Skip to main content

Learning and Teaching the Basic Quantum Chemical Concepts

  • Chapter
  • First Online:
Book cover Concepts of Matter in Science Education

Part of the book series: Innovations in Science Education and Technology ((ISET,volume 19))

Abstract

In this chapter, after a review of the relevant literature on learning the basic quantum chemical concepts, I analyze and synthesize the findings of a number of my research group’s studies on the relevant misconceptions and learning difficulties occurring with students at the university and the high school level. University chemistry students who had passed the quantum chemistry course (at the physical chemistry level) demonstrated many failures. For many students both at the high school and the university level, the orbitals represent a definite, well-bounded space; also, they do not realize the approximate nature of atomic orbitals for many-electron atoms. The planetary Bohr model is strongly favored, while the probabilistic nature of the orbital concept is absent. Other students hold a hybrid model. A notable difference has been identified in performance on questions that tested recall of knowledge or application of algorithmic procedures with that on questions that required conceptual understanding and/or critical thinking. Four levels of students’ explanations as well as three levels of models have been reported based on Ausubel’s theory of meaningful learning. These were combined into four categories, of which two of the categories are in the rote-learning part of a continuum, while the other two categories are in the meaningful-learning part. Finally, we tested for deep understanding and critical thinking about the basic concepts taught at twelfth grade with the aim to achieve conceptual change in students. The method proved effective in a number of cases and ineffective in others. The chapter is concluded with implications and recommendations for learning and teaching.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    A feature of most introductions to quantum chemistry is their postulative approach. Although the Schrödinger equation cannot be proved or derived strictly, there are many ways to introduce this equation that provide insights into the meaning of quantum mechanics. I have suggested an approach from the historical perspective, in which I first study the methods of the pioneers Schrödinger, Heisenberg, and Dirac. Following that, I made a synthesis of various modern heuristic treatments into a coherent and meaningful whole (Tsaparlis 2001).

References

  • Ausubel, D. P. (1968). Educational psychology – A cognitive view. New York: Holt, Reinhart & Winston.

    Google Scholar 

  • Ausubel, D. P. (2000). The acquisition and retention of knowledge: A cognitive view. Dordrecht: Kluwer.

    Book  Google Scholar 

  • Ausubel, D. P., Novak, J. D., & Hanesian, H. (1978). Educational psychology – A cognitive view. New York: Holt, Reinhart & Winston.

    Google Scholar 

  • Bodner, G. M. (1991). I have found you an argument – The conceptual knowledge of beginning chemistry graduate students. Journal of Chemical Education, 68, 385–388.

    Article  Google Scholar 

  • Borkoff, G., & von Newmann, J. (1936). The logic of quantum mechanics. Annals of Mathematics, 37, 835–843.

    Google Scholar 

  • Castro, E. A., & Fernandez, F. M. (1987). Intellectual development beyond formal operations. International Journal of Science Education, 9, 441–447.

    Article  Google Scholar 

  • Coll, R. K., & Taylor, N. (2002). Mental models in chemistry: Senior chemistry students mental models of chemical bonding. Chemistry Education Research and Practice, 3, 175–184.

    Article  Google Scholar 

  • Coll, R. K., & Treagust, D. F. (2001). Learners’ mental models of chemical bonding. Research in Science Education, 31, 357–382.

    Article  Google Scholar 

  • Coll, R. K., & Treagust, D. F. (2002). Exploring tertiary students’ understanding of covalent bonding. Research in Science and Technological Education, 20, 241–267.

    Article  Google Scholar 

  • Coulson, C. A. (1974). Mathematics in modern chemistry. Chemistry in Britain, 10, 16–18.

    Google Scholar 

  • Dirac, P. (1929). Quantum mechanics of many-electron systems. Proceedings of the Royal Society of London, A123, 714–733.

    Google Scholar 

  • DiSessa, A. (1988). Knowledge in pieces. In G. Formn & P. B. Pufall (Eds.), Constructivism in the computer age (pp. 49–70). Hillsdale: Erlbaum.

    Google Scholar 

  • Driver, R. (1983). The pupil as scientist? Milton Keynes: Open University Press.

    Google Scholar 

  • Driver, R., Leach, J., Millar, R., & Scott, P. (1996). Young people’s image of science. Buckingham: Oxford University Press.

    Google Scholar 

  • Driver, R., Newton, P., & Osborne, J. (2000). Establishing the norms of scientific argumentation in classrooms. Science Education, 84, 287–312.

    Article  Google Scholar 

  • Duncan-Hewitt, W., Mount, D. L., & Apple, D. A. (1995). A handbook on cooperative learning (2nd ed.). Corvallis: Pacific Crest.

    Google Scholar 

  • Eylon, B.-S., & Linn, M. C. (1988). Learning and instruction: An examination of four research perspectives in science education. Review of Educational Research, 58, 251–301.

    Article  Google Scholar 

  • Fishler, H., & Lichtfeldt, M. (1992). Modern physics and students’ conceptions. International Journal of Science Education, 14, 181–190.

    Article  Google Scholar 

  • Fong, P. (1962). Elementary quantum mechanics. Reading: Addison-Wesley.

    Google Scholar 

  • Franco, C., Lins de Barros, H., Colinvaux, D., Krapas, S., Queiroz, G., & Alves, F. (1999). From scientists’ and inventors’ minds to some scientific and technological products: Relationship between theories, models, mental models, and conceptions. International Journal of Science Education, 21, 277–291.

    Article  Google Scholar 

  • Gardner, D. E., & Bodner, G. M. (2008). Existence of a problem-solving mindset among students taking quantum mechanics and its implications. In M. D. Ellison & T. A. Schoolcraft (Eds.), Advances in teaching physical chemistry (pp. 155–173). Washington, DC: American Chemical Society/Oxford University Press.

    Google Scholar 

  • Gavroglu, K., & Simões, A. (2012). Neither physics nor chemistry: A history of quantum chemistry. Cambridge, MA: Massachusetts Institute of Technology Press.

    Google Scholar 

  • Gillespie, R. J., & Matta, C. F. (2001). Teaching the VSEPR model and electron densities. Chemistry Education Research and Practice, 2, 73–90.

    Article  Google Scholar 

  • Gold, M. (1988). Chemical education: An obsession with content. Journal of Chemical Education, 65, 780–781.

    Article  Google Scholar 

  • Gomatam, R. (2004). Physics and commonsense – Reassessing the connection in the light of the quantum theory. http://arxiv.org/ftp/arxiv/papers/0708/0708.1536.pdf. Accessed 20 April 2013.

  • Greca, I. M., & Freire, O., Jr. (2003). Does an emphasis on the concept of quantum states enhance students’ understanding of quantum mechanics? Science Education, 12, 541–557.

    Article  Google Scholar 

  • Halloun, I. A. (2007). Mediated modeling in science education. Science Education, 16, 653–697.

    Article  Google Scholar 

  • Harrison, A. G., & Treagust, D. F. (2000). Learning about atoms, molecules, and chemical bonds: A case study of multiple-model use in grade 11 chemistry. Science Education, 84, 352–381.

    Article  Google Scholar 

  • Hewson, W. H., & Hewson, M. G. A. (1984). The role of conceptual conflict in conceptual change and the design of science instruction. Instructional Science, 13, 1–13.

    Article  Google Scholar 

  • Ireson, G. (2001). On the quantum thinking of physics undergraduates. In H. Behrendt, H. Dahncke, R. Duit, W. Graber, M. Komorek, A. Kross, & P. Reiska (Eds.), Research in science education – Past, present, and future (pp. 83–88). Dordrecht: Kluwer.

    Google Scholar 

  • Johnson, D. W., Johnson, R. T., & Smith, K. A. (1991). Active learning cooperation in the learning classroom. Edina: Interaction Book Co.

    Google Scholar 

  • Johnstone, A. H., Morrison, T. I., & Reid, N. (1981). Chemistry about us. London: Heinemann Educational Books.

    Google Scholar 

  • Kalkanis, G., Hadzidaki, P., & Stavrou, D. (2003). An instructional model for a radical conceptual change towards quantum mechanics concepts. Science Education, 87, 257–280.

    Article  Google Scholar 

  • Kemble, E. C. (1937). The fundamental principles of quantum mechanics (pp. 243–244). New York: McGraw-Hill [reprinted by Dover].

    Google Scholar 

  • Kontogeorgiou, A., Bellou, J., & Mikropoulos, T. A. (2007). Visualizing the quantum atom. In R. Pintó & C. Digna (Eds.), Contributions from science education research (pp. 465–475). Dordrechet: Springer.

    Chapter  Google Scholar 

  • Kuhn, T. (1970). The structure of scientific revolutions (2nd ed.). Chicago: University of Chicago Press.

    Google Scholar 

  • Lewis, G. N. (1923). Valence and the structure of atoms and molecules. New York: The Chemical Catalog Company.

    Google Scholar 

  • Marton, F. (1981). Phenomenography – Describing conceptions of the world around us. Instructional Science, 10, 177–200.

    Article  Google Scholar 

  • Matthews, M. R. (2007). Models in science and in science education. Science Education, 16, 647–652.

    Article  Google Scholar 

  • McKelvey, D. R. (1983). Relativistic effects on chemical properties. Journal of Chemical Education, 60, 112–116.

    Article  Google Scholar 

  • Mortimer, E. F., & Scott, P. (2003). Meaning making in secondary science classroom. Maidenhead: Open University Press.

    Google Scholar 

  • Nakhleh, Μ. Β. (1993). Are our students conceptual thinkers or algorithmic problem solvers? Journal of Chemical Education, 70, 52–55.

    Article  Google Scholar 

  • Nakiboğlu, C. (2003). Instructional misconceptions of Turkish prospective chemistry teachers about atomic orbitals and hybridization. Chemistry Education Research and Practice, 4, 171–188.

    Article  Google Scholar 

  • Nakiboğlu, C. (2008). Using word associations for assessing non major science students’ knowledge structure before and after general chemistry instruction: The case of atomic structure. Chemistry Education Research and Practice, 9, 309–322.

    Article  Google Scholar 

  • Nersessian, N. (1992). How do scientists think? Capturing the dynamics of conceptual change in science. In R. N. Giere (Ed.), Minnesota studies in the philosophy of science (pp. 3–45). Minneapolis: University of Minnesota Press.

    Google Scholar 

  • Niaz, M., & Femández, R. (2008). Understanding quantum numbers in general chemistry textbooks. International Journal of Science Education, 30, 869–901.

    Article  Google Scholar 

  • Nicoll, G. (2001). A report of undergraduates’ bonding misconceptions. International Journal of Science Education, 23, 707–730.

    Article  Google Scholar 

  • Nicoll, G., Francisco, J., & Nakhleh, M. (2001). A three-tier system for assessing concept map links: A methodological study. International Journal of Science Education, 8, 863–875.

    Article  Google Scholar 

  • Novak, J. D. (2002). Meaningful learning: The essential factor for conceptual change in limited or inappropriate propositional hierarchies leading to empowerment of learners. Science Education, 86, 548–571.

    Article  Google Scholar 

  • Ogborn, J., Kress, G., Martins, I., & McGillycuddy, K. (1996). Explaining science in the classroom. Milton Keynes: Open University Press.

    Google Scholar 

  • Olsen, R. V. (2001). A study of Norwegian upper secondary physics specialists’ understanding of quantum physics. Paper presented at the 3rd ESERA Conference, Thessaloniki, Greece.

    Google Scholar 

  • Papaphotis, G., & Tsaparlis, G. (2008a). Conceptual versus algorithmic learning in high school chemistry: The case of basic quantum chemical concepts, part 1. Statistical analysis of a quantitative study. Chemistry Education Research and Practice, 8, 323–331.

    Article  Google Scholar 

  • Papaphotis, G., & Tsaparlis, G. (2008b). Conceptual versus algorithmic learning in high school chemistry: The case of basic quantum chemical concepts, part 2. Students’ common errors, misconceptions, and difficulties in understanding. Chemistry Education Research and Practice, 8, 332–340.

    Article  Google Scholar 

  • Park, E. J., & Light, G. (2009). Identifying atomic structure as a threshold concept: Student mental models and troublesomeness. International Journal of Science Education, 31, 233–258.

    Article  Google Scholar 

  • Pauling, L. (1938). The nature of the chemical bond (1st ed.). Ithaca: Cornell University Press.

    Google Scholar 

  • Pauling, L., & Wilson, E. B., Jr. (1935). Introduction to quantum mechanics with applications to chemistry. New York: McGraw-Hill.

    Google Scholar 

  • Petri, J., & Niedderer, H. (1998). A learning pathway in high-school level quantum atomic physics. International Journal of Science Education, 20, 1075–1088.

    Article  Google Scholar 

  • Pople, J. A. (1999). Nobel lecture: Quantum chemical models. Reviews of Modern Physics, 71, 1267–1274.

    Article  Google Scholar 

  • Sánchez Gómez, P. J., & Martín, F. (2003). Quantum versus ‘classical’ chemistry in university chemistry education: A case study of the role of history in thinking the curriculum. Chemistry Education Research and Practice, 4, 131–148.

    Article  Google Scholar 

  • Scerri, E. (2001). The new philosophy of chemistry and its relevance to chemical education. Chemistry Education Research and Practice, 2, 165–170.

    Article  Google Scholar 

  • Scott, P. H., Mortimer, E. F., & Aguiar, O. G. (2006). The tension between authoritative and dialogic discourse: A fundamental characteristic of meaning making interactions in high school science lessons. Science Education, 90, 605–631.

    Article  Google Scholar 

  • Shiland, T. W. (1997). Quantum mechanics and conceptual change in high school chemistry texts. Journal of Research in Science Teaching, 34, 535–545.

    Article  Google Scholar 

  • Simons, J. (1991). There are no such things as orbitals – Act two. Journal of Chemical Education, 68, 131–132.

    Article  Google Scholar 

  • Stamovlasis, D., Tsaparlis, G., Kamilatos, C., Papaoikonomou, D., & Zarotiadou, E. (2004). Conceptual understanding versus algorithmic problem solving: A principal component analysis of a national examination. The Chemical Educator, 9, 398–405.

    Google Scholar 

  • Stamovlasis, D., Tsaparlis, G., Kamilatos, C., Papaoikonomou, D., & Zarotiadou, E. (2005). Conceptual understanding versus algorithmic problem solving: Further evidence from a national chemistry examination. Chemistry Education Research and Practice, 6, 104–118.

    Article  Google Scholar 

  • Stamovlasis, D., Dimos, A., & Tsaparlis, G. (2006). A study of group interaction processes on learning lower secondary physics. Journal of Research in Science Teaching, 43, 556–576.

    Article  Google Scholar 

  • Stefani, C., & Tsaparlis, G. (2009). Students’ levels of explanations, models, and misconceptions in basic quantum chemistry: A phenomenographic study. Journal of Research in Science Teaching, 46, 520–536.

    Article  Google Scholar 

  • Stofflett, R. T., & Stoddart, T. (1994). The ability to understand and use conceptual change pedagogy as a function of prior content learning experiences. Journal of Research in Science Teaching, 31, 31–51.

    Article  Google Scholar 

  • Taber, K. S. (2001). Building the structural concepts of chemistry: Some considerations from educational research. Chemistry Education Research and Practice, 2, 123–158.

    Article  Google Scholar 

  • Taber, K. S. (2002a). Conceptualizing quanta – Illuminating the ground state of student understanding of atomic orbitals. Chemistry Education Research and Practice, 3, 145–158.

    Article  Google Scholar 

  • Taber, K. S. (2002b). Compounding quanta – Probing the frontiers of student understanding of molecular orbitals. Chemistry Education Research and Practice, 3, 159–173.

    Article  Google Scholar 

  • Taber, K. S. (2005). Learning quanta: Barriers to stimulating transitions in student understanding of orbital ideas. Science Education, 89, 94–116.

    Article  Google Scholar 

  • Taber, K. S., & Watts, M. (2000). Learners’ explanations for chemical phenomena. Chemistry Education Research and Practice, 1, 329–353.

    Article  Google Scholar 

  • Tsaparlis, G. (1993). Orbitales atomiques et conceptions pertinentes: Idées fausses des étudiants de chimie. In Actes/Proceedings 1st ECRICE: Le Bulletin du CIFEC, Numero: Hors Serie (Vol. 2, pp. 212–216). Montpellier, France: Centre International Francophone pour l’ Education en Chimie.

    Google Scholar 

  • Tsaparlis, G. (1997). Atomic orbitals, molecular orbitals and related concepts: Misconceptions and difficulties in understanding among chemistry students. Research in Science Education, 27, 271–287.

    Article  Google Scholar 

  • Tsaparlis, G. (2001). Towards a meaningful introduction to the Schrödinger equation through historical and heuristic approaches. Chemistry Education Research and Practice, 2, 203–213.

    Article  Google Scholar 

  • Tsaparlis, G. (2008). Teaching and learning physical chemistry – Review of educational research. In M. D. Ellison & T. A. Schoolcraft (Eds.), Advances in teaching physical chemistry (pp. 75–112). Washington, DC: American Chemical Society/Oxford University Press.

    Google Scholar 

  • Tsaparlis, G., & Papaphotis, G. (2002). Quantum-chemical concepts: Are they suitable for secondary students? Chemistry Education Research and Practice, 3, 129–144.

    Article  Google Scholar 

  • Tsaparlis, G., & Papaphotis, G. (2009). High-school students’ conceptual difficulties and attempts at conceptual change: The case of basic quantum chemical concepts. International Journal of Science Education, 31, 895–930.

    Article  Google Scholar 

  • Van Driel, J. H., & Verlop, N. (1999). Teachers’ knowledge of models. International Journal of Science Education, 21, 1141–1153.

    Article  Google Scholar 

  • Vosniadou, S., Ioannidis, C., Dimitrakopoulou, A., & Papademetriou, E. (2001). Designing learning environments to promote conceptual change in science. Learning and Instruction, 11, 381–419.

    Article  Google Scholar 

  • Vygotsky, L. (1962). Thought and language. Cambridge, MA: MIT Press.

    Book  Google Scholar 

  • Wikipedia. Naïve realism. http://en.wikipedia.org/wiki/Na%C3%AFve_realism. Accessed 20 April 2013.

  • Ziellinski, T. J. (2005). Introducing JCE LivTexts: Physical chemistry. Journal of Chemical Education, 82, 1880.

    Google Scholar 

  • Zoller, U. (1990). Students’ misunderstandings and misconceptions in college freshman chemistry (general and organic). Journal of Research in Science Teaching, 27, 1053–1065.

    Article  Google Scholar 

  • Zoller, U. (1993). Lecture and learning: Are they compatible? Maybe for LOCS; unlikely for HOCS. Journal of Chemical Education, 70, 195–197.

    Article  Google Scholar 

  • Zoller, U., Lubezky, A., Nakhleh, M. B., Tessier, B., & Dori, J. (1995). Success on algorithmic and LOCS vs. conceptual chemistry exam questions. Journal of Chemical Education, 72, 987–989.

    Article  Google Scholar 

  • Zoller, U., & Tsaparlis, G. (1997). Higher- and lower-order cognitive skills: The case of chemistry. Research in Science Education, 27, 117–130.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Georgios Tsaparlis .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Tsaparlis, G. (2013). Learning and Teaching the Basic Quantum Chemical Concepts. In: Tsaparlis, G., Sevian, H. (eds) Concepts of Matter in Science Education. Innovations in Science Education and Technology, vol 19. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5914-5_21

Download citation

Publish with us

Policies and ethics