de Boissieu M, Francoual S, Kaneko Y, Ishimasa T (2005) Phys Rev Lett 95:105503

    Article  Google Scholar 

Download references

Acknowledgement

This work is part of a common project within the European C-MAC network.

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Correspondence to Holger Euchner or Marc de Boissieu .

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Euchner, H. et al. (2013). Dynamical Flexibility in the Periodic Zn6Sc 1/1-Approximant. In: Schmid, S., Withers, R., Lifshitz, R. (eds) Aperiodic Crystals. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6431-6_34

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