State of Water in Confinement near Hydrophilic Surfaces Below the Freezing Temperature

Conference paper
Part of the NATO Science for Peace and Security Series B: Physics and Biophysics book series (NAPSB)


The main goal of the research is to find a relationship between the dynamic and the structural properties of water in hydrated heterogeneous systems. The results of dielectric spectroscopy studies of hydrated matrixes of porous glasses, clays and hydrated powder of Lysozyme are presented in wide frequency and temperature intervals. It is shown that for all systems studied the low temperature relaxation process demonstrates Arrhenius kinetics and exhibits a Cole-Cole (CC) behavior. A new phenomenological approach has been recently presented (see Puzenko A, Ben Ishai P, Feldman Yu, Phys Rev Lett 105:037601, 2010) that clarifies the physical mechanism of the dipole-matrix interaction in complex systems (CS) underlying the CC behaviour. A comparison porous glass with clays helps one to understand the specific adsorbed water dynamics due to the variety in the distribution of hydration centers.


Porous Glass Complex Dielectric Permittivity Hydrophilic Material High Temperature Relaxation Unfreezable Water 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.



The authors would like to thank Olga Maximov for help in conducting the Lysozyme experiments and preparation of this article.


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© Springer Science+Business Media Dordrecht 2013

Authors and Affiliations

  1. 1.Department of Applied Physics, Edmond J. Safra CampusThe Hebrew University of JerusalemJerusalemIsrael
  2. 2.Radio-Electronic DepartmentThe Kazan (Volga Region) Federal UniversityKazanRepublic of Tatarstan, Russia

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