Skip to main content

Chemical Properties of Soil

  • Chapter
  • First Online:
Soils

Abstract

The soil is a chemical entity. All the materials there are chemical substances. Soils are composed of solid, liquid, and gas; soluble and insoluble; and organic as well as inorganic substances. There are ions and compounds, salts, acids, bases, minerals, and rock fragments. There are also colloids which are very active chemically. They are very fine soil particles, including humus, fine silicate clays, and oxides and hydroxides of iron and aluminum. Colloids carry electrochemical charges, both positive and negative, and these charges develop by substitution in the lattice structure and dissociation of active groups. These charges hold oppositely charged ions which are replaceable by ions of similar charges in the soil solution. Along with ion exchange properties, two other important indices of soil chemical environment are pH and Eh. Soil pH is the negative logarithm of hydrogen ion concentration in soil suspensions. It denotes the degree of acidity and alkalinity and influences solubility of chemical substances, availability and uptake of nutrients, and growth and activity of soil microorganisms. Some nutrients become unavailable if the soil pH remains at extremely acid or extremely alkaline conditions. The Eh represents the redox potential which indicates the tendency of a soil to be reduced or oxidized. Redox reactions are very important in soil genesis. There are a variety of other chemical reactions occurring all the time in the soil.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Bolt GH (1982) Soil chemistry. B: Physico-chemical models, 2nd rev edn. Elsevier, Amsterdam

    Google Scholar 

  • Brandt RK, Hughes MR, Bourget LP, Truszkowska K, Greenler RG (1993) The interpretation of CO adsorbed on Pt/SiO2 of two different particle-size distributions. Surf Sci 286:15–25

    Article  CAS  Google Scholar 

  • Chapman DL (1913) A contribution to the theory of electrocapillarity. Philos Mag 25(6):475–481

    Google Scholar 

  • Chisholm-Brause CJ, O’Day PA, Brown GE Jr, Parks GA (1990) Evidence for multinuclear metal-ion complexes at solid/water interfaces from X-ray absorption spectroscopy. Nature 348:528–530

    Article  CAS  Google Scholar 

  • Delaune RD, Reddy KR (2005) Redox potential. In: Hillel D (ed) Encyclopedia of soils in the environment. Academic, New York

    Google Scholar 

  • Evangelou VP (1998) Environmental soil and water chemistry principles and applications. Wiley, New York

    Google Scholar 

  • Foy CD (1984) Physiological effects of hydrogen, aluminum, and manganese toxicities in acid soil. In: Adams F (ed) Soil acidity and liming. American Society of Agronomy, Madison

    Google Scholar 

  • Fried M, Shapiro G (1956) Phosphate supply pattern of various soils. Soil Sci Soc Am Proc 20:471–475

    Article  CAS  Google Scholar 

  • Gee W, Shober A, Anderson B (1999) Chemical reactions in soils. http://www.cee.vt.edu/ewr/environmental/teach/gwprimer/group01/intro.html. Accessed 7 Oct 2011

  • Goldberg S (1992) Use of surface complexation models in soil chemical systems. Adv Agron 47:233–329

    Article  CAS  Google Scholar 

  • Gouy G (1910) Sur la constitution de la charge électrique à la surface d’un electrolyte. Ann Phys (Paris) (IV) 9:457–468

    Google Scholar 

  • Harter RD, Smith G (1981) Langmuir equation and alternate methods of studying “adsorption” reactions in soils. In: Dowdy RH, Ryan JA, Volk VV, Baker DE (eds) Chemistry in the soil environment, Special publication no 40. American Society of Agronomy, Madison

    Google Scholar 

  • Hough RL, Tye A, Crout N, McGrath SP, Zhang H, Young S (2005) Evaluating a free ion activity model applied to metal uptake by Lolium perenne L. grown in contaminated soils. Plant Soil 270(1):1–12

    Article  CAS  Google Scholar 

  • http://www.plantstress.com/Articles/min_deficiency_i/soil_fertility.pdf. Accessed 8 Nov 2011

  • Islam AKMS, Edwards DG, Asher CJ (1980) pH optima for crop growth. Results of a flowing solution culture experiment with six species. Plant Soil 54:339–357

    Article  Google Scholar 

  • IUPAC (2003) IUPAC compendium of chemical terminology. International Union of Pure and Applied Chemistry, Research Triangle Park

    Google Scholar 

  • Jackson ML (2005) Soil chemical analysis – advanced course, Rev 2nd edn. Parallel Press, University of Wisconsin, Madison

    Google Scholar 

  • Jett JW (2005) pH preference of plants. http://www.wvu.edu/~agexten/hortcult/homegarden/pHpref.pdf. Accessed 9 Oct 2011

  • Kennedy CW, Jones JE (1991) Evaluating quantitative screening methods for manganese toxicity in cotton genotypes. J Plant Nutr 14:1331–1339

    Article  CAS  Google Scholar 

  • Langmuir I (1918) The adsorption of gases on plane surface of glass, mica, and platinum. J Am Chem Soc 40:1361–1382

    Article  CAS  Google Scholar 

  • Lovell J (2006) Guidelines for environmental assurance in Australian horticulture. Horticulture Australia Ltd., Sydney

    Google Scholar 

  • McBride MB (1991) Processes of heavy and transition metal sorption by soil minerals. In: Bolt GH, Boodt MFD, Hayes MHB, McBride MB (eds) Interactions at the soil colloid-soil solution interface 190:149–176. Kluwer, Dordrecht

    Google Scholar 

  • McBride MB (1994) Environmental chemistry of soils. Oxford University Press, New York

    Google Scholar 

  • Mgema WG, Clark RB (1995) Sorghum genotypic differences in tolerance to excess manganese. J Plant Nutr 18:983–993

    Article  CAS  Google Scholar 

  • Mortley DG (1993) Manganese toxicity and tolerance in sweet potato. Hortic Sci 28:812–813

    CAS  Google Scholar 

  • Mulder J, Cresser MS (1994) Soil and solution chemistry. In: Moldan B, Cerny J (eds) Biogeochemistry of small catchments, a tool for environmental research. Wiley, Chichester

    Google Scholar 

  • O’Day PA, Brown GE Jr, Parks GA (1994) X-ray absorption spectroscopy of cobalt (II) multinuclear surface complexes and surface precipitates on kaolinite. J Colloid Interf Sci 165:269–289

    Article  Google Scholar 

  • Olsen SR, Watanabe FS (1957) A method to determine a phosphorus adsorption maximum of soils as measured by the Langmuir isotherm. Soil Sci Soc Am Proc 21:144–149

    Article  CAS  Google Scholar 

  • Schofield RK (1947) Calculation of surface areas from measurements of negative adsorption. Nature 160:408

    Article  Google Scholar 

  • Schwertmann U (1991) Solubility and dissolution of iron oxides. Plant Soil 130(1&2):1–25

    Article  CAS  Google Scholar 

  • Seilsepour M, Rashidi M, Khabbaz BG (2009) Prediction of soil exchangeable sodium percentage based on soil sodium adsorption ratio. Am-Eur J Agric Environ Sci 5(1):01–04

    CAS  Google Scholar 

  • Sorenson SPL (1909) Enzyme studies II. The measurement and the importance of the hydrogen ion concentration in enzyme reaction. Coml Rend Tran Lab (Carlsberg) 8:1–168

    Google Scholar 

  • Sparks DL (2003) Environmental soil chemistry, 2nd edn. Academic, Amsterdam

    Google Scholar 

  • Sposito G (1986) Distinguishing adsorption from surface precipitation. In: Davis JA, Hayes KF (eds) Geochemical processes at mineral surfaces. Am Chem Soc Symp Ser 323:217–229

    Google Scholar 

  • Tan KH (2011) Principles of soil chemistry, 4th edn. CRC Press, Boca Raton

    Google Scholar 

  • Taylor GJ, Stadt KJ, Dale MRT (1991) Modelling the phytotoxicity of aluminum, cadmium, copper, manganese, nickel, and zinc stress using the Weibull frequency distribution. Can J Bot 69:359–367

    Article  CAS  Google Scholar 

  • Visconti F, De Paz JM, Rubio JL (2010) Calcite and gypsum solubility products in water-saturated salt-affected soil samples at 25 °C and at least up to 14 dS m−1. Eur J Soil Sci 61:255–270

    Article  CAS  Google Scholar 

  • White RE (2006) Principles and practice of soil science: the soil as a natural resource, 4th edn. Blackwell Publishing, Malden

    Google Scholar 

  • Wolt J (1994) Soil solution chemistry. Wiley, New York

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Khan Towhid Osman .

Rights and permissions

Reprints and permissions

Copyright information

© 2013 Springer Science+Business Media Dordrecht

About this chapter

Cite this chapter

Osman, K.T. (2013). Chemical Properties of Soil. In: Soils. Springer, Dordrecht. https://doi.org/10.1007/978-94-007-5663-2_8

Download citation

Publish with us

Policies and ethics