Abstract
This chapter provides an explanation for the kinetic features of C60 molecule hydrogenation by analyzing the state and structure of double bonds in the frame of fullerene molecule. The status of these bonds, that changes the chemical activity of C60 molecules, and hence the ability of fullerene molecule to accept different number of reagents particles, has been proposed. The special features of fullerene molecule formation and mechanism of structural transformations of fullerene molecule in solutions and fullerite have been considered.
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References
Schur DV, Zaginaichnko S, Veziroglu TN (2008) Peculiarities of hydrogenation of pentatomic carbon molecules in the frame of fullerene molecule C60. Int J Hydrog Energy 33:3330–3345
Schur DV, Zaginaichenko SY, Savenko AF, Bogolepov VA, Anikina NS, Zolotarenko AD et al (2011) Experimental evaluation of total hydrogen capacity for fullerite C60. Int J Hydrog Energy 36:1143–1151
Schur DV, Zaginaichenko SY, Lysenko EA (2008) The forming peculiarities of C60 molecule. In: Carbon nanomaterials in clean energy hydrogen systems, NATO science series. Springer, Dordrecht, pp 53–65
Ruoff RS, Malhotra R, Huestis DL, Tse DS, Lorents DC (1993) Anomalous solubility behaviour of C60. Lett Nat 362:140–141
Ying Q, Marecek J, Chu B (1994) Slow aggregation of buckminsterfullerene (C60) in benzene solution. Chem Phys Lett 219:214–218
Suzuki E et al (1998) Molecular nanostructures. World Scientific, Singapore
Sivaraman N, Dhamodaran R, Kaliappan I, Srinivasan TG, Rao PRV (1992) Solubility of C60 in organic solvents. J Org Chem 57:6077–6079
Doome RJ, Fonseca A, Nagu JB (1999) 13C–MAS–NMR investigation of solutions saturated with fullerenes: study of the anomalous solubility behaviour. Colloids Surf A Physicochem Eng Asp 158(1–2):137–143
Beck MT, Mandi G (1996) Fuller Sci Technol 3:32
Bezmel’nitsyn VN, Eletskii AV, Okun’ MV (1998) Fullerenes in solutions. Uspekhi Fiz Nauk 168(11):1195–1220 (in Russian)
Ruof RS, Tse DS, Malhotra R, Lorents DC (1993) Solubility of fullerene (C60) in a variety of solvents. J Phys Chem 97:3379–3383
Scrivenns WA, Tour JM (1993) Potent solvents for C60 and their utility for the rapid acquisition of 13C NMR data for fullerenes. J Chem Soc Chem Commun, p.1207
Beck MT, Mandi G (1996) Fulle Sci Technol 5(2):291–310
Letcher TM et al (1993) Solubility buckminsterfullerene, C60, in Benzene and Toluene. S Afr J Chem 46:41
Bochvar DA, Gal’pern EG (1973) About hypothetical system: carbododecahedron, s-icosahedron and carbo-s-icosahedron. Dokl Akad Nauk SSSR 209(3):610–612 (in Russian)
Schur DV, Zaginaichenko SY, Zolotarenko AD, Veziroglu TN (2008) Solubility and transformation of fullerene C60 molecule. In: Carbon nanomaterials in clean energy hydrogen systems, NATO science series. Springer, Dordrecht, pp 85–95
Schur DV, Zaginaichenko SY, Matysina ZA (2008) The special features of formation of carbon nanostructures, their classification and site on the state diagram of carbon. In: Carbon nanomaterials in clean energy hydrogen systems, NATO science series. Springer, Dordrecht, pp 67–83
Schur DV, Zaginaichenko SYu, Lysenko EA, Golovchenko TN, Vlasenko AYu (2007) The peculiatities of molecule С60 formation. In: Proceedings of 10th international conference “hydrogen materials science and chemistry of carbon nanomaterials”, Sudak, Crimea, Ukraine, p 716–721
Schur DV, Zaginaichenko SY, Matysina ZA (2007) Effects of stimulation of hydrogen solubility in fullerite C60. Nanosyst Nanomater Nanotechnol 5(2):385–409
Schur DV, Matysina ZA, Zaginaichenko SY (2007) Carbon nanomaterials and phase transformations in them. Nauka i obrazovanie, Dnepropetrovsk, p 678
Zaginaichenko SY, Anikina NS, Zolotarenko AD, Krivushenko OJ, Shur DV (2007) Regularity of C60 fullerene dissolving in methyl derivatives of benzene. In: Proceedings of 10th international conference “hydrogen materials science and chemistry of carbon nanomaterials”, Sudak, Crimea, Ukraine, p 668–671
Anikina NS, Shur DV, Zaginaichenko SYu, Zolotarenko AD, Krivushenko OYa (2008) On the donor-acceptor mechanism of C60 fullerene dissolving in aromatic hydrocarbons. Ibid. pp 676–679
Anikina NS, Shur DV, Zaginaichenko SYu, Zolotarenko AD, Krivushenko OYa (2008) The role of chemical and physical properties of C60 fullerene molecules and benzene derivatives in processes of C60 dissolving. Ibid. pp 680–683
Matysina ZA, Schur DV, Zaginaichenko SY (2009) The solid-phase transformations in fullerite stimulated by rearrangement of the structure of fullerene molecules. Met Phys Adv Technol 31(2):147–163
Acknowledgment
This work has been done within the framework of SCOPES project «Implementation in East Europe of new methods of synthesis and functionalization of carbon nanotubes for applications in the energy storage and sensors field»
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Schur, D.V., Zaginaichenko, S.Y., Veziroğlu, T.N., Javadov, N.F. (2013). The Peculiarities of Hydrogenation of Fullerene Molecules C60 and Their Transformation. In: Veziroğlu, A., Tsitskishvili, M. (eds) Black Sea Energy Resource Development and Hydrogen Energy Problems. NATO Science for Peace and Security Series C: Environmental Security. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-6152-0_17
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DOI: https://doi.org/10.1007/978-94-007-6152-0_17
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